A no bake process is provided for preparing a foundry shape. A major amount of an appropriate foundry aggregate, especially a sand that has been mechanically-reclaimed, is mixed with an amount of halloysite tubes. A binder system, especially a water-based binder, such as an aqueous alkaline phenolic resole resin, is added to the mixed aggregate and halloysite, and a liquid co-reactant for curing the binder is also added. By intimately mixing the components, a foundry molding compound is formed and it can be placed into a mold or patter to cure into a foundry shape. When removed from the mold or pattern, the foundry shape can be used to cast molten metal.

A no bake process is provided for preparing a foundry shape. A major amount of an appropriate foundry aggregate, especially a sand that has been mechanically-reclaimed, is mixed with an amount of halloysite tubes. A binder system, especially a water-based binder, such as an aqueous alkaline phenolic resole resin, is added to the mixed aggregate and halloysite, and a liquid co-reactant for curing the binder is also added. By intimately mixing the components, a foundry molding compound is formed and it can be placed into a mold or patter to cure into a foundry shape. When removed from the mold or pattern, the foundry shape can be used to cast molten metal.

This invention relates to aminoplast crosslinker resins compositions based on at least partially alkylated reaction products A of melamine, formaldehyde and an alkanol with the following parameters: the ratio of the amount of substance n(CH.sub.2O) of combined formaldehyde to the amount of substance n(Mel) of melamine is in the range of from 5.6 mol/mol to 6.2 mol/mol, the ratio of the amount of substance n(RO) of alkyl ether groups in the crosslinker resin to the amount of substance n(Mel) of melamine is in the range of from 5.0 mol/mol to 5.6 mol/mol, the mass fraction of monomer in the resin, calculated as the ratio of the mass of monomer m(1) to the mass m(A) of the reaction products A is between 35% and 55%, to a process for their preparation, and to a method of use thereof as crosslinker in combination with hydroxy-functional polymers for coating of heat-sensitive substrates.

Provided is an addition condensation product of an aromatic compound and a carbonyl compound. The addition condensation product includes an aromatic compound dimer in which two composition units derived from the aromatic compounds are bonded via one composition unit derived from the carbonyl compound and an aromatic compound multimer in which each of three or more composition units derived from the aromatic compounds is bonded via one composition unit derived from the carbonyl compound. A ratio of the aromatic compound dimer to the aromatic compound multimer is in the range of 1:75 to 1:1,000.

A production method of an addition condensation product includes a step at which an aromatic compound, a carbonyl compound, and a catalyst are mixed in a reaction solvent, and an addition condensation reaction of the aromatic compound and the carbonyl compound is conducted in the temperature range of 60 to 97° C., both inclusive, to obtain the addition condensation product of the aromatic compound and the carbonyl compound. At the step to obtain the addition condensation product, 1 mole of the aromatic compound is mixed with 0.1 to 0.999 mole, both inclusive, of the carbonyl compound as the mole ratio. A ratio of the aromatic compound dimer to the aromatic compound multimer is in the range of 1:75 to 1:1,000.

Provided is an addition condensation product of an aromatic compound and a carbonyl compound. The addition condensation product includes an aromatic compound dimer in which two composition units derived from the aromatic compounds are bonded via one composition unit derived from the carbonyl compound and an aromatic compound multimer in which each of three or more composition units derived from the aromatic compounds is bonded via one composition unit derived from the carbonyl compound. A ratio of the aromatic compound dimer to the aromatic compound multimer is in the range of 1:75 to 1:1,000.

The present invention has an object to provide a new compound that is useful as a film forming material for lithography or an optical component forming material, a resin containing a constituent unit derived from said compound, a composition, a resist pattern formation method, a circuit pattern formation method, and a purification method.

A compound represented by formula (1), a resin containing a constituent unit derived from said compound, a composition containing one or more selected from the group consisting of said compound and said resin, a resist pattern formation method using said composition, a circuit pattern formation method, and a purification method thereof.

A composition for film formation containing a polycyclic polyphenolic resin having repeating units derived from at least one monomer selected from the group consisting of aromatic hydroxy compounds represented by the following formulae (1A) and (1B), wherein the repeating units are linked to each other by a direct bond between aromatic rings.

##STR00001##

(In the formula (1A), X represents an oxygen atom, a sulfur atom, a single bond, or non-crosslinked state and Y represents a 2n-valent group having 1 to 60 carbon atoms, or a single bond, wherein when X is non-crosslinked state, Y represents the 2n-valent group; in the formula (1B), A represents a benzene ring or a fused ring; in the formulas (1A) and (1B), each R.sup.0 is independently an alkyl group having 1 to 40 carbon atoms and optionally having a substituent, an aryl group having 6 to 40 carbon atoms and optionally having a substituent, an alkenyl group having 2 to 40 carbon atoms and optionally having a substituent, an alkynyl group having 2 to 40 carbon atoms, an alkoxy group having 1 to 40 carbon atoms and optionally having a substituent, a halogen atom, a thiol group, or a hydroxy group, wherein at least one R.sup.0 is a hydroxy group, and each m is independently an integer of 1 to 9; and N is an integer of 1 to 4, and each p is independently an integer of 0 to 3.)

The formaldehyde-free binder for materials containing cellulose contains a hydroxy aldehyde resin polycondensed with an ammonium salt, the resin being obtained, in especially preferred embodiments, from glycerin, in situ, with the aid of hydrogen peroxide. A protein component consisting of animal blood is added. The binder is urea-free and can be used as a one-component or two-component binder. It binds materials such as wood, paper and other natural fibres to form high-quality composite material products.

An admixture for a hydraulic composition includes a polycondensation product P containing a copolymer prepared by polycondensation of a monomer mixture containing compounds A to C of the following Formulae (A) to (C); and a polycarboxylic acid-based polymer Q including a structural unit having an amino and an imino group, and/or a structural unit having an amino, imino, and amido group: ##STR00001## (wherein R.sub.1 is a hydrogen atom, alkyl, or alkenyl group; A.sub.1O is a C.sub.2-4 alkylene oxide group; p is a number of 1 to 300; and X is a hydrogen atom, an alkyl, or acyl group; R.sub.2 is an alkyl or alkenyl group; A.sub.2O is a C.sub.2-4 alkylene oxide group; q is a number of 1 to 300; and Y.sub.1 is a phosphate ester group; and R.sub.3 is a hydrogen atom, carboxy, alkyl, alkenyl, phenyl, naphthyl, or heterocyclic group; and r is a number of 1 to 100).