A method for making a high temperature composite, which is a carbon carbon composite, carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or a carbon silica composite, including: a) providing a precursor part including a resin comprising a poly(aryl ether ketone) (PAEK) and at least one reinforcing material, wherein the resin has a degree of crystallinity of 10% or more; b) pyrolyzing the precursor part to a pyrolyzed part; c) infusing a liquid second resin into the pyrolyzed part to make an infused part; and d) pyrolyzing the infused part to make the carbon carbon composite carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or the carbon silica composite, optionally repeating steps c. through d. Also, a carbon carbon composite, carbon fiber reinforced ceramic matrix composite, ceramic fiber reinforced ceramic matrix composite, or carbon silica composite made by the method.

A resin composition containing: a melt-fabricable fluororesin containing at least one functional group selected from a carbonyl group-containing group and a hydroxy group; at least one fluorine-free resin selected from a liquid crystal polymer, a polyarylene sulfide, and an aromatic polyether ketone; and particulate boron nitride, wherein the particulate boron nitride is contained in an amount of 30 to 65% by volume.

A polymer composition comprising carbon nanostructures dispersed within a polymer matrix that includes a thermoplastic polymer having a deflection temperature under load of about 40° C. or more as determined in accordance with ISO 75:2013 at a load of 1.8 MPa and a melting temperature of about 140° C. or more is provided. The carbon nanostructures include carbon nanotubes that are arranged in a network having a web-like morphology and optionally disposed on a substrate.

The use of compatible, semi-miscible or miscible polymer compositions as support structures for the 3D printing of objects, including those made from polyether-block-amide copolymers such as PEBAX® block copolymers from Arkema, polyamides such as RILSAN® polyamides from Arkema, polyether ketone ketone such as KEPSTAN® PEKK from Arkema, and fluoropolymers, such a KYNAR® PVDF from Arkema, especially objects of polyvinylidene fluoride and its copolymers. One particularly useful miscible polymer is an acrylic polymer, which is miscible with the fluoropolymer in the melt. The support structure composition provides the needed adhesion to the build plate and to the printed object and support strength during the 3D printing process, yet it is removable after the fluoropolymer object has cooled. The support polymer composition is selected to be stiff and low warping, yet flexible enough to be formed into filaments.

The objective of the present invention is to provide a polyarylketone resin composition, a fiber-reinforced resin base material, and formed products therefrom having excellent thermal stability and mechanical properties. In order to achieve the above objective, the present invention has the following constitution. That is, the polyaryletherketone resin composition comprises (A) a polyaryletherketone and (B) a transition metal compound, wherein the transition metal content is between 0.001 parts by mass and 4 parts by mass inclusive with respect to 100 parts by mass of (A) the polyaryletherketone.

The present invention relates to a novel polyaryletherketone (PAEK) polymer composition with a significantly increased crystallization rate, and preferably, to a polyetherketoneketone (PEKK) polymer composition. According to the present invention, there is provided a polymer composition including a liquid crystal polymer (LCP), an inorganic nucleating agent, a reinforcing agent, and a filler in polyaryletherketone (PAEK). Therefore, the present invention provides an effect of improving a crystallization rate of the polymer composition and improving molding processability, thereby improving productivity, shape, dimensional stability, or the like of products.

A reactive oligomer has a backbone derived from at least one of polyamideimide, polyimide, polyetherimide, polyaryletherketone, polyethersulfone, polyphenylene sulfide, polyamide, polyester, polyarylate, polyesteramide, polycarbonate, polybenzoxazole or polybenzimidazole and functionalized with at least one unreacted functional group capable of thermal chain extension and crosslinking after formation of the reactive oligomer, wherein the reactive oligomer has an M.sub.n of about 250 to about 10,000 g/mol, calculated using the Carothers equation. Compositions comprising the reactive oligomer have at least one other component that includes a second reactive oligomer, an oligomer lacking unreacted functional groups capable of thermal chain extension and crosslinking, a thermoplastic polymer, a thermoplastic polymer having the same backbone repeat units as the reactive oligomer, a filler, or an additive. A method of manufacture of an article comprises heating a composition comprising the reactive oligomer at a sufficient temperature and time to shape and crosslink the reactive oligomer, including additive manufacturing.

A polymer composition includes at least one poly(aryl ether ketone) (PAEK) component and at least one low molecular weight aromatic compound. A polymer metal junction including the polymer composition and a method of making a polymer metal junction are also described.

Provided are a yaw brake pad and a method of producing the same, which relate to the technical field of friction material. The yaw brake pad is prepared from, by weight, the following main ingredients: 70-75 parts of polyether ether ketone, 10-20 parts of carbon fiber, 3-5 parts of glass fiber and 3-5 of graphite. It alleviates the technical problem that the metal-based friction materials generally for producing current international and domestic yaw brake pads are likely to rust, harmful to dual discs, and produce screechy. It has not only significantly improved mechanical properties and high temperature tolerance, much lower hardness, less wear to dual discs, and lower noise, but also improved friction stability and adaptability to working conditions, and thus can effectively satisfy the demand of the wind driven generator for yaw braking at a low speed.

A powder with a volume-weighted particle size distribution, with a median diameter D50 ranging from 40 to 120 micrometers, including at least one polyaryl ether ketone and at least one filler, in which: said at least one polyaryl ether ketone forms a matrix incorporating, at least partly, said at least one filler, and said filler has a Stokes equivalent spherical diameter distribution with a median diameter d′50 of less than or equal to 5 micrometers. Also a powder manufacturing process and the use thereof in a process for the layer-by-layer construction of objects by electromagnetic radiation-mediated sintering.