Patent classifications
C08G61/121
WATER-SOLUBLE II-CONJUGATED FLUORESCENT 1,1 -BINAPHTHYL-BASED POLYMERS WITH TUNEABLE ABSORPTION
The invention is directed to a conjugate having the general formula (I)
##STR00001## Wherein AR and MU are repeating units of a polymer MU is a polymer modifying unit or band gap modifying unit that is evenly or randomly distributed along the polymer main chain, G1 and G2 stand for hydrogen, halogen or an antigen recognizing moiety, with the provision that at least one of G1 or G2 is an antigen recognizing moiety, a is 10 to 100 mol %, b is 0 to 90 mol % c is 1 to 10 000; with the provisio that a+b=100 mol % characterized in that AR is connected in the polymer chain via the 2,2′ or 3,3′ or 5,5′ or 6,6′ or 7,7′ or 8,8′ positions according to general formula (II)
##STR00002## Wherein the remaining positions 2,2′; 3,3′; 4,4′; 5,5′; 6,6′; 7,7′ and 8,8′ are substituted with same or different residues selected from the group consisting of H, SO.sub.2CF.sub.3, SO.sub.2R.sub.a, CF.sub.3, CCl.sub.3, CN, SO.sub.3H, NO.sub.2, NR.sub.aR.sub.bR.sub.c.sup.+, CHO, CORa, CO.sub.2Ra, COCl, CONRaRb, F, Cl, Br, I, R.sub.a, OR.sub.a, SR.sub.a, OCOR.sub.a, NR.sub.aR.sub.b, NHCOR.sub.a, CCR.sub.a, aryl-, heteroaryl-, C.sub.6H.sub.4OR.sub.a or C.sub.6H.sub.4NRaRb, with Ra-c independently hydrogen, alkyl-, alkenyl-, alkinyl-, heteroalkyl-, aryl-, heteroaryl-, cycloalkyl-, alkylcycloalkyl-, heteroalkylcycloalkyl-, heterocycloalkyl-, aralkyl- or a heteroaralkyl residue or (CH.sub.2)x(OCH.sub.2CH.sub.2)yO(CH.sub.2)zCH.sub.3, wherein x is an integer from 0 to 20; y is an integer from 0 to 50 and z is an integer from 0 to 20
Water-soluble M-conjugated fluorescent 1,1-binaphthyl-based tandem polymers
The invention is directed to a conjugate having the general formula (I)
##STR00001## Wherein AR, MU and MU* are repeating units of a polymer and MU and MU* are polymer modifying units or band gap modifying units which are evenly or randomly distributed along the polymer main chain, G1 and G2 stand for hydrogen, halogen or an antigen recognizing moiety, with the provision that at least one of G1 or G2 is an antigen recognizing moiety, a is 10 to 100 mol %, b is 0 to 90 mol % c is 0.1 to 90 mol % d is 1 to 10 000; with the provisio that a+b+c=100 mol % characterized in that AR is connected in the polymer chain via the 2,2′ or 3,3′ or 4,4′ or 5,5′ or 6,6′ or 7,7′ or 8,8′ positions according to general formula (II)
##STR00002## Wherein the remaining positions 2,2′; 3,3′; 4,4′; 5,5′; 6,6′; 7,7′ and 8,8′ are substituted with same or different residues selected from the group consisting of H, SO.sub.2CF.sub.3, SO.sub.2R.sub.a, CF.sub.3, CCl.sub.3, CN, SO.sub.3H, NO.sub.2, NR.sub.aR.sub.bR.sub.c.sup.+, CHO, CORa, CO.sub.2Ra, COCl, CONRaRb, F, Cl, Br, I, R.sub.a, OR.sub.a, SR.sub.a, OCOR.sub.a, NR.sub.aR.sub.b, NHCOR.sub.a, CCR.sub.a, aryl-, heteroaryl-, C.sub.6H.sub.4OR.sub.a or C.sub.6H.sub.4NRaRb, with Ra-c independently hydrogen, alkyl-, alkenyl-, alkinyl-, heteroalkyl-, aryl-, heteroaryl-, cycloalkyl-, alkylcycloalkyl-, heteroalkylcycloalkyl-, heterocycloalkyl-, aralkyl- or a heteroaralkyl residue or (CH.sub.2).sub.x(OCH.sub.2CH.sub.2).sub.yO(CH.sub.2).sub.zCH.sub.3, wherein x is an integer from 0 to 20; y is an integer from 0 to 50 and z is an integer from 0 to 20.
FLUORINATED AROMATIC POLYMER AND METHOD FOR PRODUCING SAME
The present invention addresses the problem of providing a fluorine-containing aromatic polymer; a method for producing the fluorine-containing aromatic polymer; etc. The problem can be solved by: a polymer having a monomer unit represented by formula (1) (wherein R.sup.1 in each occurrence is independently a halogen atom, NR.sup.11R.sup.12 (wherein R.sup.11 and R.sup.12 are independently a hydrogen atom or an organic group), or an organic group; n1 is an integer of 0 to 4; two R.sup.1s that can be present in the ortho-positions may form a ring together with two carbon atoms on the adjacent benzene ring, wherein the formed ring may have an organic group as a substituent; and L.sup.1 is a single bond, an oxygen atom, a sulfur atom, -L.sup.11-O—, —O-L.sup.12-O—, -L.sup.13-S—, or —S-L.sup.14-S— (wherein L.sup.11 to L.sup.14 are each independently an alkylene group optionally having one or more substituents); etc.
UV Excitable Polyfluorene Based Conjugates and Their Use in Methods of Analyte Detection
The invention provides for UV excitable polyfluorene based conjugates and their use in methods of analyte detection.
Fluorinated aromatic polymer and method for producing same
The present invention addresses the problem of providing a fluorine-containing aromatic polymer; a method for producing the fluorine-containing aromatic polymer; etc. The problem can be solved by: a polymer having a monomer unit represented by formula (1) (wherein R.sup.1 in each occurrence is independently a halogen atom, NR.sup.11R.sup.12 (wherein R.sup.11 and R.sup.12 are independently a hydrogen atom or an organic group), or an organic group; n1 is an integer of 0 to 4; two R.sup.1s that can be present in the ortho-positions may form a ring together with two carbon atoms on the adjacent benzene ring, wherein the formed ring may have an organic group as a substituent; and L.sup.1 is a single bond, an oxygen atom, a sulfur atom, -L.sup.11-O—, —O-L.sup.12-O—, -L.sup.13-S—, or —S-L.sup.14-S— (wherein L.sup.11 to L.sup.14 are each independently an alkylene group optionally having one or more substituents); etc.
Novel Polymer and Organic Light Emitting Device Comprising Same
The present disclosure provides a polymer compound and an organic light emitting device including e same, wherein the polymer comprising a repeating unit represented by the following Chemical Formula 1:
##STR00001##
wherein L, R.sub.1 to R.sub.5, and * are described herein.
COMPOSITIONS COMPRISING AT LEAST ONE POLYMER AND AT LEAST ONE METAL COMPLEX AND TO ELECTROLUMINESCENT DEVICES CONTAINING SAID COMPOSITIONS
The present invention relates to compositions comprising at least one polymer which contains triarylamine repeating units, and at least one metal complex, to methods for the production thereof, and the use thereof in electronic devices, especially in organic electroluminescent devices, so-called OLEDs (OLED=Organic Light Emitting Diode). The present invention also relates to organic electroluminescent devices which contain said compositions
Nanoparticles
The present invention relates to nanoparticles of π-conjugated polymers. The present invention also relates to an aqueous composition comprising these polymeric nanoparticles, to processes for making the nanoparticles, and to the use of these nanoparticles in the fabrication of electronic devices and components.
MULTI-ACID POLYMERS AND METHODS OF MAKING THE SAME
A multi-acid polymer disclosed herein has the formula
##STR00001##
wherein R is one or more units of a non-SOF.sub.2 or non-SO.sub.2Cl portion of a polymer precursor in sulfonyl fluoride or sulfonyl chloride form, X is a non-sulfonyl halide group of a multi-sulfonyl halide compound having a minimum of two acid giving groups, and Y is remaining sulfonyl halide groups of the multi-sulfonyl halide compound.
SELF-ORGANIZED AND ELECTRICALLY CONDUCTING PEDOT POLYMER MATRIX FOR APPLICATIONS IN SENSORS AND ENERGY GENERATION AND STORAGE
The present invention relates to a one-step process for preparation of “in-situ” or “ex-situ” self-organized and electrically conducting polymer nanocomposites using thermally initiated polymerization of a halogenated 3,4-ethylenedioxythiophene monomer or its derivatives. This approach does not require additional polymerization initiators or catalysts, produce gaseous products that are naturally removed without affecting the polymer matrix, and do not leave by-product contaminants. It is demonstrated that self-polymerization of halogenated 3,4-ethylenedioxythiophene monomer is not affected by the presence of a solid-state phase in the form of nanoparticles and results in formation of 3,4-polyethylenedioxythiophene (PEDOT) nanocomposites.