Polymers containing halogen functionality are prepared by the addition or condensation polymerization of at least one halogenated reactant containing at least two active hydrogen-containing functional groups per molecule and at least one halogenated heteroalkyl or halogenated heteroalkenyl group per molecule and at least one co-reactant containing at least two functional groups reactive with the active hydrogen groups of the at least one halogenated reactant.

The present invention relates to processes for the manufacture of aqueous polyurethane/acrylic hybrid dispersions that can be used as adhesives or coatings, are solvent free and have low VOC emissions, and are environmentally friendly. Also encompassed are the dispersions as such, compositions containing them and their use as coatings and adhesives.

A process for preparing halogen-containing polyoxyalkylenepolyols, comprising the step of reacting an alkylene oxide with carbon dioxide in the presence of an H-functional starter compound and of a double metal cyanide catalyst, wherein the reaction is also conducted in the presence of an α,β-epoxy-γ-haloalkane.

Two-component formulation for producing open-cell flexible foams having compressive strength of 1N/cm.sup.2, contained in 2-component aerosol can with crosslinker sleeve which can be opened prior to deploying formulation from aerosol can wherein the contents thereof enter aerosol can, wherein first component is present in aerosol can and second component that is reactive to first component is present separately in crosslinker sleeve and wherein aerosol can includes prepolymer composed of 25-35% by weight MDI and 40-55% by weight of polyol mixture having free isocyanate groups, and 10-21% by weight of propellant gas mixture and crosslinker sleeve includes 4-10% by weight of crosslinker mixture, wherein weight data are based on weight of formulation. Polyol mixture includes at least one trifunctional polyether and bifunctional polyester polyols, together with flame retardant, foam stabilizer, cell opener, amine catalyst, and crosslinker mixture including ethylene glycol in deficiency relative to free isocyanate groups and amine catalyst.

Polymers containing halogen functionality are prepared by the addition or condensation polymerization of at least one halogenated reactant containing at least two active hydrogen-containing functional groups per molecule and at least one halogenated heteroalkyl or halogenated heteroalkenyl group per molecule and at least one co-reactant containing at least two functional groups reactive with the active hydrogen groups of the at least one halogenated reactant.

This present disclosure relates to a two-component polyurethane composition comprising: (A) a prepolymer component comprising: (i) at least one isocyanate terminated intermediate compound prepared from a reaction mixture comprising at least one isocyanate compound and at least one active hydrogen containing compound selected from the group consisting of a polyol compound, a polyamine compound and a combination thereof, (ii) at least one isocyanate compound, and (iii) optionally at least one liquid rubber; and (B) a curative component comprising: (i) at least one polyol terminated intermediate compound prepared from a reaction mixture comprising at least one isocyanate compound and at least one active hydrogen containing compound selected from the group consisting of a polyol compound, a polyamine compound and a combination thereof, (ii) at least one liquid rubber, (iii) at least one catalyst, (iv) at least one polyol, (v) optionally at least one amine compound, and (vi) optionally a chain extender.

Two-component formulation for producing open-cell flexible foams having compressive strength of 1N/cm.sup.2, contained in 2-component aerosol can with crosslinker sleeve which can be opened prior to deploying formulation from aerosol can wherein the contents thereof enter aerosol can, wherein first component is present in aerosol can and second component that is reactive to first component is present separately in crosslinker sleeve and wherein aerosol can includes prepolymer composed of 25-35% by weight MDI and 40-55% by weight of polyol mixture having free isocyanate groups, and 10-21% by weight of propellant gas mixture and crosslinker sleeve includes 4-10% by weight of crosslinker mixture, wherein weight data are based on weight of formulation. Polyol mixture includes at least one trifunctional polyether and bifunctional polyester polyols, together with flame retardant, foam stabilizer, cell opener, amine catalyst, and crosslinker mixture including ethylene glycol in deficiency relative to free isocyanate groups and amine catalyst.

Described herein are fire-resistant one-component polyurethane spray foam compositions. Also described herein are methods of making and using fire-resistant one-component polyurethane spray foam compositions. Also described herein are dispensers for dispensing the fire-resistant one-component polyurethane spray foam compositions. Compositions and methods in accordance with the present disclosure are useful in a wide variety of applications, and particularly useful in meeting building codes for construction applications.