A method for producing a polyurethane polymer comprises the steps of: (a) providing a polyol composition, the polyol composition comprising (i) a polyol, (ii) a polyethylenimine compound; and (iii) a bisulfite compound, (b) providing an isocyanate compound; (c) providing a catalyst; (d) combining and reacting the polyol composition, the isocyanate compound, and the catalyst to produce a polyurethane polymer.

A flexible discontinuous process produces a series of at least two articles containing thermally insulating polyurethane foam from at least three streams (A), (B) and (C). The process involves mixing the at least three streams with different mixing ratios and injecting the mixture into cavities of the articles. A production unit can be used for performing this process.

Polymer polyols (“PMPOs”), processes for their production, and the use of such PMPOs, particularly in the production of flexible polyurethane foams. The PMPOs are produced using an ethylenically unsaturated composition that includes a crosslinker that results in crosslinks in the PMPO polymer particles that may decompose when exposed to flame temperatures. The PMPOs is capable of providing a flexible polyurethane foam that may exhibit combustibility resistance properties.

The subject application relates to polyurethane foam and methods of forming the same. A polyurethane foam may include a polyurethane foam may include a first polyol component, a second polyol component, and a third polyol component. The first polyol component may include at least one component selected from the group of a polyether polyol and a polyester polyol. The second polyol component may include a polyether polyol. The third polyol component may include a grafted polyether polyol. The polyurethane foam may have a density of at least about 100 kg/m.sup.3 and not greater than about 800 kg/m.sup.3. The polyurethane foam may have an adjusted compression force deflection to density ratio of at least about 0.3.

The present disclosure relates to a foam layer that may include a silicone based matrix component, a flame retardant filler component, and an insulation filler component. The foam layer may have a thickness of at least about 0.5 mm and no greater than about 10 mm. The foam layer may further have a compression force deflection at 25% of at least about 5 kPa and not greater than about 500 kPa. The foam layer may also have a HBF flammability rating as measured according to ASTM D4986.

To provide a polyether polyol having a high degree of freedom in the design of a polyurethane foam, and capable of providing a polyol system solution excellent in storage stability. A polyether polyol having a polyoxyalkylene chain consisting of oxyalkylene units, and having a degree of unsaturation of at most 0.020 meq/g, a hydroxy value of from 1 to 80 mgKOH/g, a content of oxyethylene units of from 0 to 50 mass %, and a content of ultra-high molecular weight components which have molecular weights of from 12 to 46 times the number average molecular weight of at most 1,000 mass ppm. The number average molecular weight is a molecular weight as calculated as polystyrene measured by gel permeation chromatography (GPC) method, and the content of ultra-high molecular weight components is a value measured by high performance liquid chromatography (HPLC) method using a charged aerosol detector (CAD).

Polyurethane foams that are hydrophilic but nonetheless have low compression sets are made from a combination of MDI and TDI prepolymers, water, and a polymer polyol. The foams optionally are made incorporating a phase change material in the foam formulation. The phase change material does not require encapsulation.

This invention relates to novel macromers that comprise a polyether polyol having (meth)acrylate unsaturation. These novel macromers are the polymerization product of a glycidyl (meth)acrylate, with a polyether polyol, and optionally, an alkylene oxide, in the presence of a double metal cyanide catalyst. This invention also relates to preformed stabilizers prepared from these macromers, and to polymer polyols prepared from these novel macromers and novel preformed stabilizers. The present invention also relates to processes for preparing these compositions, to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

Processes for producing filled polyol compositions, such as polymer polyol compositions. The processes include reacting a polymerizable composition in the presence of a composition comprising a base polyol and an amine antioxidant, in which the amine antioxidant comprises a secondary diarylamine, a primary aromatic amide, a triazole, or a combination thereof.

Polyether polyols are prepared by polymerizing unsaturated monomers in a continuous phase of a base polyol. A macromer or polymerization produce of such a macromer is present during the polymerization to stabilize the polymer particles as they form. The macromer is a polyether capped with certain unsaturated epoxide compounds.