Compositions may include an EVA copolymer produced from ethylene, vinyl acetate, and one or more polar comonomers, wherein at least one of the one or more polar comonomers include an amine moiety. Methods may include preparing a polymer composition by adding ethylene, vinyl acetate and one or more polar comonomers to a reactor or extruder, wherein at least one of the one or more polar comonomers include an amine moiety; and reacting the ethylene, vinyl acetate and one or more comonomers to produce the polymer composition. Compositions may include an adhesive film composition that include at least one layer including a polymer produced from ethylene, vinyl acetate, and one or more polar comonomers, wherein at least one of the one or more polar comonomers include an amine moiety.

Compositions may include an EVA copolymer produced from ethylene, vinyl acetate, and one or more polar comonomers, wherein at least one of the one or more polar comonomers include an amine moiety. Methods may include preparing a polymer composition by adding ethylene, vinyl acetate and one or more polar comonomers to a reactor or extruder, wherein at least one of the one or more polar comonomers include an amine moiety; and reacting the ethylene, vinyl acetate and one or more comonomers to produce the polymer composition. Compositions may include an adhesive film composition that include at least one layer including a polymer produced from ethylene, vinyl acetate, and one or more polar comonomers, wherein at least one of the one or more polar comonomers include an amine moiety.

The present disclosure relates to a formaldehyde-free aqueous curable composition comprising: A) a polymer polymerized from a monomer mixture comprising (a) 30-90 wt % of C.sub.1-C.sub.10 alkyl acrylate; (b) 10-60 wt % of vinylaromatics; (c) 0.5-10 wt % of an ethylenically unsaturated compound having at least two carboxylic acid groups; (d) 0-10 wt % of an ethylenically unsaturated acid having one carboxylic acid group; (e) 0-5 wt % of other ethylenically unsaturated monomers; wherein the percentages are based on the total weight of the monomer mixture; and B) a titanium catalyst.

The present disclosure relates to a formaldehyde-free aqueous curable composition comprising: A) a polymer polymerized from a monomer mixture comprising (a) 30-90 wt % of C.sub.1-C.sub.10 alkyl acrylate; (b) 10-60 wt % of vinylaromatics; (c) 0.5-10 wt % of an ethylenically unsaturated compound having at least two carboxylic acid groups; (d) 0-10 wt % of an ethylenically unsaturated acid having one carboxylic acid group; (e) 0-5 wt % of other ethylenically unsaturated monomers; wherein the percentages are based on the total weight of the monomer mixture; and B) a titanium catalyst.

It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##

It is an object of the present invention to provide a method for producing a terminal-modified polybutadiene or terminal-modified hydrogenated polybutadiene that does not become colored or white and turbid, without using an organotin compound. The production method of the present invention includes reacting an acrylate or methacrylate represented by formula (I), a diisocyanate compound represented by formula (II), and a polybutadiene or hydrogenated polybutadiene having a hydroxyl group at a polymer terminal, represented by formula (III), in the presence of at least one selected from an organoaluminum compound and an organozinc compound (with the proviso that zinc naphthenate is excluded). ##STR00001##

A compound represented by Formula (1) given below. (In the formula, R.sup.1 represents a hydrogen atom or a methyl group, and X represents a C.sub.2 to 6 alkylene group, a C.sub.4 to 6 alkylene group containing an oxygen atom and/or a sulfur atom, or a C.sub.3 to 6 alkylene group in which at least one hydrogen is replaced with an acryloxy group or a methacryloxy group.)

A compound represented by Formula (1) given below. (In the formula, R.sup.1 represents a hydrogen atom or a methyl group, and X represents a C.sub.2 to 6 alkylene group, a C.sub.4 to 6 alkylene group containing an oxygen atom and/or a sulfur atom, or a C.sub.3 to 6 alkylene group in which at least one hydrogen is replaced with an acryloxy group or a methacryloxy group.)

A cured product that is reduced in warping and has high hardness can be obtained from an active energy ray-curable resin composition which uses a methacrylic acid ester polymer that has an acid value of 50 mg KOH/g or less and a transition metal content of 1 ppm or less, while containing 80% by mole or more of a polymer that has a double bond-terminated structure represented by formula (1). (In formula (1), R represents an alkyl group, a cycloalkyl group or an aryl group.) ##STR00001##

A cured product that is reduced in warping and has high hardness can be obtained from an active energy ray-curable resin composition which uses a methacrylic acid ester polymer that has an acid value of 50 mg KOH/g or less and a transition metal content of 1 ppm or less, while containing 80% by mole or more of a polymer that has a double bond-terminated structure represented by formula (1). (In formula (1), R represents an alkyl group, a cycloalkyl group or an aryl group.) ##STR00001##