The present invention provides an optical composition from which an optical article having reduced poor appearance such as cloudiness and optical strain during lens base material production can be obtained, and when a photochromic compound is added, a photochromic cured body having excellent photochromism and mechanical strength can also be formed, and a polyrotaxane used therefor. The polyrotaxane has a composite molecular structure formed of an axle molecule and a plurality of cyclic molecules clathrating the axle molecule, satisfying at least one of (X) and (Y). (X): A side chain having a secondary or tertiary hydroxyl group is introduced into at least part of the cyclic molecule of the polyrotaxane. (Y): A side chain having a group represented by -A (A is an organic group, and contains at least one hydroxyl group) is introduced into at least part of the cyclic molecule of the polyrotaxane, and a pKa of the hydroxyl group of the compound represented by H-A is 6 or more and less than 14.

The present invention provides an optical composition from which an optical article having reduced poor appearance such as cloudiness and optical strain during lens base material production can be obtained, and when a photochromic compound is added, a photochromic cured body having excellent photochromism and mechanical strength can also be formed, and a polyrotaxane used therefor. The polyrotaxane has a composite molecular structure formed of an axle molecule and a plurality of cyclic molecules clathrating the axle molecule, satisfying at least one of (X) and (Y). (X): A side chain having a secondary or tertiary hydroxyl group is introduced into at least part of the cyclic molecule of the polyrotaxane. (Y): A side chain having a group represented by -A (A is an organic group, and contains at least one hydroxyl group) is introduced into at least part of the cyclic molecule of the polyrotaxane, and a pKa of the hydroxyl group of the compound represented by H-A is 6 or more and less than 14.

A surface-treating agent including a perfluoro(poly)ether group-containing silane compound and a perfluoro(poly)ether group-containing compound. The perfluoro(poly)ether group-containing compound contains a radical capturing group or a UV absorbing group in the molecule.

A curable epoxy resin adhesive including first and second amine curing agents each having a respective curing property determined by mixing the respective amine curing agent alone with a test epoxy resin to form a first or second curable mixture, and each curing property comprises a gel time when the curable mixture is at an ambient temperature of 25° C. and a peak exotherm temperature when the curable mixture is cured in air at a curing temperature of 70° C. A ratio between the first and second gel times is from 4-15:1 and the second amine curing agent has peak exotherm temperature is higher than the peak exotherm temperature of the first amine curing agent by a temperature Δt which is at least 2° C.

Embodiments of the present disclosure are directed processes to produce a low-color esterified oil soluble polyalkylene glycol, the process comprising forming a reaction mixture including a low viscosity oil soluble polyalkylene glycol and an excess amount of valeric acid, where the reaction mixture is formed in the presence of a catalytic amount of ortho-phosphoric acid catalyst to yield an organic phase including the low-color esterified oil soluble polyalkylene glycol.

Embodiments of the present disclosure are directed processes to produce a low-color esterified oil soluble polyalkylene glycol, the process comprising forming a reaction mixture including a low viscosity oil soluble polyalkylene glycol and an excess amount of valeric acid, where the reaction mixture is formed in the presence of a catalytic amount of ortho-phosphoric acid catalyst to yield an organic phase including the low-color esterified oil soluble polyalkylene glycol.

Disclosed is a method for producing a biphenyl-skeleton-containing epoxy resin represented by Formula (1) described below including a step of allowing polyvalent hydroxy biphenyl obtained by a production step including a regioselective cross-coupling reaction to react with epihalohydrin. ##STR00001##
(In the formula, k1 and l1 each represent an integer of 0 to 4, m and n each represent an integer of 1 to 5, R.sup.1 and R.sup.2 each independently represent a hydrocarbon group having 1 to 10 carbon atoms which may have a substituent group, and R.sup.1 and R.sup.2 may be identical to each other or different from each other. (Provided that left and right phenyl structures of a biphenyl skeleton are different from each other.)

The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used. The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I): ##STR00001##
wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m′ represents an integer of 0 or more; n′ represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.

The present invention is concerned with a reactive surfactant composition for emulsion polymerization, which is able to micronize the particle diameter of a polymer emulsion and to reduce the addition amount of the reactive surfactant composition to be used. The reactive surfactant composition for emulsion polymerization of the present invention contains a reactive anionic surfactant (component A) represented by the following formula (I): ##STR00001##
wherein AO represents an alkyleneoxy group having a carbon number of 3 or more and 18 or less; EO represents an ethyleneoxy group; p represents an integer of 1 or more and 15 or less; m′ represents an integer of 0 or more; n′ represents an integer of 0 or more; M.sup.+ represents a hydrogen ion or a cation; and plural kinds of AOs may coexist.

The present disclosure belongs to the field of organic synthesis, and particularly relates to a ring-opening polymerization method for a cyclic monomer. A specific solution is that a Lewis acid-base pair is used to catalyze ring-opening polymerization of the cyclic monomer in the presence of an initiator. By using the Lewis acid-base pair as a catalyst, on one hand, a range of a ring-opening polymerization catalyst is widened, and on the other hand, this catalyst achieves a higher catalytic efficiency and is milder in comparison with previously reported strong acid or strong base catalysts. In addition, through a bifunctional activation mechanism, this catalyst system activates the monomer and simultaneously activates the initiator or a chain end, and has the characteristics of high efficiency in comparison with the reported monomer activation mechanism or chain end activation mechanism. By adopting the catalyst, a polyester product with a target molecular weight can be synthesized in a controlled manner as required, with a narrower molecular weight distribution index, a high product yield, a high product conversion rate and no monomer or metal residues.