A curable composition which comprises (A) an organopolysiloxane represented by formula (1)

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(wherein R.sup.1 represents an alkyl group, R.sup.2 represents an alkyl or aryl group, R.sup.3 represents a hydrogen atom or methyl group, Me represents a methyl group, m is an integer of 1-10, and a and b are integers of 1 or larger, a+b being an integer of 3-120), (B) a photopolymerization initiator, and (C) a hydrosilylation catalyst and which has a surface tension at 23° C. of 23-30 mN/m and a viscosity at 23° C. of 5-80 mPa.Math.s.

There are provided a photosensitive resin composition, a cured product thereof, and a wiring structure body, an electronic component, a semiconductor device, and a camera module each including the cured product. This photosensitive resin composition is cured by irradiation with active energy rays, instead of by heat treatment at high temperatures. In this photosensitive resin composition, film loss after a development process is restrained. Furthermore, a miniaturized pattern can be accurately formed by photolithography. An aspect of the present invention is a photosensitive resin composition including components (A) to (C): (A) a modified polyphenylene ether represented by formula (1) and formula (2), (B) a silsesquioxane compound represented by formula (3), and (C) a photopolymerization initiator, a cured product thereof, and a wiring structure body, an electronic component, a semiconductor device, and a camera module each including the cured product.

Described herein are wound dressing comprising a silicone hydrogel composition and optionally an antimicrobial agent, and methods of making and use thereof. The silicone hydrogel compositions comprise an actinically-crosslinkable polysiloxane-polyglycerol block copolymer crosslinked with a crosslinker. The actinically-crosslinkable polysiloxane-polyglycerol block copolymer being derived from: a polysiloxane prepolymer comprising a polyglycerol side chain, the polyglycerol side chain comprising an ethylenically unsaturated group covalently linked thereto, wherein the ethylenically unsaturated group is actinically curable.

This invention relates to a coating comprising prepolymer and monomers for application onto polyurethane for chemical resistance, abrasion resistance, water proof etc. Usually polyurethane is porous and does not have sufficient stain, abrasion and chemical resistance. The said coatings developed using technology of chemical grafting that involves the use of prepolymers, monomers, catalyst, graft initiator, wetting agents, fillers and other ingredients of the composition. The coating thus obtained when applied on the polyurethane allows obtaining graft polymerization, thereby forming a polymeric film chemically attached to the substrate. The polyurethane substrate is reacted with craft initiator which creates the reaction sites on the substrate via free radical mechanism. This in turn renders the substrate receptive to attachment of monomers/prepolymers forming polymeric film that is chemically bonded to the substrate which has then the desired property in terms of stain resistance, abrasion wear, crock, water, chemical resistance and other properties.

This invention relates to a coating comprising prepolymer and monomers for application onto polyurethane for chemical resistance, abrasion resistance, water proof etc. Usually polyurethane is porous and does not have sufficient stain, abrasion and chemical resistance. The said coatings developed using technology of chemical grafting that involves the use of prepolymers, monomers, catalyst, graft initiator, wetting agents, fillers and other ingredients of the composition. The coating thus obtained when applied on the polyurethane allows obtaining graft polymerization, thereby forming a polymeric film chemically attached to the substrate. The polyurethane substrate is reacted with craft initiator which creates the reaction sites on the substrate via free radical mechanism. This in turn renders the substrate receptive to attachment of monomers/prepolymers forming polymeric film that is chemically bonded to the substrate which has then the desired property in terms of stain resistance, abrasion wear, crock, water, chemical resistance and other properties.

A resin composition, wherein a resin component in the resin composition has a group represented by the following General Formula (11), (21) or (31) and a urethane bond:

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(in the formulae, Z.sup.1 is an alkyl group, and one or more hydrogen atoms in the alkyl group may be substituted with a cyano group, a carboxy group or a methoxycarbonyl group, and two or more of the substituents may be the same as or different from each other; Z.sup.2 is an alkyl group; Z.sup.3 is an aryl group; R.sup.4 is a hydrogen atom or a halogen atom; and the bond with the symbol * is formed with the bonding destination of the group represented by General Formula (11), (21) or (31)).

A resin composition, wherein a resin component in the resin composition has a group represented by the following General Formula (11), (21) or (31) and a urethane bond:

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(in the formulae, Z.sup.1 is an alkyl group, and one or more hydrogen atoms in the alkyl group may be substituted with a cyano group, a carboxy group or a methoxycarbonyl group, and two or more of the substituents may be the same as or different from each other; Z.sup.2 is an alkyl group; Z.sup.3 is an aryl group; R.sup.4 is a hydrogen atom or a halogen atom; and the bond with the symbol * is formed with the bonding destination of the group represented by General Formula (11), (21) or (31)).

A hydrophilic silicone particle containing a surfactant fixed by a chemical bond formed by radical polymerization to a surface of a silicone particle having a volume average particle size of 0.1 to 100 μm and a method for producing the hydrophilic silicone particle, the method including fixing a hydrophilic group derived from a component (B) to a surface of a silicone particle by subjecting an emulsion to radical polymerization, the emulsion containing: (A) 100 parts by mass of an organopolysiloxane having a radical polymerization reactive group; (B) 0.5 to 50 parts by mass of a surfactant having a radical polymerization reactive group; (C) 0.1 to 5 parts by mass of a radical generator; and (D) 10 to 1000 parts by mass of water. A silicone particle may be readily dispersed in an aqueous material without the additional use of a dispersant (typically, a surfactant) and has a hydrophilic group.

A silicone particle containing: a dialkylsiloxane unit represented by the following general formula (1), R.sup.4.sub.2SiO.sub.2/2 (1), where, in the formula (1), R.sup.4s each independently represent a monovalent hydrocarbon group having 1 to 6 carbon atoms; and a poly(alkyleneoxyalkyl)methylsiloxane unit represented by the following general formula (2), where, in the formula (2), R.sup.1s each independently represent a hydrogen atom or a monovalent hydrocarbon group having 1 to 6 carbon atoms, R.sup.2s each independently represent a divalent aliphatic group having 1 to 6 carbon atoms, and “n” is a number that satisfies 1≤n≤20, where the silicone particle has an oxyalkylene group in a surface thereof. A silicone particle may be readily dispersed in an aqueous material without the use of a dispersant or a surfactant, the silicone particle having a hydrophilic group.

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The phosphorylcholine group-containing polysiloxane monomer of the present invention is represented by the formula (1). In the formula, a represents an integer of 20 to 500, b represents an integer of 1 to 70, c represents an integer of 1 to 70, d represents 0 or 1, p and q each represent 0 or 1, X represents —CH.sub.2— or —CH.sub.2CH.sub.2—, and R represents an alkyl group having 2 to 18 carbon atoms. The present invention provides the phosphorylcholine group-containing polysiloxane monomer which gives, when copolymerized with a polymerizable monomer such as methacrylic acid or a hydrophilic monomer other than methacrylic acid, a polymer that exhibits surface hydrophilicity and sufficient stability as ophthalmic devices.