A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A copolymer may be obtained by polymerization reaction(s) using an anionic monomer and two polyethoxylated monomers. Such copolymers may have a polydispersity index, determined by size exclusion chromatography (SEC), of less than 3, and be obtained by at least one radical polymerisation reaction in water at a temperature ranging from 10 to 90° C. A composition may include such copolymers. Such copolymers may be prepared and use as a superplasticizer for a hydraulic binder composition.

A copolymer may be obtained by polymerization reaction(s) using an anionic monomer and two polyethoxylated monomers. Such copolymers may have a polydispersity index, determined by size exclusion chromatography (SEC), of less than 3, and be obtained by at least one radical polymerisation reaction in water at a temperature ranging from 10 to 90° C. A composition may include such copolymers. Such copolymers may be prepared and use as a superplasticizer for a hydraulic binder composition.

A polyvinyl alcohol-based resin composition including a modified vinyl alcohol-based polymer (A) in which a polyoxyalkylene unit represented by a general formula (I) is bonded to a polyvinyl alcohol chain and a modified vinyl alcohol-based polymer (B) having a double bond in a polyvinyl alcohol chain.

##STR00001##

(In which: R.sub.1 and R.sub.2 are independently, a methyl group, an ethyl group or a hydrogen atom, and R.sub.3 is an alkyl group or a hydrogen atom. N represents a number of repeating units and is an integer of 5≤n≤70.)

A polyvinyl alcohol-based resin composition including a modified vinyl alcohol-based polymer (A) in which a polyoxyalkylene unit represented by a general formula (I) is bonded to a polyvinyl alcohol chain and a modified vinyl alcohol-based polymer (B) having a double bond in a polyvinyl alcohol chain.

##STR00001##

(In which: R.sub.1 and R.sub.2 are independently, a methyl group, an ethyl group or a hydrogen atom, and R.sub.3 is an alkyl group or a hydrogen atom. N represents a number of repeating units and is an integer of 5≤n≤70.)

Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.

Provided in this patent disclosure are two types of novel fluoro-monomers that can be polymerized for the fabrication of ion-exchange fluoropolymers. In addition, new proton-conductive zirconium-perfluorophosphonic acid fluoropolymer membranes that can reduce metal crossovers in redox flow batteries are also provided.

A monomer composition containing an unsaturated polyalkylene glycol ether-based monomer is provided having excellent stability. The monomer composition contains an unsaturated polyalkylene glycol ether-based monomer represented by the following chemical formula (1):
YO(R.sup.1O).sub.nR.sup.2  (1)
[in the formula, Y represents an alkenyl group having 2 to 7 carbon atoms; R.sup.1O represents one or two or more types of oxyalkylene groups having 2 to 18 carbon atoms; n represents an average addition mole number of oxyalkylene groups and is a number of 5 to 500; and R.sup.2 represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms], an organic acid, and water, and having a pH of 4 to 13.

The present invention relates to water-soluble hydrophobically associating copolymers which are obtained in the presence of a nonpolymerizable surface-active compound and which comprise novel hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether block, the polyether block comprising a hydrophilic polyethyleneoxy block and a hydrophobic polyalkyleneoxy block consisting of alkyleneoxy units having at least 4 carbon atoms. The monomers may optionally have a terminal polyethyleneoxy block. The invention further relates to processes for preparing the copolymers and to the use thereof.