One of the objects of the present invention is to provide a thermally conductive silicone resin composition which has good thermal conductivity, a light weight (namely, a light weight per unit volume), and good reliability in high humidity, and a molded body thereof. The present invention provides a thermally conductive silicone resin composition comprising the following components (A) to (E): (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in an amount of 100 parts by mass, (B) an organohydrogen polysiloxane having at least two hydrogen atoms each bonded to a silicon atom in an amount such that a ratio of the number of the hydrogen atom bonded to a silicon atom relative to the number of the alkenyl group in component (A) is 0.1 to 2, (C) a thermally conductive filler in an amount of 2500 to 6000 parts by mass, (D) a catalytic amount of an addition reaction catalyst, and (E) an addition-reaction controlling agent in an amount of 0.01 to 1 part by mass, wherein the thermally conductive filler (C) comprises magnesium oxide having a specific surface area of 0.4 m.sup.2/g or less in an amount of 20 to 50 wt % and aluminum hydroxide in an amount of 10 to 30 wt %, relative to a total weight of component (C).

One of the objects of the present invention is to provide a thermally conductive silicone resin composition which has good thermal conductivity, a light weight (namely, a light weight per unit volume), and good reliability in high humidity, and a molded body thereof. The present invention provides a thermally conductive silicone resin composition comprising the following components (A) to (E): (A) an organopolysiloxane having at least two alkenyl groups each bonded to a silicon atom in an amount of 100 parts by mass, (B) an organohydrogen polysiloxane having at least two hydrogen atoms each bonded to a silicon atom in an amount such that a ratio of the number of the hydrogen atom bonded to a silicon atom relative to the number of the alkenyl group in component (A) is 0.1 to 2, (C) a thermally conductive filler in an amount of 2500 to 6000 parts by mass, (D) a catalytic amount of an addition reaction catalyst, and (E) an addition-reaction controlling agent in an amount of 0.01 to 1 part by mass, wherein the thermally conductive filler (C) comprises magnesium oxide having a specific surface area of 0.4 m.sup.2/g or less in an amount of 20 to 50 wt % and aluminum hydroxide in an amount of 10 to 30 wt %, relative to a total weight of component (C).

The present invention addresses the problem of providing a super-liquid-repellent coating film that has improved abrasion resistance. Provided as a means for solving the problem is a coating film that has a fluorine atom content of 1 to 60 wt %, the coating film having a surface that has an average surface roughness Ra of 0.5 to 20, a surface area ratio of 1.7 to 5, a contact angle with water of 150° or more, a contact angle with n-hexadecane of 80° or more, and a surface that has a contact angle with water of 150° or more after being rubbed 100 times with a PET film under a load of 100 g.

The present invention addresses the problem of providing a super-liquid-repellent coating film that has improved abrasion resistance. Provided as a means for solving the problem is a coating film that has a fluorine atom content of 1 to 60 wt %, the coating film having a surface that has an average surface roughness Ra of 0.5 to 20, a surface area ratio of 1.7 to 5, a contact angle with water of 150° or more, a contact angle with n-hexadecane of 80° or more, and a surface that has a contact angle with water of 150° or more after being rubbed 100 times with a PET film under a load of 100 g.

The present disclosure discloses a low-water-vapor-permeability polyolefin-elastomer film and its preparation method. The film comprises: 50-100 mass parts of a matrix resin, 0-40 mass parts of a modified resin, 0.001-2 mass parts of an activator, 0.1-3 mass parts of an organic peroxide, 0.02-5 mass parts of an assistant cross-linker, 0.02-2 mass parts of a silane coupling agent, 0.005-2 mass parts of a light stabilizer, and 0-20 mass parts of a water blocking filler. In the present disclosure, by adding the modified resin and the activator that have an active group, a cross-linking degree and a cross-linking density of the film are improved, and a water-vapor permeability is reduced; by adding the water blocking filler, the water blocking property of the film is further improved, thereby ensuring reliability of the assembly, and prolonging service life of the assembly.

Curable compositions, cured compositions, articles containing the curable or cured compositions, and methods of making the articles are provided. More particularly, the curable compositions contain a (meth)acrylate-based polymer having pendant (meth)acryloyl groups, at least one monomer having a single ethylenically unsaturated group, a photoinitiator that includes an acyl phosphine oxide, and a thixotropic agent. The curable compositions can be printed or dispensed, if desired, and the cured compositions are pressure-sensitive adhesives.

A pressure-sensitive adhesive comprising a polymer (X1) containing 48% by mass or more of a constituent unit derived from at least one monomer (Y) selected from the group consisting of a monomer (A1) represented by the following general formula (1) and a monomer (B1) represented by the following general formula (2), in which a tan δ (23° C.) determined as G″ (23° C.)/G′ (23° C.) is 0.8 to 1.3, wherein a storage elastic modulus and a loss coefficient at 23° C. are respectively represented by G′ (23° C.) and G″ (23° C.). In the formula (1), R.sup.1 represents H or CH.sub.3, R.sup.2 represents —C.sub.nH.sub.2n+1 and n represents an integer of 7 to 14. In the formula (2), R.sup.3 represents —C(═O)C.sub.mH.sub.2m+1 and m represents an integer of 7 to 13. Thus, retention force under high temperature, low-temperature attachability, and adhesiveness to a low-polar adherend are favorable along with a high bio rate.

A pressure-sensitive adhesive comprising a polymer (X1) containing 48% by mass or more of a constituent unit derived from at least one monomer (Y) selected from the group consisting of a monomer (A1) represented by the following general formula (1) and a monomer (B1) represented by the following general formula (2), in which a tan δ (23° C.) determined as G″ (23° C.)/G′ (23° C.) is 0.8 to 1.3, wherein a storage elastic modulus and a loss coefficient at 23° C. are respectively represented by G′ (23° C.) and G″ (23° C.). In the formula (1), R.sup.1 represents H or CH.sub.3, R.sup.2 represents —C.sub.nH.sub.2n+1 and n represents an integer of 7 to 14. In the formula (2), R.sup.3 represents —C(═O)C.sub.mH.sub.2m+1 and m represents an integer of 7 to 13. Thus, retention force under high temperature, low-temperature attachability, and adhesiveness to a low-polar adherend are favorable along with a high bio rate.

A crosslinking agent composition for water-compatible resins which comprises a hydrophobic crosslinking agent, a water-soluble organic compound, one or more oily media selected from among hydrocarbon-based solvents and ketone-based solvents having a solubility parameter of 9.0 (cal/cm.sup.−3).sup.1/2 or less, and an aqueous medium. The crosslinking agent composition can improve the storage stability of a water-compatible resin composition. The water-compatible resin composition which contains this crosslinking agent composition can give cured objects satisfactory in terms of water resistance and solvent resistance and is suitable also for use in wet-on-wet coating.

A vulcanizable rubber composition comprises an interpenetrating or ionic network (IPN)-promoting resin. The resin comprises side chain functional groups along the resin backbone, which, in the presence of an additive material, form the connections that make up the IPN. In one embodiment, such material is ZnO. A method for forming the rubber composition comprises, in a productive step, mixing the product of the non-productive step, the zinc oxide, and a resin derived from maleic anhydride. The zinc oxide and the resin are simultaneously added to the composition during the productive mixing stage. The rubber composition can be cured and incorporated in a tire component, such as, a tread.