A perfluorodiacyl peroxide represented by the following formula (1):
(C.sub.5F.sub.11COO).sub.2   (1).
Also disclosed is a solution containing the perfluorodiacyl peroxide, a polymerization initiator containing the perfluorodiacyl peroxide, a method for producing a polymer which includes polymerizing a radically polymerizable monomer with the perfluorodiacyl peroxide, and a perfluoroacyl chloride represent by the following formula (2):
C.sub.5F.sub.11COCl (2).

A perfluorodiacyl peroxide represented by the following formula (1):
(C.sub.5F.sub.11COO).sub.2   (1).
Also disclosed is a solution containing the perfluorodiacyl peroxide, a polymerization initiator containing the perfluorodiacyl peroxide, a method for producing a polymer which includes polymerizing a radically polymerizable monomer with the perfluorodiacyl peroxide, and a perfluoroacyl chloride represent by the following formula (2):
C.sub.5F.sub.11COCl (2).

The present invention relates to a flame-retardant polycarbonate composition comprising the following components, relative to the total weight of the composition: A) 30-70 wt. % of at least one aromatic polycarbonate, B) 20-60 wt. % of at least one polysiloxane-polycarbonate block condensate, C) 0.5-5 wt. % of at least one cyclic phosphazene, D) 1-5 wt. % of at least one silicone-acrylate rubber based impact modifier, E) 0.3-3 wt % of kaolin, F) 0.1-1 wt. % of at least one anti-dripping agent, and G) 0.1-1 wt. % of at least one UV absorber. The present invention also relates to a shaped article produced from the composition. The polycarbonate composition according to the present invention has a good combination of low-temperature impact performance, flame-retardancy, hydrolytic stability, anti-UV performance, and heat resistance.

The present invention relates to a flame-retardant polycarbonate composition comprising the following components, relative to the total weight of the composition: A) 30-70 wt. % of at least one aromatic polycarbonate, B) 20-60 wt. % of at least one polysiloxane-polycarbonate block condensate, C) 0.5-5 wt. % of at least one cyclic phosphazene, D) 1-5 wt. % of at least one silicone-acrylate rubber based impact modifier, E) 0.3-3 wt % of kaolin, F) 0.1-1 wt. % of at least one anti-dripping agent, and G) 0.1-1 wt. % of at least one UV absorber. The present invention also relates to a shaped article produced from the composition. The polycarbonate composition according to the present invention has a good combination of low-temperature impact performance, flame-retardancy, hydrolytic stability, anti-UV performance, and heat resistance.

The present invention relates to a process for preparing a fluoropolymer in a liquid reaction medium, comprising the following steps: provide a reactor containing a liquid reaction medium comprising water introduce in said reactor ethylene monomers and fluorinated monomers, said fluorinated monomers being selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE) or mixtures thereof, pressurize the reactor, initiate polymerization feeding into said reactor a redox initiator comprising an oxidising agent and a reducing agent, wherein said reducing agent in said redox couple initiator is free from sulphur atoms having an oxidation number of 4 or below, wherein the reaction medium is free of fluorinated surfactants.

The present invention relates to a process for preparing a fluoropolymer in a liquid reaction medium, comprising the following steps: provide a reactor containing a liquid reaction medium comprising water introduce in said reactor ethylene monomers and fluorinated monomers, said fluorinated monomers being selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE) or mixtures thereof, pressurize the reactor, initiate polymerization feeding into said reactor a redox initiator comprising an oxidising agent and a reducing agent, wherein said reducing agent in said redox couple initiator is free from sulphur atoms having an oxidation number of 4 or below, wherein the reaction medium is free of fluorinated surfactants.

A method for producing a fluoropolymer which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer, the surfactant being represented by the general formula (1): CR.sup.1R.sup.2R.sup.4—CR.sup.3R.sup.5—X-A, wherein R.sup.1 to R.sup.5 are each H or a monovalent substituent, with the proviso that at least one of R.sup.1 and R.sup.3 represents a group represented by the general formula: —Y—R.sup.6 and at least one of R.sup.2 and R.sup.3 represents a group represented by the general formula: —X-A or a group represented by the general formula: —Y—R.sup.6; and A is the same or different at each occurrence and is —COOM, —SO.sub.3M, or —OSO.sub.3M. Also disclosed is a surfactant for polymerization represented by the general formula (1), a method for producing a fluoropolymer using the surfactant, a composition including a fluoropolymer and the surfactant and a molded body including the composition.

To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):

CXY═CR.sup.1—COO-(L-O).sub.n—R.sup.2  formula (1):

CXY═CR.sup.3—(O).sub.m—CH.sub.2—Z—R.sup.4  formula (2):

To provide a method for producing a fluorinated polymer which does not require an emulsifier as an essential component while an aqueous medium with little environmental burden is used. A method for producing a fluorinated polymer, which comprises polymerizing at least one fluorinated polymer selected from tetrafluoroethylene, chlorotrifluoroethylene and vinylidene fluoride, in an aqueous medium in the presence of a specific polymer having at least one type of units selected from units based on a compound represented by the formula (1) and units based on a compound represented by the formula (2) to produce a fluorinated polymer (provided that when tetrafluoroethylene is polymerized, tetrafluoroethylene is polymerized so that the content of units based on tetrafluoroethylene in the fluorinated polymer becomes less than 99 mass % to all units in the fluorinated polymer):

CXY═CR.sup.1—COO-(L-O).sub.n—R.sup.2  formula (1):

CXY═CR.sup.3—(O).sub.m—CH.sub.2—Z—R.sup.4  formula (2):

A method for producing a composition containing low molecular weight polytetrafluoroethylene, the method including: (I) irradiating a composition containing high molecular weight polytetrafluoroethylene with ionizing radiation to obtain a composition containing low molecular weight polytetrafluoroethylene having a melt viscosity at 380° C. in the range of 1.0×10.sup.2 to 7.0×10.sup.5 Pa.Math.s; and (II) decomposing a low molecular weight fluorine-containing compound contained in the composition containing low molecular weight polytetrafluoroethylene obtained above.