Isocyanate-reactive compositions that include a hydrofluoroolefin blowing agent, polyurethane foam-forming compositions, as well as spray-applied polyurethane foams formed therefrom that can provide structural support to wall structures and can also exhibit ASTM E84-16 Class A flame spread and smoke development characteristics at a foam thickness of 4 inches.

Foam compositions are provided. The compositions are prepared from multi-functional acetoacetate esters and multi-functional amines or acrylates. The foam compositions can include one or more additives. The foam compositions can be used for home and commercial insulation, air sealing, sound proofing, structural improvement, and exterior roofing, among other applications. The foam compositions provide advantages of being isocyanate free and offer reduced exposure to isocyanate.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

The present disclosure relates to acid-blocked pyrrolidine catalysts for use in a polyurethane formulation. The polyurethane formulation includes the acid-blocked pyrrolidine catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound and a halogenated olefin compound. The use of such acid-blocked pyrrolidine catalysts show surprisingly low reactivity with halogenated olefin compounds yet sufficient reactivity to catalyze polyurethane formation.

Foam compositions are provided. The compositions are prepared from multi-functional acetoacetate esters and multi-functional amines or acrylates. The foam compositions can include one or more additives. The foam compositions can be used for home and commercial insulation, air sealing, sound proofing, structural improvement, and exterior roofing, among other applications. The foam compositions provide advantages of being isocyanate free and offer reduced exposure to isocyanate.

Hybrid spray foams utilize a urethane reactant, a crosslinker, and an (optional) epoxy and/or acrylic resin along with a blowing agent and rheology modifier to produce a quick-setting foam that remains in place until the foam forms and cures. The urethane reactant may be formed as an adduct with or without the use of isocyanate chemistry. In some embodiments, the polyurethane oligomer is made by reacting cyclocarbonates and di- or polyamines, while in other embodiments the polyurethane backbone employs the use of commercially available capped or blocked urethane oligomers made by any method. The oligomers contain reactive groups, typically at the oligomer ends, that crosslink with crosslinkers or with acrylic or epoxy resins to form hybrid polyurethane foams. Foams may also contain a plasticizer, and/or a surfactant as well as other optional additives. Methods of making such foams are also provided.

The present disclosure relates to a polyol resin blend for use in a polyurethane formulation. The polyol resin blend generally includes (a) an amine having a pKa value between about 6 and about 8.5 and a protonated amine obtained by contacting a methylamino-containing tertiary amine or primary etheramine having a pKa value greater than about 9 and an acid compound, (b) a polyol, and (c) a halogenated olefin. The present disclosure also provides polyurethane formulations containing the polyol resin blend and methods of making polyurethane foam from such polyurethane formulations.

A method, a device, and a composition are disclosed. The method includes providing a polyol blend that includes a polyol resin and an electromagnetic (EMA) additive, providing an isocyanate resin selected such that blending the isocyanate resin with the polyol blend results in an EMA spray foam. The device includes a first compartment containing an isocyanate resin and a second compartment containing a polyol blend, which includes a polyol resin and an EMA additive. The composition includes a polyurethane spray foam and an EMA additive blended into the polyurethane spray foam.

Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of hydrohaloolefin, including trans1233zd, and wherein the polyol comprises a polyol or mixture of polyols such that the hydrohaloolefin, including trans1233zd, has a solubility in said polyol of less than about 30%; and (b) forming a foam from said foamable composition.

The invention pertains generally to a low-pressure (100-250 psi) process of seaming adjacent seams of artificial turf using a one-component or a two-component polyurethane adhesive using an apparatus which employs a payoff spool of base material in the front of the apparatus and an activation trigger adjacent the handle to begin the application of polyurethane spray foam adhesive by connectivity between the application trigger and the foam spray gun trigger.