Copolymers and latex paint compositions using such copolymers that are heat-age stable and provide good adhesion, block resistance, and hiding all while using lower amounts of pigment are described herein. In one aspect, the heat-age stable compositions include an acrylic, styrene acrylic, vinyl acrylic copolymer or blends thereof including, as additional polymerizable units, at least one polymerizable phosphate surfactant and at least one linear or branched hydrophobic monomer that are both polymerized into the acrylic, styrene acrylic, vinyl acrylic copolymer backbone.

The present specification relates to a (meth)acrylate compound, and a copolymer and a homopolymer including a repeating unit derived therefrom.

The invention relates to the use of a branched polyester having an average of at least 2.8 terminal groups as additive for a curable pre-polymer composition, wherein the branched polyester acts as de-foaming agent.

The invention relates to the use of a branched polyester having an average of at least 2.8 terminal groups as additive for a curable pre-polymer composition, wherein the branched polyester acts as de-foaming agent.

Provided is a method for producing a polyvinyl alcohol having improved mechanical strength without significantly impairing productivity. A method for producing a polyvinyl alcohol having an average degree of polymerization of 5.0×10.sup.3 or more and 1.5×10.sup.4 or less, the method including steps of: subjecting a vinyl ester-based monomer to suspension polymerization at a polymerization temperature of 10° C. or more and 50° C. or less with a polymerization rate of 10% or more and 70% or less to obtain a vinyl ester-based polymer; dissolving the vinyl ester-based polymer in an alcohol-based solvent; and carrying out a saponification reaction by adding a saponification catalyst to an alcohol-based solution of the dissolved vinyl ester-based polymer.

Provided is a method for producing a polyvinyl alcohol having improved mechanical strength without significantly impairing productivity. A method for producing a polyvinyl alcohol having an average degree of polymerization of 5.0×10.sup.3 or more and 1.5×10.sup.4 or less, the method including steps of: subjecting a vinyl ester-based monomer to suspension polymerization at a polymerization temperature of 10° C. or more and 50° C. or less with a polymerization rate of 10% or more and 70% or less to obtain a vinyl ester-based polymer; dissolving the vinyl ester-based polymer in an alcohol-based solvent; and carrying out a saponification reaction by adding a saponification catalyst to an alcohol-based solution of the dissolved vinyl ester-based polymer.

A vinyl alcohol-based polymer useful as an additive for oil well cement is provided. The vinyl alcohol-based polymer is produced by saponification of a homopolymer of a vinyl ester monomer or a copolymer of a vinyl ester monomer and a polyfunctional monomer, wherein the vinyl alcohol-based polymer has a difference between transmittance (A) of 1 mass % aqueous solution at 660 nm and transmittance (B) of 1 mass % aqueous solution at 430 nm, i.e. (A-B), of 5 to 25. It is preferable that 1 mass % aqueous solution of the vinyl alcohol-based polymer have a transmittance of 95% or less in an entire wavelength region of 200 nm to 800 nm, and the vinyl alcohol-based polymer have a yellow index of 10 or less.

Provided is a method for producing a polyvinyl alcohol having improved mechanical strength without significantly impairing productivity. A method for producing a polyvinyl alcohol having an average degree of polymerization of 5.0×10.sup.3 or more and 1.5×10.sup.4 or less, the method including steps of: subjecting a vinyl ester-based monomer to suspension polymerization at a polymerization temperature of 10° C. or more and 50° C. or less with a polymerization rate of 10% or more and 70% or less to obtain a vinyl ester-based polymer; dissolving the vinyl ester-based polymer in an alcohol-based solvent; and carrying out a saponification reaction by adding a saponification catalyst to an alcohol-based solution of the dissolved vinyl ester-based polymer.

Provided is a method for producing a polyvinyl alcohol having improved mechanical strength without significantly impairing productivity. A method for producing a polyvinyl alcohol having an average degree of polymerization of 5.0×10.sup.3 or more and 1.5×10.sup.4 or less, the method including steps of: subjecting a vinyl ester-based monomer to suspension polymerization at a polymerization temperature of 10° C. or more and 50° C. or less with a polymerization rate of 10% or more and 70% or less to obtain a vinyl ester-based polymer; dissolving the vinyl ester-based polymer in an alcohol-based solvent; and carrying out a saponification reaction by adding a saponification catalyst to an alcohol-based solution of the dissolved vinyl ester-based polymer.

A preparation method of vinyl ester resin for optimizing heat-release during curing includes: (A) providing a vinyl ester, a solvent and a phase change material to perform mixture; (B) performing a heating process to remove the solvent, so as to obtain a vinyl ester resin containing the phase change material. Thereby, the organic PCM material with high heat absorption and good resin affinity can be used as the temperature control agent of the vinyl ester resin during the curing process for avoiding the defects such as bubbles and cracks being generated in the vinyl ester resin.