Patent classifications
C08F214/28
Perfluoro diacyl peroxide as polymerization initiator and polymer preparation method
A perfluorodiacyl peroxide represented by the following formula (1):
(C.sub.5F.sub.11COO).sub.2 (1).
Also disclosed is a solution containing the perfluorodiacyl peroxide, a polymerization initiator containing the perfluorodiacyl peroxide, a method for producing a polymer which includes polymerizing a radically polymerizable monomer with the perfluorodiacyl peroxide, and a perfluoroacyl chloride represent by the following formula (2):
C.sub.5F.sub.11COCl (2).
Perfluoro diacyl peroxide as polymerization initiator and polymer preparation method
A perfluorodiacyl peroxide represented by the following formula (1):
(C.sub.5F.sub.11COO).sub.2 (1).
Also disclosed is a solution containing the perfluorodiacyl peroxide, a polymerization initiator containing the perfluorodiacyl peroxide, a method for producing a polymer which includes polymerizing a radically polymerizable monomer with the perfluorodiacyl peroxide, and a perfluoroacyl chloride represent by the following formula (2):
C.sub.5F.sub.11COCl (2).
Co-cured fluoroelastomers with improved chemical resistance
Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
Co-cured fluoroelastomers with improved chemical resistance
Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
Co-cured fluoroelastomers with improved chemical resistance
Co-cured blends of fluoroelastomers of tetrafluoroethylene-propylene copolymer with cure site monomer and terpolymers of Vinylidene fluoride (VDF), Hexafluoropropylene (HFP) and Tetrafluoroethylene (TFE) with peroxide as initiator and coagent TAIC as crosslinker show improved curing performance, improved mechanical properties and improved compression set as well. The co-cured fluoroelastomers show improved chemical resistance to the solvent aging systems and better retention of mechanical properties after aging at high temperature in the solvents system.
METHOD FOR MANUFACTURING FLUOROPOLYMER, SURFACTANT FOR POLYMERIZATION, USE FOR SURFACTANT, AND COMPOSITION
A method for producing a fluoropolymer which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer, the surfactant being represented by the general formula (1): CR.sup.1R.sup.2R.sup.4—CR.sup.3R.sup.5—X-A, wherein R.sup.1 to R.sup.5 are each H or a monovalent substituent, with the proviso that at least one of R.sup.1 and R.sup.3 represents a group represented by the general formula: —Y—R.sup.6 and at least one of R.sup.2 and R.sup.3 represents a group represented by the general formula: —X-A or a group represented by the general formula: —Y—R.sup.6; and A is the same or different at each occurrence and is —COOM, —SO.sub.3M, or —OSO.sub.3M. Also disclosed is a surfactant for polymerization represented by the general formula (1), a method for producing a fluoropolymer using the surfactant, a composition including a fluoropolymer and the surfactant and a molded body including the composition.
METHOD FOR MANUFACTURING FLUOROPOLYMER, SURFACTANT FOR POLYMERIZATION, USE FOR SURFACTANT, AND COMPOSITION
A method for producing a fluoropolymer which includes polymerizing a fluoromonomer in an aqueous medium in the presence of a surfactant to provide a fluoropolymer, the surfactant being represented by the general formula (1): CR.sup.1R.sup.2R.sup.4—CR.sup.3R.sup.5—X-A, wherein R.sup.1 to R.sup.5 are each H or a monovalent substituent, with the proviso that at least one of R.sup.1 and R.sup.3 represents a group represented by the general formula: —Y—R.sup.6 and at least one of R.sup.2 and R.sup.3 represents a group represented by the general formula: —X-A or a group represented by the general formula: —Y—R.sup.6; and A is the same or different at each occurrence and is —COOM, —SO.sub.3M, or —OSO.sub.3M. Also disclosed is a surfactant for polymerization represented by the general formula (1), a method for producing a fluoropolymer using the surfactant, a composition including a fluoropolymer and the surfactant and a molded body including the composition.
ETHYLENE-VINYL ALCOHOL COPOLYMER COMPOSITION, AND MONOLAYER FILM AND MULTILAYER STRUCTURE CONTAINING THE SAME
The present invention relates to an ethylene-vinyl alcohol copolymer composition, a single-layer film and a multilayer structure containing the same. Said ethylene-vinyl alcohol copolymer composition includes an ethylene-vinyl alcohol copolymer, an antioxidant, and a fluorine-containing compound; and the ratio of the antioxidant content to the fluorine content is 0.5 to 65. Thereby, the film containing said ethylene-vinyl alcohol copolymer composition not only has good heat resistance, but also can avoid the situation that a large number of gels are generated during the preparation process.
ETHYLENE-VINYL ALCOHOL COPOLYMER COMPOSITION, AND MONOLAYER FILM AND MULTILAYER STRUCTURE CONTAINING THE SAME
The present invention relates to an ethylene-vinyl alcohol copolymer composition, a single-layer film and a multilayer structure containing the same. Said ethylene-vinyl alcohol copolymer composition includes an ethylene-vinyl alcohol copolymer, an antioxidant, and a fluorine-containing compound; and the ratio of the antioxidant content to the fluorine content is 0.5 to 65. Thereby, the film containing said ethylene-vinyl alcohol copolymer composition not only has good heat resistance, but also can avoid the situation that a large number of gels are generated during the preparation process.
High strength polyvinylidene fluoride composite
The invention relates to fluoropolymer composites having a fluoropolymer matrix containing a functionalized fluoropolymer composition, and reinforced with fibers. The fibers can be chopped fibers, long fibers, or a mixture thereof, and the fluoropolymer matrix preferably is based on polyvinylidene fluoride. Any type of fibers, sized or unsized may be used with the functionalized fluoropolymer matrix composition to form the fluoropolymer composite.