The present invention relates to a process for preparing a fluoropolymer in a liquid reaction medium, comprising the following steps: provide a reactor containing a liquid reaction medium comprising water introduce in said reactor ethylene monomers and fluorinated monomers, said fluorinated monomers being selected from tetrafluoroethylene (TFE), chlorotrifluoroethylene (CTFE) or mixtures thereof, pressurize the reactor, initiate polymerization feeding into said reactor a redox initiator comprising an oxidising agent and a reducing agent, wherein said reducing agent in said redox couple initiator is free from sulphur atoms having an oxidation number of 4 or below, wherein the reaction medium is free of fluorinated surfactants.

A film includes a copolymer having a tetrafluoroethylene-based unit and an ethylene-based unit, in which the film has a haze of from 1.2% to 8.0%, an ultraviolet reflectance of less than 17.0%, and a thickness of from 250 to 400 μm.

The present invention aims to provide a method of producing a fluoropolymer, especially a fluoropolymer essentially including a tetrafluoroethylene or chlorotrifluoroethylene unit, at a higher polymerization rate with improved efficiency, the method being capable of improving the moldability in extrusion molding and suppressing discoloration. The method of producing a fluoropolymer of the present invention includes producing a fluoropolymer by polymerizing tetrafluoroethylene or chlorotrifluoroethylene in the presence of a peroxydicarbonate. The peroxydicarbonate is represented by the formula:
R—O—C(═O)—O—O—C(═O)—O—R
wherein R's may be the same as or different from each other and individually represent a C4 alkyl group or alkoxy alkyl group.

A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.

Methods for forming a graft copolymer of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer are provided. The methods comprise a) irradiating a poly(vinylidene fluoride)-based polymer with a stream of electrically charged particles; b) forming a solution comprising the irradiated poly(vinylidene fluoride)-based polymer, an electrically conductive monomer and an acid in a suitable solvent; and c) adding an oxidant to the solution to form the graft copolymer. Graft copolymers of a poly(vinylidene fluoride)-based polymer and at least one type of electrically conductive polymer, wherein the electrically conductive polymer is grafted on the poly(vinylidene fluoride)-based polymer, nanocomposite materials comprising the graft copolymer, and multilayer capacitors comprising the nanocomposite material are also provided.

The invention pertains to a thermoplastic fluoropolymer composition comprising one or more polymer A comprising recurring units derived from ethylene and recurring units derived from halogenated monomers selected from chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE) and one or more polymer B comprising recurring units derived from ethylene, recurring units derived from halogenated monomers selected from CTFE and TFE, and recurring units derived from hexafluoroisobutylene (HFIB) and/or perfluoropropylvinylether (PPVE). The resulting composition allows to manufacture films having exceptional transparency and good mechanical properties which can be used for examples as architectural films.

The invention pertains to a thermoplastic fluoropolymer composition comprising one or more polymer A comprising recurring units derived from ethylene and recurring units derived from halogenated monomers selected from chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE) and one or more polymer B comprising recurring units derived from ethylene, recurring units derived from halogenated monomers selected from CTFE and TFE, and recurring units derived from hexafluoroisobutylene (HFIB) and/or perfluoropropylvinylether (PPVE). The resulting composition allows to manufacture films having exceptional transparency and good mechanical properties which can be used for examples as architectural films.

The invention pertains to a multilayer assembly comprising: (L1) a first inner layer [layer (L1)] made from a first composition [composition (C1)], said composition (C1) comprising: at least one polymer comprising recurring units derived from ethylene (E) and from chlorotrifluoroethylene (CTFE), and at least one Ti compound; and (L2) a second outer layer [layer (L2)] made from a second composition [composition (C2)], said composition (C2) being substantially free from TiO.sub.2-containing additives, said second composition comprising at least one semi-crystalline polymer comprising recurring units derived from ethylene and from at least one fluoromonomer selected from chlorotrifluoroethylene (CTFE), tetrafluoroethylene (TFE) and mixtures thereof, said semi-crystalline polymer having a heat of fusion of at least 35 J/g [polymer (A)].

A curable composition containing at least one of a haloalkyl ether (meth)acrylate or a haloalkenyl ether (meth)acrylate and, optionally, one or more different types of co-monomers is cured to provide a polymer having advantageous properties as a result of the incorporation of halogenated functionality derived from the haloalkyl/haloalkenyl ether (meth)acrylate monomer.

The invention pertains to certain fluoropolymer-based hybrid organic/inorganic composites, to polymer electrolytes obtained therefrom and to use of said polymer electrolytes in electrochemical devices.