The present disclosure may generally relate to the field of polymer synthesis and provide a method for preparing branched poly(2-hydroxyethyl methacrylate) at room temperature by inverse emulsion polymerization. The method may include: using benzoyl peroxide as an oxidant, and 2-methyl-N-[3-(methyl-phenyl-amino)-propyl]-acrylamide as a reductant monomer to form a redox initiation system, water, and toluene as media, a nonionic surfactant as an emulsifier, 2-hydroxyethyl methacrylate as a monomer, reacting at room temperature and normal pressure to obtain branched poly(2-hydroxyethyl methacrylate). In the present disclosure, the polymerization system may be simple and stable, and the synthesis and purification of the reductant monomer may be simple, greatly reducing the polymerization cost. The reaction may not need temperature control and pressure control, with low energy consumption, easy operation, and less impact on the environment. The obtained branched poly(2-hydroxyethyl methacrylate) may have a high molecular weight. The molecular weight and a branching degree may be adjusted in a wide range. The method may be of great significance to the theoretical research and large-scale application of branched poly(2-hydroxyethyl methacrylate).

The present disclosure may generally relate to the field of polymer synthesis and provide a method for preparing branched poly(2-hydroxyethyl methacrylate) at room temperature by inverse emulsion polymerization. The method may include: using benzoyl peroxide as an oxidant, and 2-methyl-N-[3-(methyl-phenyl-amino)-propyl]-acrylamide as a reductant monomer to form a redox initiation system, water, and toluene as media, a nonionic surfactant as an emulsifier, 2-hydroxyethyl methacrylate as a monomer, reacting at room temperature and normal pressure to obtain branched poly(2-hydroxyethyl methacrylate). In the present disclosure, the polymerization system may be simple and stable, and the synthesis and purification of the reductant monomer may be simple, greatly reducing the polymerization cost. The reaction may not need temperature control and pressure control, with low energy consumption, easy operation, and less impact on the environment. The obtained branched poly(2-hydroxyethyl methacrylate) may have a high molecular weight. The molecular weight and a branching degree may be adjusted in a wide range. The method may be of great significance to the theoretical research and large-scale application of branched poly(2-hydroxyethyl methacrylate).

A preparation method of a hydrogel of a mercapto-modified macromolecular compound includes the steps of combining the mercapto-modified macromolecular compound with an acrylated macromolecular compound and/or an acrylated micromolecular crosslinker. The mercapto-modified macromolecular compound can be crosslinked with the acrylated macromolecular compound and/or the acrylated micromolecular crosslinker under physiological conditions to form the hydrogel. Due to the rapid mercapto-vinyl crosslinking reaction, the formed hydrogel system can be quickly gelled in situ after being injected into the body. The hydrogel is thus suitable for use in the fields of biomedicine, medical cosmetic plastic surgery and cosmetics.

A preparation method of a hydrogel of a mercapto-modified macromolecular compound includes the steps of combining the mercapto-modified macromolecular compound with an acrylated macromolecular compound and/or an acrylated micromolecular crosslinker. The mercapto-modified macromolecular compound can be crosslinked with the acrylated macromolecular compound and/or the acrylated micromolecular crosslinker under physiological conditions to form the hydrogel. Due to the rapid mercapto-vinyl crosslinking reaction, the formed hydrogel system can be quickly gelled in situ after being injected into the body. The hydrogel is thus suitable for use in the fields of biomedicine, medical cosmetic plastic surgery and cosmetics.

The invention provides (meth)acrylic oligomers prepared from C1-C20 alkyl and C5-C20 cycloalkyl (meth)acrylates, wherein said oligomers have a Mn of about 300 g/mole to about 3,000 g/mole; a Mw of about 700 g/mole to about 6,000 g/mole; a Mz of about 900 g/mole to about 10,000 g/mole. The oligomers may have a Yellowness Index, according to ASTM E313 of less than 2. The oligomers of the invention are useful as tackifiers in adhesive compositions, but also are believed to be useful also in general polymer modification as plasticizers, leveling agents, viscosity reducers (i.e., rheology modifiers), and for increasing solids content in solvent-borne applications of all types with little detrimental impact on viscosity. The invention also provides adhesive compositions and laminate articles coated on at least one side with the adhesive compositions of the invention.

The invention provides (meth)acrylic oligomers prepared from C1-C20 alkyl and C5-C20 cycloalkyl (meth)acrylates, wherein said oligomers have a Mn of about 300 g/mole to about 3,000 g/mole; a Mw of about 700 g/mole to about 6,000 g/mole; a Mz of about 900 g/mole to about 10,000 g/mole. The oligomers may have a Yellowness Index, according to ASTM E313 of less than 2. The oligomers of the invention are useful as tackifiers in adhesive compositions, but also are believed to be useful also in general polymer modification as plasticizers, leveling agents, viscosity reducers (i.e., rheology modifiers), and for increasing solids content in solvent-borne applications of all types with little detrimental impact on viscosity. The invention also provides adhesive compositions and laminate articles coated on at least one side with the adhesive compositions of the invention.

An object of the present invention is to provide a sealing method using a cover film where a problem of odor is not likely to occur and quick drying properties and sealability are high.

The sealing method according to the present invention is a sealing method that is performed using at least a cover film and a sealing solvent, the cover film including a polymer layer provided on a transparent support, in which the sealing solvent is a solvent including at least one kind selected from the group consisting of an ester, an alcohol, a ketone, an ether, and an aromatic hydrocarbon, in a case where the sealing solvent is an ester, an alcohol, a ketone, or an ether, a boiling point of the sealing solvent is 80° C. to 170° C., and in a case where the sealing solvent is an aromatic hydrocarbon, a boiling point of the sealing solvent is 150° C. to 170° C.

A surface physical property modifier composition includes (A) a wax, (B) a vinyl (co)polymer, and (C) an aliphatic hydrocarbon having a carbon number of 5 to 14. Component (A) is set to be at least one selected from the group consisting of (a1) paraffin wax, (a2) microcrystalline wax, (a3) Fischer-Tropsch wax, and (a4) polyethylene wax, and component (B) is produced from at least one of (b1) a (meth)acrylonitrile, (b2) a (meth)acrylic acid having a carbon number of 1 to 4, (b3) a hydroxyethyl (meth)acrylate or hydroxypropyl (meth)acrylate, (b4) styrene, and (b5) predetermined (meth)acrylic acid alkyl esters. Component (A) is 50 to 98 parts by mass relative to 100 parts by mass of the total of (A) and (B), and component (C) is 0.001 to 1 percent by mass relative to the total amount of (A).

A multiple-component composition that can be used for producing a corrosion inhibiting (meth)acrylic hydrogel. The multiple-component composition including at least one water soluble (meth)acrylic compound, at least one free radical initiator, at least one benzoate, and optionally at least one catalyst for free radical formation. A method for producing a hydrogel, to a hydrogel obtainable by the method, to a (meth)acrylic injection material, and to a method for sealing cracks, voids, flaws and cavities in building structures.

A multiple-component composition that can be used for producing a corrosion inhibiting (meth)acrylic hydrogel. The multiple-component composition including at least one water soluble (meth)acrylic compound, at least one free radical initiator, at least one benzoate, and optionally at least one catalyst for free radical formation. A method for producing a hydrogel, to a hydrogel obtainable by the method, to a (meth)acrylic injection material, and to a method for sealing cracks, voids, flaws and cavities in building structures.