The present disclosure relates to a composition that includes a first repeat unit that includes ##STR00001##
where x is between 1 and 1,000, inclusively, and R.sub.1 includes at least one of a first hydrocarbon chain and/or a first hydrocarbon ring. In some embodiments of the present disclosure, R.sub.1 may further include at least one of an oxygen atom, a nitrogen atom, a sulfur atom, and/or a phosphorus atom.

The present disclosure relates to a composition that includes a first repeat unit that includes ##STR00001##
where x is between 1 and 1,000, inclusively, and R.sub.1 includes at least one of a first hydrocarbon chain and/or a first hydrocarbon ring. In some embodiments of the present disclosure, R.sub.1 may further include at least one of an oxygen atom, a nitrogen atom, a sulfur atom, and/or a phosphorus atom.

The present invention relates to processes for making compatibilized high aspect ratio barrier additives and polymer compositions that comprise compatibilized high aspect ratio barrier additives. The invention also relates to compositions produced by these processes, and articles formed from polymer compositions of this invention. The barrier additives provide passive barriers to gas molecules such as oxygen and carbon dioxide minimizing transit of such molecules through sidewalls of polymer articles containing the barrier additives.

The present invention relates to a reactor-grade copolyester composition having radio-frequency sealing capability. The present invention further relates to films and thermoformable packaging prepared from the reactor-grade copolyester composition and the methods for making such films and articles therefrom.

The present invention relates to a reactor-grade copolyester composition having radio-frequency sealing capability. The present invention further relates to films and thermoformable packaging prepared from the reactor-grade copolyester composition and the methods for making such films and articles therefrom.

The polymer includes a first structural unit represented by formula (1), a second structural unit represented by formula (2), and a third structural unit represented by formula (3). R.sup.1, R.sup.2, R.sup.10 and R.sup.11 each independently represent a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a nitro group or a cyano group; R.sup.3A, R.sup.3B R.sup.4A and R.sup.4B each independently represent a methylene group or an alkylene group having 2 to 4 carbon atoms; Z.sup.A to Z.sup.D each independently represent —O— or —S—; and L represents a divalent group represented by formula (3-1) or (3-2), wherein R.sup.a represents a divalent alicyclic hydrocarbon group having 5 to 30 ring atoms or a divalent fluorinated alicyclic hydrocarbon group having 5 to 30 ring atoms.

##STR00001##

Process for preparing copolyesters by introducing TPA, EG, and CHDM at an EG:TPA molar ratio of 2.3:1 to 2.7:1 into a reaction zone; reacting TPA with EG and CHDM at a temperature of at least 250° C. and pressure of up to 40 psi to form a first esterification product; passing the first esterification product to a reaction zone; esterifying the first esterification product at a temperature of at least 250° C. and pressure of up to 20 psi to form a second esterification product, passing the second esterification product to a reaction zone; polycondensing the second esterification product in the presence of a catalyst to form a prepolymerization product; passing the prepolymerization product to one or more reaction zones; and polycondensing the prepolymerization product in the presence of the catalyst to form a copolyester comprising 1.0 wt % or less of DEG, without requiring the use of DEG-suppressing additives.

Process for preparing copolyesters by introducing TPA, EG, and CHDM at an EG:TPA molar ratio of 2.3:1 to 2.7:1 into a reaction zone; reacting TPA with EG and CHDM at a temperature of at least 250° C. and pressure of up to 40 psi to form a first esterification product; passing the first esterification product to a reaction zone; esterifying the first esterification product at a temperature of at least 250° C. and pressure of up to 20 psi to form a second esterification product, passing the second esterification product to a reaction zone; polycondensing the second esterification product in the presence of a catalyst to form a prepolymerization product; passing the prepolymerization product to one or more reaction zones; and polycondensing the prepolymerization product in the presence of the catalyst to form a copolyester comprising 1.0 wt % or less of DEG, without requiring the use of DEG-suppressing additives.

A catalytic composition for preparing a polyethylene terephthalate (PET) resin is provided. The catalytic composition comprises a polycondensation catalyst and cesium tungsten oxide (Cs.sub.xWO.sub.3-yCl.sub.y), and 0<x≦1 and 0≦y≦0.5. A PET resin prepared by the catalytic composition above is also provided. The PET resin comprises 2-80 ppm of cesium tungsten oxide. This catalytic composition can solve the problems of slow solid-state polymerization rate of the PET preparation and thus the long preparation time, as well as yellowing. Moreover, the PET resin can absorb infrared radiation.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.