The invention relates to biosourced vinylidene difluoride. The invention also relates to methods for preparation of biosourced vinylidene difluoride from various renewable raw materials. The invention also relates to homopolymers of vinylidene difluoride obtained from polymerization of said monomer, and also copolymers obtained by copolymerization of said monomer with one or several compatible comonomers. Finally, the invention relates to the use of said homopolymers or copolymers in applications, such as chemical engineering or electronics, in particular mass-market electronic devices.

The invention relates to biosourced vinylidene difluoride. The invention also relates to methods for preparation of biosourced vinylidene difluoride from various renewable raw materials. The invention also relates to homopolymers of vinylidene difluoride obtained from polymerization of said monomer, and also copolymers obtained by copolymerization of said monomer with one or several compatible comonomers. Finally, the invention relates to the use of said homopolymers or copolymers in applications, such as chemical engineering or electronics, in particular mass-market electronic devices.

To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):

CXY═CR.sup.1—COO-(L-O).sub.n—R.sup.2  formula (1):

CXY═CR.sup.3—(O).sub.m—CH.sub.2—Z—R.sup.4  formula (2):

To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):

CXY═CR.sup.1—COO-(L-O).sub.n—R.sup.2  formula (1):

CXY═CR.sup.3—(O).sub.m—CH.sub.2—Z—R.sup.4  formula (2):

High spherical particles for use in piezoelectric applications may be produced mixing a mixture comprising a graphene oxide-polyvinylidene fluoride (GO-PVDF) composite, a carrier fluid that is immiscible with the PVDF, and optionally an emulsion stabilizer at a temperature equal to or greater than a melting point or softening temperature of the PVDF to disperse the GO-PVDF composite in the carrier fluid, wherein the GO-PVDF composite has a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less; cooling the mixture to below the melting point or softening temperature of the PVDF to form GO-PVDF particles; and separating the GO-PVDF particles from the carrier fluid, wherein the GO-PVDF particles comprise the graphene oxide dispersed in the PVDF, and wherein the GO-PVDF particles have a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less.

High spherical particles for use in piezoelectric applications may be produced mixing a mixture comprising a graphene oxide-polyvinylidene fluoride (GO-PVDF) composite, a carrier fluid that is immiscible with the PVDF, and optionally an emulsion stabilizer at a temperature equal to or greater than a melting point or softening temperature of the PVDF to disperse the GO-PVDF composite in the carrier fluid, wherein the GO-PVDF composite has a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less; cooling the mixture to below the melting point or softening temperature of the PVDF to form GO-PVDF particles; and separating the GO-PVDF particles from the carrier fluid, wherein the GO-PVDF particles comprise the graphene oxide dispersed in the PVDF, and wherein the GO-PVDF particles have a transmission FTIR minimum transmittance ratio of β-phase PVDF to α-phase PVDF of about 1 or less.

A fluorinated polymer suitable for deposition and capable of favorable metal patterning, is provided. A resin film containing such a fluorinated polymer as a material is provided. Further, a photoelectronic element having such a resin film in its structure is provided.

A fluorinated polymer which satisfies the following requirements (1) to (3): (1) the melting point is less than 200° C., or no melting point is observed, (2) the thermogravimetric loss rate when the temperature is increased at a temperature-increasing rate of 2° C./min under a pressure of 1×10.sup.−3 Pa, substantially reaches 100% at 400° C. or lower, (3) when the temperature is increased at a temperature-increasing rate of 2° C./min under a pressure of 1×10.sup.−3 Pa, the temperature width from a temperature at which the thermogravimetric loss rate is 10% to a temperature at which it is 90%, is within 200° C.

A fluorinated polymer suitable for deposition and capable of favorable metal patterning, is provided. A resin film containing such a fluorinated polymer as a material is provided. Further, a photoelectronic element having such a resin film in its structure is provided.

A fluorinated polymer which satisfies the following requirements (1) to (3): (1) the melting point is less than 200° C., or no melting point is observed, (2) the thermogravimetric loss rate when the temperature is increased at a temperature-increasing rate of 2° C./min under a pressure of 1×10.sup.−3 Pa, substantially reaches 100% at 400° C. or lower, (3) when the temperature is increased at a temperature-increasing rate of 2° C./min under a pressure of 1×10.sup.−3 Pa, the temperature width from a temperature at which the thermogravimetric loss rate is 10% to a temperature at which it is 90%, is within 200° C.

Examples include a device including a nanovoided polymer element having a first surface and a second surface, a first plurality of electrodes disposed on the first surface, a second plurality of electrodes disposed on the second surface, and a control circuit configured to apply an electrical potential between one or more of the first plurality of electrodes and one or more of the second plurality of electrodes to induce a physical deformation of the nanovoided polymer element.

Examples include a device including a nanovoided polymer element having a first surface and a second surface, a first plurality of electrodes disposed on the first surface, a second plurality of electrodes disposed on the second surface, and a control circuit configured to apply an electrical potential between one or more of the first plurality of electrodes and one or more of the second plurality of electrodes to induce a physical deformation of the nanovoided polymer element.