Patent classifications
C08J2301/16
Cellulose fiber-containing resin composition, sheet, and molded body
It is an object of the present invention to provide a resin composite comprising ultrafine cellulose fibers, in which deterioration of a resin component is suppressed. The present invention relates to a cellulose fiber-containing resin composition comprising cellulose fibers with a fiber width of 1000 nm or less having phosphoric acid groups or phosphoric acid group-derived substituents, and a resin, wherein the counterions of the phosphoric acid groups or phosphoric acid group-derived substituents are organic onium ions, and the conjugate bases of the organic onium ions have a pKb value of 1.0 or more.
Thickener, composition, and sheet
It is an object of the present invention to provide a thickener capable of exhibiting excellent light resistance. The present invention relates to a thickener comprising cellulose fibers having a fiber width of 8 nm or less and water, wherein the thickener is a slurry or a gel, and when the thickener is filled in a colorless and transparent glass cell having an inside dimension of 1 cm in depth×4 cm in width×4.5 cm in height and the thickener is then irradiated with ultraviolet rays with a wavelength of 300 nm or more and 400 nm or less, using a xenon lamp, from the side of the maximum area surface of the glass cell, so as to be an irradiance of 180 W/m.sup.2 and an integrated light amount of 500 mJ/m.sup.2, the amount of a change in the yellowness before and after ultraviolet irradiation measured in accordance with JIS K 7373 is 10 or less.
NANOCELLULOSE DISPERSION LIQUID AND METHOD FOR PRODUCING THE SAME
A nanocellulose dispersion liquid including nanocellulose and a protic polar solvent having a dielectric constant of not less than 15 and less than 80 at 25° C. The nanocellulose contains a sulfuric acid group and/or a sulfo group derived from a sulfuric acid treatment and an anionic functional group derived from a hydrophilization treatment. Further, the total amount of the sulfuric acid group and/or the sulfo group and the anionic functional group is 0.20 to 4 mmol/g. Also disclosed is a method for producing the nanocellulose dispersion liquid.
RESIN BEADS, METHOD FOR PRODUCING RESIN BEADS, AND PRODUCT USING RESIN BEADS
The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 μm or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.
Material comprising ultrafine cellulose fibers
An object of the invention is to provide a material comprising ultrafine cellulose fibers, having good dispersibility of fine particles in an aqueous medium containing ultrafine cellulose fibers. According to the invention, there is provided a material comprising ultrafine cellulose fibers, wherein the content of the ultrafine cellulose fibers is 80% by mass or more, and the haze value of a sample, which has been prepared by adding the material comprising ultrafine cellulose fibers to pure water to a solid concentration of 0.4% by mass, and stirring the mixture with a disperser under conditions of 1500 rpm and 5 minutes, is 20% or less.
Sheet, method for producing sheet, and laminate
An object of the present invention is to improve the strength of a sheet containing substituent-introduced ultrafine fiber under high-humidity conditions while maintaining its high transparency. The sheet of the present invention comprises ultrafine fiber having an ionic substituent, and a divalent or higher metal, and has a haze of 10.0% or less.
CELLULOSE FIBER-CONTAINING RESIN COMPOSITION, SHEET, AND MOLDED BODY
It is an object of the present invention to provide a resin composite comprising ultrafine cellulose fibers, in which deterioration of a resin component is suppressed. The present invention relates to a cellulose fiber-containing resin composition comprising cellulose fibers with a fiber width of 1000 nm or less having phosphoric acid groups or phosphoric acid group-derived substituents, and a resin, wherein the counterions of the phosphoric acid groups or phosphoric acid group-derived substituents are organic onium ions, and the conjugate bases of the organic onium ions have a pKb value of 1.0 or more.
THICKENER, COMPOSITION, AND SHEET
It is an object of the present invention to provide a thickener capable of exhibiting excellent light resistance. The present invention relates to a thickener comprising cellulose fibers having a fiber width of 8 nm or less and water, wherein the thickener is a slurry or a gel, and when the thickener is filled in a colorless and transparent glass cell having an inside dimension of 1 cm in depth4 cm in width4.5 cm in height and the thickener is then irradiated with ultraviolet rays with a wavelength of 300 nm or more and 400 nm or less, using a xenon lamp, from the side of the maximum area surface of the glass cell, so as to be an irradiance of 180 W/m.sup.2 and an integrated light amount of 500 mJ/m.sup.2, the amount of a change in the yellowness before and after ultraviolet irradiation measured in accordance with JIS K 7373 is 10 or less.
Resin beads, method for producing resin beads, and product using resin beads
The present invention provides resin beads that can provide various types of products, such as a cosmetic having excellent tactile impression, spreadability on the skin, and transparency, that can be substituted for resin particles composed of a synthetic material derived from petroleum, and that have favorable biodegradability, and the present invention also provides various types of products, such as a cosmetic using the resin beads. The resin beads are formed with a resin containing cellulose as a main component. The resin beads have a cumulative 50% particle size on a volume basis of 50 m or smaller, a degree of sphericity of 0.7 to 1.0, a degree of surface smoothness of 70 to 100%, a degree of solidity of 50 to 100%, and a biodegradation rate for 5 days, as measured in accordance with JIS K6950:2000 (ISO 14851:1999), of 20% or more, and the content of the cellulose in the resin is 90 to 100% by mass. In addition, the present invention provides a product of any one of a cosmetic, a dermatological preparation, a paint, a shaped article, a film, a coating agent, and a resin composition which contain the resin beads.
DISPERSION, COMPOSITE, AND PRODUCING METHODS THEREFOR
A dispersion of a cellulose nanofiber (CNF) and a cellulose nanocrystal (CNC) that maintains a physical property even after drying and redispersing and has a long pot life is provided. A composite of the CNF and the CNC having a higher rupture strength and a higher oxygen gas barrier property is also provided. The dispersion contains a CNF having a sulfate ester group and a CNC having a sulfate ester group. The composite contains the CNF having a sulfate ester group and the CNC having a sulfate ester group.