Methods of forming nanoporous materials are described herein that include forming a polymer network with a chemically removable portion. The chemically removable portion may be polycarbonate polymer that is removable on application of heat or exposure to a base, or a polyhexahydrotriazine (PHT) or polyhemiaminal (PHA) polymer that is removable on exposure to an acid. The method generally includes forming a reaction mixture comprising a formaldehyde, a solvent, a primary aromatic diamine, and a diamine having a primary amino group and a secondary amino group, the secondary amino group having a base-reactive substituent, and heating the reaction mixture to a temperature of between about 50 degC and about 150 degC to form a polymer. Removing any portion of the polymer results in formation of nanoscopic pores as polymer chains are decomposed, leaving pores in the polymer matrix.

The present invention relates to resin compositions, fiber reinforced polymeric structures and electromagnetic induction processes for making same. Such magnetic induction processes are pulsed processes that can be optionally coupled with cooling steps between pulses. The aforementioned fiber reinforced polymeric structures can take forms that include, but are not limited to, pipes; pressure vessels, including rocket motor cases and fire extinguishers; golf club shafts; tennis and badminton racquets; skis; snowboards; hockey sticks; fishing rods; bicycle frames; boat masts; oars; paddles; baseball bats; and softball bats. In addition, such fiber reinforced polymeric structures can be supplemented with other materials, such as a rocket propellant, to form articles, for example, a rocket motor.

The present disclosure provides a polymerizable thermosetting composition comprising an acetylene-bearing benzoxazine compound and a phthalonitrile monomer. The composition can provide a low viscosity for RTM application and can fully cured at a much lower temperature than the phthalonitrile monomer. The cured thermoset polymers having excellent thermal and mechanical properties, such as high thermal stability, heat resistance, high char yield, and enhanced structural rigidity.

For example, a triazine ring-containing polymer containing a repeating unit structure represented by formula (25) below,

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wherein R.sup.a represents R.sup.102 or R.sup.103, R.sup.102 represents a fluorine atom or a fluoroalkyl group having 1 to 10 carbon atoms, and R.sup.103 represents a crosslinking group.

Carbon phosphonitride (CPN) including tricyanophosphine (P(CN).sub.3), its pre-polymer (CPN-PP), and/or solid CPN (C.sub.3N.sub.3P) can serve as a useful additive for thermoset resins, resulting in improved thermal and mechanical properties.

The present application is directed to methods for solvent-free preparation of polymers and their subsequent processing into activated carbon materials. These methods unexpectedly demonstrate ability to tune pore structure in the polymer gel and carbon produced there from, while also providing distinct advantages over the current art.

A polymer of intrinsic microporosity having a repeating subunit including both a spirobisindane imide moiety and an amido (lactam) moiety.

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A process for the manufacture of a degradable polycyanurate bulk molding composition includes: contacting a liquid cyanate ester monomer with an additive material and a polymerization catalyst to form a reaction mixture; maintaining a temperature of the reaction mixture at about 80° C. to about 100° C. to form a polycyanurate product having a viscosity of about 120 to about 200 centipoise at 23° C.; heating a reinforcing filler at a temperature of about 50 to about 150° C. to form a pre-heated reinforcing filler; and blending the polycyanurate product with the pre-heated reinforcing filler to form the degradable polycyanurate bulk molding composition. The bulk molding composition can be used to form a degradable polycyanurate article.

This disclosure describes new compositions and methods related to photoresponsive poly(hexahydrotriazines) and related polymers.

A well treatment composition for use in a hydrocarbon-bearing reservoir comprising a reversible aminal gel composition is disclosed. The reversible aminal gel composition includes a liquid precursor composition. The liquid precursor composition is operable to remain in a liquid state at about room temperature. The liquid precursor composition comprises an organic amine composition; an aldehyde composition; a polar aprotic organic solvent; and a metal salt composition with valence 3, 4, or 5. The liquid precursor composition transitions from the liquid state to a gel state responsive to an increase in temperature in the hydrocarbon-bearing reservoir. The gel state is stable in the hydrocarbon-bearing reservoir at a temperature similar to a temperature of the hydrocarbon-bearing reservoir, and the gel state is operable to return to the liquid state responsive to a change in the hydrocarbon-bearing reservoir selected from the group consisting of: a decrease in pH in the hydrocarbon-bearing reservoir and an addition of excess metal salt composition in the hydrocarbon-bearing reservoir.