There are provided a carbodiimide compound excellent in storage stability, and performance as a crosslinking agent, and a method for producing the same, and a resin composition excellent in the film forming properties and solvent resistance of a coating made at low temperature. A polycarbodiimide compound derived from an aliphatic diisocyanate compound having at least one primary isocyanate group, the polycarbodiimide compound having a structure in which all ends are capped with an organic compound having a functional group that reacts with an isocyanate group, carbodiimide group concentration A (%) and weight average molecular weight Mw satisfying the following formula (1), and a resin composition comprising the carbodiimide compound and an aqueous resin having a predetermined acid value at a predetermined ratio.
(A/Mw)×1000≥0.55  (1).

A continuous process for producing a polyurea concentrate or powder. The process includes combing at least one amine and an isocayante in the presence of a liquid diluent or a base oil in a rotor stator mixer. The concentrate comprises a polyurea in a base oil wherein the concentration of from about 20 weight percent to about 50, or 40 or 35 or 30 weight percent of polyurea based on total weight of grease thickener. The powder has particle size of 2 to 400 microns. This concentrate or powder can then be formulated by grease manufacturers to the desired final properties without the need for handling of the isocyanate and amine raw materials.

There is provided a compatibilizer for polyester resin which can produce better compatibility than conventional counterparts, and a polyester resin composition using the compatibilizer. The compatibilizer comprises a polycarbodiimide compound represented by the formula (1) describe below wherein the carbodiimide equivalent of the polycarbodiimide compound is 280 or higher; and in the formula (1), R.sup.1 and R.sup.2 are residues formed by eliminating a functional group from an organic compound having the one functional group reactive with an isocyanate group; R.sup.3 is a divalent residue formed by eliminating two isocyanate groups from a diisocyanate compound; R.sup.4 is a divalent residue formed by eliminating two hydroxyl groups from a diol compound; X.sup.1 and X.sup.2 are bonds formed by reaction of the functional group of the organic compound with one of the two isocyanate groups of the diisocyanate compound; and m and n=1 to 20, m+n≤25, and p=0 to 39, provided that the number of carbodiimide groups in one molecule is 2 to 40.

##STR00001##

Provided are a polycarbodiimide compound that enables an aqueous resin composition capable of forming a coating (layer) having water resistance and adhesion that can withstand use for food packaging to be obtained, an aqueous resin composition containing the polycarbodiimide compound, and a food packaging having a layer formed of the aqueous resin composition. A polycarbodiimide compound (A) represented by formula (1) below,

##STR00001##

wherein R.sup.1 represents a residue obtained by removing a functional group capable of reacting with isocyanate from a hydrophilic compound having the functional group capable of reacting with isocyanate, R.sup.2 represents a divalent residue obtained by removing an isocyanate group from an aliphatic diisocyanate compound, and R.sup.3 represents a divalent residue obtained by removing a hydroxyl group from a glycol compound having 2 or 3 carbon atoms; X represents a group that is formed by reaction between the hydrophilic compound and the aliphatic diisocyanate compound; n1 represents a number of 1 to 10, n2 represents a number of 1 to 10, and p represents a number of 2 to 4; and a plurality of R.sup.1 and R.sup.2 each may be the same or different.

A modified polycarbodiimide compound which is obtained by modifying at least some of carbodiimide groups in a polycarbodiimide derived from a diisocyanate compound, said polycarbodiimide having a terminal blocked with a hydrophilic compound, with an aromatic heterocyclic compound such as 3,5-dimethylpyrazole having endocyclic secondary amine nitrogen has a potential for a cuing agent, and exhibits the activity of the carbodiimide groups by being unblocked at relatively low temperatures.

A method for producing a carbodiimide compound, comprising a carbodiimide production step of reacting an aliphatic tertiary isocyanate compound (A) in the presence of an organic alkali metal compound (B) having Lewis basicity.

Coated packages and methods for coating such packages is disclosed The coating compositions comprise a carboxyl-containing polymer and a polycarbodiimide.

A continuous process for producing a polyurea concentrate or powder. The process includes combing at least one amine and an isocayante in the presence of a liquid diluent or a base oil in a rotor stator mixer. The concentrate comprises a polyurea in a base oil wherein the concentration of from about 20 weight percent to about 50, or 40 or 35 or 30 weight percent of polyurea based on total weight of grease thickener. The powder has particle size of 2 to 400 microns. This concentrate or powder can then be formulated by grease manufacturers to the desired final properties without the need for handling of the isocyanate and amine raw materials.

The present invention provides a polyisocyanate composition wherein the composition is obtained from an aliphatic diisocyanate unit including 1,6-diisocyanatohexane, and has an isocyanurate group, a uretdione group, a uretonimine group, and an iminooxadiazinedione group, and the molar ratio of the uretonimine group to the isocyanurate group is 0.0010 to 0.0050, and the molar ratio of the iminooxadiazinedione group to the isocyanurate group is 0.00050 to 0.30.

A continuous process for producing a polyurea concentrate or powder. The process includes combing at least one amine and an isocyanate in the presence of a liquid diluent or a base oil in a rotor stator mixer. The concentrate comprises a polyurea in a base oil wherein the concentration of from about 20 weight percent to about 50, or 40 or 35 or 30 weight percent of polyurea based on total weight of grease thickener. The powder has particle size of 2 to 400 microns. This concentrate or powder can then be formulated by grease manufacturers to the desired final properties without the need for handling of the isocyanate and amine raw materials.