The present specification relates to a polymer including a first unit of Chemical Formula 1; a second unit of Chemical Formula 2; and a third unit of Chemical Formula 3 or 4, and an organic solar cell including the same.

Disclosed are an electroluminescent polymer based on phenanthroimidazole units, a preparation method therefor, and the use thereof. The electroluminescent polymer based on phenanthroimidazole units has a structure as shown in the formula (I), and the side chain thereof contains phenanthroimidazole units. The electroluminescent polymer (1) has the properties of hybridized local and charge-transfer states, which can improve the utilization of excitons and the electroluminescence properties of devices by means of reverse inter-system crossing to effectively utilize triplet state excitons; (2) the phenanthroimidazole unit has a large degree of conjugation and a strong rigidity, which can not only improve the thermal stability of a material, but can also increase the radiation transition rate of the material and improve the light-emitting efficiency thereof; and (3) the raw materials of the polymer are cheap, the synthetic route is simple, and purification is convenient, which is beneficial for industrial scaled-up production thereof. The polymer has a good solubility, and can be used to prepare large-area flexible display devices by means of a solution processing technology. The polymer has great development potential and prospects in the field of organic electronic display.

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The invention provides a photoinduced-nonlinear-expansion coordination polymer and preparation method thereof. The coordination polymer has a chemical formula of [Zn(iba)(tkpvb)Cl].sub.n1, wherein iba represents p-iodobenzoate, tkpvb represents 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene, and n=3000-60000; and crystallographic parameters of: (1) crystal system: monoclinic system; (2) space group: Cc; (3) a = 28.6156(16) Å, b = 7.2901(4) Å, c = 21.5157(13) Å, β = 127.430(4)°, and V = 3574.2(4) Å.sup.3; (4) Z = 4; and (5) F(000) = 1680, R.sub.1 = 0.1363, wR.sub.2 = 0.3788, and GOF = 1.620; wherein iba represents p-iodobenzoate, tkpvb represents 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene, and n1=3000-60000. The preparation method of the coordination polymer of the present invention is simple, and has mild reaction conditions, and fast light conversion rate. Moreover, the coordination polymer undergoes an addition reaction, exhibits the photoinduced nonlinear expansion performance of the material, and affords a corresponding isomeric compound under the irradiation of light of various wavelengths.

An anion exchange polymer includes aryl ether linkage free polyarylenes having aromatic/polyaromatic rings in polymer backbone and a tethered alkyl quaternary ammonium hydroxide side groups. This anion exchange polymer may be utilized in an anion exchange process and may be made into a thin anion transfer membrane. An ion transfer membrane may be mechanically reinforced having one or more layers of functional polymer based on a terphenyl backbone with quaternary ammonium functional groups and an inert porous scaffold material for reinforcement. An anion exchange membrane may have multilayers of anion exchange polymers which each containing varying types of backbones, varying degrees of functionalization, or varying functional groups to reduce ammonia crossover through the membrane.

There is a polymeric photovoltaic cell (or solar cell) with inverted structure having an anode; an anodic buffer layer; an active layer having at least one photoactive organic polymer as electron-donor and at least one electron-accepting organic compound; a cathodic buffer layer; and a cathode. The at least one photoactive organic polymer is selected from conjugated polymers comprising an anthraditiophenic derivative having a general formula (I):

##STR00001##

The polymeric photovoltaic cell (or solar cell) with inverted structure shows good values of power conversion efficiency (PCE) (η) and can be advantageously used in the construction of photovoltaic modules (or solar modules), either on a rigid support or on a flexible support.

A polymer and a light-emitting device employing the same are provided. The polymer includes a first repeat unit with a structure represented by Formula (I):

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wherein the definitions of R.sup.1, R.sup.2, A.sup.1, A.sup.2, A.sup.3, and Z.sup.1 and n are as defined in the specification. At least one of A.sup.1, A.sup.2, and A.sup.3 is not hydrogen.

The present application relates to a photoactive composition comprising a blend of polymers. The present application further relates to an organic photovoltaic cell or an organic photodetector comprising a photoactive layer consisting of said photoactive composition.

The present invention relates to the field of hydrogen energy, and more particularly to an anion-conducting polyelectrolyte comprising an amide group, a preparation method and application thereof. The method includes: polymerizing aromatic hydrocarbons and ketone comprising amide group by superacid catalysis, forming a membrane by a casting method, performing the membrane prepared under alkaline conditions to obtain the anion-conducting polyelectrolytes comprising amide group. The anion-conducting polyelectrolytes obtained have good solubility and excellent stability. It is a kind of high molecular polymer with excellent alkali stability with an amide structure on the backbone. After alkaline treatment, the polymer not only has high hydroxide conductivity, good mechanical properties, and thermal stability but also has excellent alkali stability and excellent performance of water electrolysis.

A resist composition including a compound (D0) represented by general formula (d0) and a resin component (A1) has a structural unit (a0) in which a compound represented by general formula (a0-1) has a polymerizable group within the W.sup.1 portion converted into a main chain (in formula (d0), Rd.sup.01 represents a fluorine atom or a fluorinated alkyl group; In formula (a0-1), W.sup.1 represents a polymerizable group-containing group; C.sup.t represents a tertiary carbon atom, and the α-position of C.sup.t is a carbon atom which constitutes a carbon-carbon unsaturated bond; R.sup.11 represents an aromatic hydrocarbon group; or a chain hydrocarbon group; R.sup.12 and R.sup.13 each independently represents a chain hydrocarbon group, or R.sup.12 and R.sup.13 are mutually bonded to form a cyclic group). ##STR00001##

A repeat unit comprising

##STR00001##

In the repeat unit, X.sub.1 and X.sub.2 are independently selected from the group consisting of: F, Cl, H, and combinations thereof. Additionally, in this monomer, R′ and R″ are independently selected from an alkyl group, an aryl group, or combinations thereof. Also, R.sub.3, and R.sub.4 are independently selected from unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.