A composition including at least one compound having a perfluoropolyether group and a curable site, wherein in a molecular weight distribution curve in gel permeation chromatography measurement, the following formula is satisfied: M2/M1≤3.5, wherein M1 is a molecular weight at a main peak, and M2 is a molecular weight at 25% intensity of an intensity of the main peak on a higher molecular weight side than M1. Also disclosed is a curable composition containing the composition and a method for producing the curable composition.

Application of a Mannich base in a flame-retardant polyurethane material is provided. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol, giving the synthesized polyether polyol good flame retardance. The amount of active hydrogen in the Mannich base is small so that occurrence of side reactions during the synthesis of the polyether polyol is reduced, and the viscosity of the flame-retardant polyether polyol is lowered. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis. A preparation method of the Mannich base is also provided.

A flame-retardant polyether polyol is provided, including a Mannich base and an epoxide. The epoxide is selected from ethylene oxide, propylene oxide and butylene oxide. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol. The amount of active hydrogen in the Mannich base is small so that side reactions during synthesis of the polyether polyol are reduced, and the viscosity of the polyether polyol is lowered. A flame-retardant polyurethane material is also provided, synthesized from raw materials comprising the above-mentioned flame-retardant polyether polyol and an isocyanate. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis.

A composition including at least one compound having a perfluoropolyether group and a curable site, wherein in a molecular weight distribution curve in gel permeation chromatography measurement, the following formula is satisfied: M2/M1≤3.5, wherein M1 is a molecular weight at a main peak, and M2 is a molecular weight at 25% intensity of an intensity of the main peak on a higher molecular weight side than M1. Also disclosed is a curable composition containing the composition and a method for producing the curable composition.

A flame-retardant polyether polyol is provided, including a Mannich base and an epoxide. The epoxide is selected from ethylene oxide, propylene oxide and butylene oxide. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol. The amount of active hydrogen in the Mannich base is small so that side reactions during synthesis of the polyether polyol are reduced, and the viscosity of the polyether polyol is lowered. A flame-retardant polyurethane material is also provided, synthesized from raw materials comprising the above-mentioned flame-retardant polyether polyol and an isocyanate. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis.

Application of a Mannich base in a flame-retardant polyurethane material is provided. The Mannich base has a structure represented by a formula (I). In the Mannich base, flame-retardant groups, i.e., halogens are introduced at the second, fourth and sixth positions of a phenyl group, and flame-retardant elements, i.e., halogens and nitrogen are introduced into synthesized polyether polyol, giving the synthesized polyether polyol good flame retardance. The amount of active hydrogen in the Mannich base is small so that occurrence of side reactions during the synthesis of the polyether polyol is reduced, and the viscosity of the flame-retardant polyether polyol is lowered. Due to autocatalytic performance of tertiary amido in the flame-retardant polyether polyol, use of a catalyst can be reduced and even avoided during the synthesis. A preparation method of the Mannich base is also provided.

A compound having the formula:

##STR00001## wherein n, y, R.sub.1 and R.sub.2 are defined herein, and others, methods of making of and using, and compositions made thereby which have an antimicrobial resistance effect are described.

A compound having the formula: ##STR00001## wherein n, y, R.sub.1 and R.sub.2 are defined herein, and others, methods of making of and using, and compositions made thereby which have an antimicrobial resistance effect are described.

Provided are a surface-modifying agent that enables production of a coating film that preserves transparency of a substrate while displaying high water repellency and excellent stain resistance, particularly in terms of wipeability of oil-based ink, and also an article for which the surface-modifying agent is used. The surface-modifying agent includes a triazine skeleton, a (meth)acrylate group bonded to the triazine skeleton via an urethane bond, and a perfluoropolyether chain bonded to the triazine skeleton.

A compound having the formula:

##STR00001## wherein n, y, R.sub.1 and R.sub.2 are defined herein, and others, methods of making of and using, and compositions made thereby which have an antimicrobial resistance effect are described.