A polymeric molecule having the formula: X—[C(A).sub.2C(B)(B′)].sub.n-Q[CY═C(Z)(Z′)] or [C(A).sub.2=C(B)].sub.n-Q[C(Y)(Y′)—C(Z)(Z′)]—X′, wherein A is either H or F; B and B′ are either H, F, or Cl, and are not necessarily the same; X and X′ are Br, Cl or I (and are not necessarily the same); Y and Y′ are F, Br, Cl or I (and are not necessarily the same); and wherein Z and Z′ are F, Br, Cl or I (and are not necessarily the same); Q is optional and is either oxygen (O) or sulfur (S); and n is at least 1.

A polymeric molecule having the formula: X—[C(A).sub.2C(B)(B′)].sub.n-Q[CY═C(Z)(Z′)] or [C(A).sub.2=C(B)].sub.n-Q[C(Y)(Y′)—C(Z)(Z′)]—X′, wherein A is either H or F; B and B′ are either H, F, or Cl, and are not necessarily the same; X and X′ are Br, Cl or I (and are not necessarily the same); Y and Y′ are F, Br, Cl or I (and are not necessarily the same); and wherein Z and Z′ are F, Br, Cl or I (and are not necessarily the same); Q is optional and is either oxygen (O) or sulfur (S); and n is at least 1.

A polymer for a gel polymer electrolyte, a gel polymer electrolyte and a lithium secondary battery comprising the same are disclosed herein. In some embodiments, a polymer for the gel polymer electrolyte includes a copolymer having a main chain and a first side chain and a second side chain bonded to the main chain, wherein the main chain contains a fluoropolymer, wherein the first side chain contains a siloxane group and the second side chain contains an acrylic polymer. The polymer improves stability of a gel polymer electrolyte and a lithium secondary battery including the same.

A polymer for a gel polymer electrolyte, a gel polymer electrolyte and a lithium secondary battery comprising the same are disclosed herein. In some embodiments, a polymer for the gel polymer electrolyte includes a copolymer having a main chain and a first side chain and a second side chain bonded to the main chain, wherein the main chain contains a fluoropolymer, wherein the first side chain contains a siloxane group and the second side chain contains an acrylic polymer. The polymer improves stability of a gel polymer electrolyte and a lithium secondary battery including the same.

A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.

A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.

The present invention relates to a process for the polymerization of fluoromonomers in an aqueous medium, said process comprising the steps of: forming an aqueous emulsion comprising a 2-Alkoxy acetate surfactant and fluoromonomer in a reactor; and initiating polymerization of said fluoromonomer by adding an initiator into the reaction mixture. Preferably, the surfactant used in the instant process is either Sodium 2-[(2-hexyldecyl)oxy] acetate or Sodium-2-dodecyloxyacetate.

The present invention relates to a process for the polymerization of fluoromonomers in an aqueous medium, said process comprising the steps of: forming an aqueous emulsion comprising a 2-Alkoxy acetate surfactant and fluoromonomer in a reactor; and initiating polymerization of said fluoromonomer by adding an initiator into the reaction mixture. Preferably, the surfactant used in the instant process is either Sodium 2-[(2-hexyldecyl)oxy] acetate or Sodium-2-dodecyloxyacetate.

Provided are a fluororesin-containing composition having significantly improved fluidity and a method for producing the same. The fluororesin-containing composition contains 99.99 to 97% by mass of a fluororesin having a melting point of 205° C. to 225° C. and 0.01 to 2% by mass of a thermotropic liquid crystal polymer. The method for producing the fluororesin-containing composition includes kneading polychlorotrifluoroethylene and a thermotropic liquid crystal polymer at 285° C. to 320° C.

A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.