The present invention is directed to a process for preparing light curable energetic polymeric binders. The process for preparing such binder comprises the steps of mixing a pre-polymer such as PGN or GAP having a terminal hydroxyl group with a solvent and adding reactants wherein the reactant has a light curable moiety and a pre-polymer reactive moiety. Catalysts such as carbodiimide and DMAP may be further added to the mixture.

Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, and a certain 3-oxopropanamide compound. Foams so produced emit low levels of aldehydes.

A two-component solventless adhesive composition including: (A) at least one isocyanate component formulated for application to a first substrate comprising either at least one aromatic-based isocyanate, or a blend of: (Ai) at least one aromatic-based isocyanate; and (Aii) at least one aliphatic-based isocyanate; and (B) at least one isocyanate-reactive component formulated for application to a second substrate comprising a blend of: (Bi) at least one amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines; (Bii) at least one hydroxyl terminated polyurethane polyol; (Biii) at least one phosphate ester polyol; (Biv) at least one polyester polyol; (Bv) at least one polyether polyol and (Bvi) optionally, at least one silane adhesion promoter; and a process for preparing the above two-component solventless adhesive composition; and a laminate structure made using the above two-component solventless adhesive composition.

A two-component solventless adhesive composition including: (A) at least one isocyanate component formulated for application to a first substrate comprising either at least one aromatic-based isocyanate, or a blend of: (Ai) at least one aromatic-based isocyanate; and (Aii) at least one aliphatic-based isocyanate; and (B) at least one isocyanate-reactive component formulated for application to a second substrate comprising a blend of: (Bi) at least one amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines; (Bii) at least one hydroxyl terminated polyurethane polyol; (Biii) at least one phosphate ester polyol; (Biv) at least one polyester polyol; (Bv) at least one polyether polyol and (Bvi) optionally, at least one silane adhesion promoter; and a process for preparing the above two-component solventless adhesive composition; and a laminate structure made using the above two-component solventless adhesive composition.

The present invention is directed to polyol composition comprising a polyol mixture (PM) comprising a polyetherol (P1) based on a polyhydric alcohol and a polyetherol (P2) based on a diamine; and at least one hydrohaloolefin (HFO) as blowing agent, a process for preparing a polyurethane foam using said polyol composition and the polyurethane foam obtained or obtainable by said process.

Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, and a certain 3-oxopropanamide compound. Foams so produced emit low levels of aldehydes.

The present invention is directed to polyol composition comprising a polyol mixture (PM) comprising a polyetherol (P1) based on a polyhydric alcohol and a polyetherol (P2) based on a diamine; and at least one hydrohaloolefin (HFO) as blowing agent, a process for preparing a polyurethane foam using said polyol composition and the polyurethane foam obtained or obtainable by said process.