The present invention provides a sulfur-modified polyacrylonitrile having a total content of sulfur of from 30 mass % to 55 mass % and having a content of free sulfur of from 0.05 ppm by mass to 4 mass % determined by a solvent extraction method, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.

The present invention provides a sulfur-modified polyacrylonitrile having a total content of sulfur of from 30 mass % to 55 mass % and having a content of free sulfur of from 0.05 ppm by mass to 4 mass % determined by a solvent extraction method, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.

Some embodiments of the disclosure provides polyacrylonitrile (PAN) and a preparation method and use thereof. The method includes the following steps. Mixing raw materials for polymerization to obtain a suspension comprising the PAN. The raw materials include an acrylonitrile monomer, a first auxiliary monomer, a second auxiliary monomer, a polymerization medium, an initiator, a chain transfer agent, and a settling agent. Removing unreacted monomers and unreacted polymerization medium in the suspension to obtain the PAN. After subsequent removal of monomers, removal of a polymerization medium, washing, and drying, a PAN powder is obtained. In some embodiments, the preparation method of the PAN has a wide adjustable range of a PAN copolymerization composition, a low viscosity of a polymerization system, a high concentration of a polymerized monomer, and a strong anti-scaling ability.

Some embodiments of the disclosure provides polyacrylonitrile (PAN) and a preparation method and use thereof. The method includes the following steps. Mixing raw materials for polymerization to obtain a suspension comprising the PAN. The raw materials include an acrylonitrile monomer, a first auxiliary monomer, a second auxiliary monomer, a polymerization medium, an initiator, a chain transfer agent, and a settling agent. Removing unreacted monomers and unreacted polymerization medium in the suspension to obtain the PAN. After subsequent removal of monomers, removal of a polymerization medium, washing, and drying, a PAN powder is obtained. In some embodiments, the preparation method of the PAN has a wide adjustable range of a PAN copolymerization composition, a low viscosity of a polymerization system, a high concentration of a polymerized monomer, and a strong anti-scaling ability.

Compositions that include a polymer and an aldaric acid, such as glucaric acid, are disclosed. The compositions may include polyvinyl alcohol and glucaric acid. The compositions may also include polyacrylonitrile and glucaric acid. In addition, the compositions may further include lignin. Also disclosed are fibers including the compositions, methods of making the fibers, and uses of the fibers.

Compositions that include a polymer and an aldaric acid, such as glucaric acid, are disclosed. The compositions may include polyvinyl alcohol and glucaric acid. The compositions may also include polyacrylonitrile and glucaric acid. In addition, the compositions may further include lignin. Also disclosed are fibers including the compositions, methods of making the fibers, and uses of the fibers.

A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

A glove including a cured film of an elastomer containing a (meth)acrylonitrile-derived structural unit, an unsaturated carboxylic acid-derived structural unit and a butadiene-derived structural unit in a polymer main chain, wherein the elastomer contains 20 to 40% by weight of a (meth)acrylonitrile-derived structural unit, 1 to 10% by weight of an unsaturated carboxylic acid-derived structural unit and 50 to 75% by weight of a butadiene-derived structural unit, and has a crosslinked structure of a carboxyl group in the unsaturated carboxylic acid-derived structural unit with an epoxy crosslinker containing an epoxy compound having three or more epoxy groups in one molecule.

The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).

The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).