A polymer including VDF-based units having an electrocaloric effect under the effect of a variable electric field. The polymer includes 0.1 to 10.0 mol % double bonds, which are substantially non-conjugated. Also, a corresponding composition including the polymer, a corresponding film including the polymer, and to various uses of the polymer.

A polymer including VDF-based units having an electrocaloric effect under the effect of a variable electric field. The polymer includes 0.1 to 10.0 mol % double bonds, which are substantially non-conjugated. Also, a corresponding composition including the polymer, a corresponding film including the polymer, and to various uses of the polymer.

The disclosure provides an improved process for preparing oleophobic fluoropolymers. The resulting fluropolymers were found to be effective in imparting hydrophobic and oleophobic properties to porous polymeric membranes such as PTFE. The treated PTFE membrane can reach an oleophobic level of 6 or above, (according to the AATCC-118-1997 oil repellency test method) with a low air flux loss.

Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

An ethylene/tetrafluoroethylene copolymer satisfying the following formula (1), wherein peak intensities, determined by Fourier transform infrared spectroscopy, of vibrations derived from a —CF.sub.2H group, a —CF.sub.2CH.sub.2COF group, a —COF group, a —COOH group, a dimer of a —CF.sub.2COOH group and a monomer of a CF.sub.2CH.sub.2COOH group, a —COOCH.sub.3 group, a —CONH.sub.2 group, and a —CH.sub.2OH group satisfy the following formula (2):
75≤tan δ(60)/tan δ(5)×100≤225  (1)
PI.sub.A/(PI.sub.B+PI.sub.C+PI.sub.D+PI.sub.E+PI.sub.F+PI.sub.G+PI.sub.H)≥0.60  (2) wherein tan δ(60), tan δ(5), PI.sub.A, PI.sub.B, PI.sub.C, PI.sub.D, PI.sub.E, PI.sub.F, PI.sub.G and PI.sub.H are as defined in the specification. Also disclosed is a molded article obtained by molding the ethylene/tetrafluoroethylene copolymer and an electric wire including a core and a coat formed from the ethylene/tetrafluoroethylene copolymer.

An ethylene/tetrafluoroethylene copolymer satisfying the following formula (1), wherein peak intensities, determined by Fourier transform infrared spectroscopy, of vibrations derived from a —CF.sub.2H group, a —CF.sub.2CH.sub.2COF group, a —COF group, a —COOH group, a dimer of a —CF.sub.2COOH group and a monomer of a CF.sub.2CH.sub.2COOH group, a —COOCH.sub.3 group, a —CONH.sub.2 group, and a —CH.sub.2OH group satisfy the following formula (2):
75≤tan δ(60)/tan δ(5)×100≤225  (1)
PI.sub.A/(PI.sub.B+PI.sub.C+PI.sub.D+PI.sub.E+PI.sub.F+PI.sub.G+PI.sub.H)≥0.60  (2) wherein tan δ(60), tan δ(5), PI.sub.A, PI.sub.B, PI.sub.C, PI.sub.D, PI.sub.E, PI.sub.F, PI.sub.G and PI.sub.H are as defined in the specification. Also disclosed is a molded article obtained by molding the ethylene/tetrafluoroethylene copolymer and an electric wire including a core and a coat formed from the ethylene/tetrafluoroethylene copolymer.

A copolymer including fluorinated units of formula (I):

—CX.sub.1X.sub.2—CX.sub.3X.sub.4—  (I)

in which each of the X.sub.1, X.sub.2, X.sub.3 and X.sub.4 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated; and fluorinated units of formula (II):

—CX.sub.5X.sub.6—CX.sub.7Z—  (II)

in which each of the X.sub.5, X.sub.6 and X.sub.7 is independently chosen from H, F and alkyl groups including from 1 to 3 carbon atoms which are optionally partially or totally fluorinated, and in which Z is a photoactive group of formula —Y—Ar—R, Y representing an oxygen atom or an NH group or a sulfur atom, Ar representing an aryl group, and R being a monodentate or bidentate group including from 1 to 30 carbon atoms. Also, a process for preparing this copolymer, a composition including this copolymer, and a film obtained from this copolymer.

Provided is a fuel filler pipe including: an inner layer that contains a fluorine-containing copolymer having a carbonyl group-containing group and having a melting point of 250° C. or lower; an intermediate layer that contains a non-fluorine copolymer having a unit based on ethylene and a unit based on vinyl alcohol; and an outer layer that contains a polyolefin, wherein the inner layer, the intermediate layer, and the outer layer are directly laminated in that order, and the outer layer is a layer that contains a polyolefin having a unit based on an acid anhydride or is a layer in which a layer that contains a polyolefin having a unit based on an acid anhydride and a layer that contains a polyolefin having no unit based on an acid anhydride are directly laminated.

Provided is a fuel filler pipe including: an inner layer that contains a fluorine-containing copolymer having a carbonyl group-containing group and having a melting point of 250° C. or lower; an intermediate layer that contains a non-fluorine copolymer having a unit based on ethylene and a unit based on vinyl alcohol; and an outer layer that contains a polyolefin, wherein the inner layer, the intermediate layer, and the outer layer are directly laminated in that order, and the outer layer is a layer that contains a polyolefin having a unit based on an acid anhydride or is a layer in which a layer that contains a polyolefin having a unit based on an acid anhydride and a layer that contains a polyolefin having no unit based on an acid anhydride are directly laminated.