Embodiments of the present invention include composite compositions extrusion compounded together comprising a polymer, an amount of nanotubes, and an amount of finely milled carbon fiber having an aspect ratio greater than 1 and less than about 5. The resulting composite materials allow for high carbon loading levels with improved tribological properties including coefficient of friction and wear rates, provides uniform surface resistance with minimal processing sensitivity, retains rheological properties similar to the base resin, and provides isotropic shrink and a reduced coefficient of thermal expansion leading to minimal warp. In general, various articles can be formed that take advantage of the properties of the composite materials incorporating a polymer, carbon nanotubes and finely milled carbon fiber.

Embodiments of the present invention include composite compositions extrusion compounded together comprising a polymer, an amount of nanotubes, and an amount of finely milled carbon fiber having an aspect ratio greater than 1 and less than about 5. The resulting composite materials allow for high carbon loading levels with improved tribological properties including coefficient of friction and wear rates, provides uniform surface resistance with minimal processing sensitivity, retains rheological properties similar to the base resin, and provides isotropic shrink and a reduced coefficient of thermal expansion leading to minimal warp. In general, various articles can be formed that take advantage of the properties of the composite materials incorporating a polymer, carbon nanotubes and finely milled carbon fiber.

A composite material having at least two layers of reinforcing fibers impregnated with a curable resin; an interlaminar region formed between adjacent layers of reinforcing fibers; and a combination of polymeric toughening particles and fire-retardant particles in the interlaminar region.

A composite material having at least two layers of reinforcing fibers impregnated with a curable resin; an interlaminar region formed between adjacent layers of reinforcing fibers; and a combination of polymeric toughening particles and fire-retardant particles in the interlaminar region.

The present disclosure provides a curable resin composition including a thermoset resin, an aliphatic polyketone as a toughener and a hardener. The curable resin composition may be combined with reinforcing fibers and then cured to form a fiber-reinforced composite article having a high glass transition temperature, excellent mechanical properties and low moisture absorption. The fiber-reinforced composite article may be used in various applications, such as in transport applications including aerospace, aeronautical, nautical and land vehicles.

The present disclosure provides an aluminum phosphite-based complex with dual-peak thermal gravity decomposition characteristics and a preparation method and use thereof. A structural formula of the complex is as follows: ((HPO.sub.3).sub.3Al.sub.2).((H.sub.2PO.sub.3).sub.3Al).sub.x, wherein x is 0.01-0.5 and represents a molar ratio of (H.sub.2PO.sub.3).sub.3Al to (HPO.sub.3).sub.3Al.sub.2. The dual-peak thermal gravity decomposition characteristics are as follows: a first gravity peak temperature is 460-490° C., and a second gravity peak temperature is 550-580° C. The preparation method includes: uniformly mixing aluminum phosphite and aluminum hydrogen phosphite according to the ratio in the structural formula, and then performing stepwise heating at a rate of 5° C./min to raise the temperature of a mixture from the normal temperature to no more than 350° C. within 1-10 hours, so as to obtain the aluminum phosphite-based complex with the dual-peak thermal gravity decomposition characteristics. The complex may serve as or is configured to prepare a flame retardant or a flame-retardant synergist.

The present disclosure provides an aluminum phosphite-based complex with dual-peak thermal gravity decomposition characteristics and a preparation method and use thereof. A structural formula of the complex is as follows: ((HPO.sub.3).sub.3Al.sub.2).((H.sub.2PO.sub.3).sub.3Al).sub.x, wherein x is 0.01-0.5 and represents a molar ratio of (H.sub.2PO.sub.3).sub.3Al to (HPO.sub.3).sub.3Al.sub.2. The dual-peak thermal gravity decomposition characteristics are as follows: a first gravity peak temperature is 460-490° C., and a second gravity peak temperature is 550-580° C. The preparation method includes: uniformly mixing aluminum phosphite and aluminum hydrogen phosphite according to the ratio in the structural formula, and then performing stepwise heating at a rate of 5° C./min to raise the temperature of a mixture from the normal temperature to no more than 350° C. within 1-10 hours, so as to obtain the aluminum phosphite-based complex with the dual-peak thermal gravity decomposition characteristics. The complex may serve as or is configured to prepare a flame retardant or a flame-retardant synergist.

The invention is targeted mainly at a process for the preparation of a semifinished product comprising a PAEK-based resin and reinforcing fibers, comprising the stages of: a. preparation of a dispersion comprising a PAEK-based resin in the pulverulent form dispersed in an aqueous phase comprising a surfactant; b. bringing the reinforcing fibers into contact with said aqueous dispersion; c. drying the fibers impregnated with dispersion; and d. heating the impregnated fibers to a temperature sufficient for the melting of the resin, so as to form a semifinished product,
characterized in that the surfactant is a thermally stable surfactant. It is furthermore targeted at the dispersion of use in said process. Finally, it is targeted at the semifinished products capable of being obtained and also at their use in the manufacture of composite materials.

A flame-retardant polyamide composition can be prepared with a glow wire ignition temperature of not less than 775° C. Such a composition can include a polyamide having a melting point of not more than 290° C. as component A, fillers and/or reinforcers as component B, a phosphinic salt of the formula (I) as component C, a compound selected from the group of the Al, Fe, TiO.sub.p and Zn salts of ethylbutylphosphinic acid, of dibutylphosphinic acid, of ethylhexylphosphinic acid, of butylhexylphosphinic acid and/or of dihexylphosphinic acid as component D, a phosphonic salt of the formula (II) as component E, and a melamine polyphosphate having an average degree of condensation of 2 to 200 as component F. Additional components can be included in the composition.

Compositions and methods for amorphous high temperature polyketone polymers incorporating 2H-benzimidazol-2-one with dihalobenzophenone and bis(halobenzoyl)benzene as comonomer units are described herein. The polyketones polymers have advantageous properties, particularly in terms of high glass transition temperatures (T.sub.g), inherently flame resistance, good mechanical properties at elevated temperature, chemical resistance and dimensional stability in wet environment. The polymers are suitable for manufacturing high temperature molded systems and other articles of manufacture via injection molding, extrusion, compression molding, coating, blow molding, thermoforming, rotational molding and additive manufacturing.