Patent classifications
C08L23/286
Polyvinyl chloride-based resin molded product and method for manufacturing the same
The present invention provides a polyvinyl chloride-based resin molded product obtained by molding a resin mixture containing 1 to 50 parts by weight of calcium carbonate having an average primary particle size of 0.01 to 0.3 μm and 5 to 18 parts by weight of an impact modifier per 100 parts by weight of a polyvinyl chloride-based resin, wherein a Charpy impact strength at 0° C. is 20 kJ/m.sup.2 or more, and a Vicat softening temperature is 85° C. or higher, and a method for manufacturing the polyvinyl chloride-based resin molded product.
Husk Plastic Composite, Production Method and Application Thereof
A husk plastic composite comprises a composition including: PVC 10˜20 wt %; vinyl chloride/vinyl acetate (VC/VAC) copolymer 10˜30 wt %; styrene-acrylonitrile copolymer (SAN) 1˜5 wt %; chlorinated polyethylene (CPE) 1˜5 wt %; rice husk powder 10˜40 wt %; inorganic filler 10˜40 wt %; internal lubricant 0.1˜1 wt %; external lubricant 0.1˜1 wt %, and heat stabilizer 1˜5 wt %. The VC/VAC copolymer in the husk plastic composition provided by the present invention can allow the composition to be processed by relatively lower processing temperature to save energy consumption. It will also prevent the husk powder from being burnt or decomposed due to high temperature during the heating process to allow this natural material being added in a large amount in the composition. The present invention can reduce the amount of PVC through a large amount of filling additives but still maintain in good product mechanical properties. The particle size of the husk is preferably in the range of 0.10˜0.60 mm for better hardness, stiffness and wood-like texture in the final product.
Husk Plastic Composite, Production Method and Application Thereof
A husk plastic composite comprises a composition including: PVC 10˜20 wt %; vinyl chloride/vinyl acetate (VC/VAC) copolymer 10˜30 wt %; styrene-acrylonitrile copolymer (SAN) 1˜5 wt %; chlorinated polyethylene (CPE) 1˜5 wt %; rice husk powder 10˜40 wt %; inorganic filler 10˜40 wt %; internal lubricant 0.1˜1 wt %; external lubricant 0.1˜1 wt %, and heat stabilizer 1˜5 wt %. The VC/VAC copolymer in the husk plastic composition provided by the present invention can allow the composition to be processed by relatively lower processing temperature to save energy consumption. It will also prevent the husk powder from being burnt or decomposed due to high temperature during the heating process to allow this natural material being added in a large amount in the composition. The present invention can reduce the amount of PVC through a large amount of filling additives but still maintain in good product mechanical properties. The particle size of the husk is preferably in the range of 0.10˜0.60 mm for better hardness, stiffness and wood-like texture in the final product.
POLYETHYLENE AND CHLORINATED POLYETHYLENE THEREOF
The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having excellent processability and size stability during high-speed extrusion by optimizing a high-crystalline region in a molecular structure, and a CPE compound including the same.
POLYETHYLENE AND CHLORINATED POLYETHYLENE THEREOF
The present disclosure relates to a polyethylene, which is reacted with chlorine to prepare a chlorinated polyethylene having excellent processability and size stability during high-speed extrusion by optimizing a high-crystalline region in a molecular structure, and a CPE compound including the same.
METHOD FOR PREPARING BUTYRONITRILE RUBBER POWDER-BASED PVC THERMOPLASTIC ELASTOMER AND USE OF BUTYRONITRILE RUBBER POWDER-BASED PVC THERMOPLASTIC ELASTOMER IN PREPARING AUTOMOTIVE PARTS
A method for preparing a butyronitrile rubber powder-based polyvinyl chloride (PVC) thermoplastic elastomer and a use of the butyronitrile rubber powder-based PVC thermoplastic elastomer in preparing automotive parts are provided. The method includes: activating a wasted nitrile butadiene rubber (NBR) powder; plasticizing one of NBR and chloroprene rubber (CR) to obtain a plasticized rubber; dispersing the activated NBR fine rubber powder with one of PVC and chlorinated polyethylene (CPE) in a kneader evenly to obtain a mixture; adding the mixture and pine tar into the plasticized rubber, then mixing evenly to obtain a mixed plastic; adding various compounding agents into the mixed plastic and dispersing evenly to perform cross-linking reaction, thereby obtaining the butyronitrile rubber powder-based PVC thermoplastic elastomer. By using the wasted NBR powder as a main material, which turns waste into treasure and has low cost, and the butyronitrile rubber powder-based PVC thermoplastic elastomer has excellent comprehensive performance.
METHOD FOR PREPARING BUTYRONITRILE RUBBER POWDER-BASED PVC THERMOPLASTIC ELASTOMER AND USE OF BUTYRONITRILE RUBBER POWDER-BASED PVC THERMOPLASTIC ELASTOMER IN PREPARING AUTOMOTIVE PARTS
A method for preparing a butyronitrile rubber powder-based polyvinyl chloride (PVC) thermoplastic elastomer and a use of the butyronitrile rubber powder-based PVC thermoplastic elastomer in preparing automotive parts are provided. The method includes: activating a wasted nitrile butadiene rubber (NBR) powder; plasticizing one of NBR and chloroprene rubber (CR) to obtain a plasticized rubber; dispersing the activated NBR fine rubber powder with one of PVC and chlorinated polyethylene (CPE) in a kneader evenly to obtain a mixture; adding the mixture and pine tar into the plasticized rubber, then mixing evenly to obtain a mixed plastic; adding various compounding agents into the mixed plastic and dispersing evenly to perform cross-linking reaction, thereby obtaining the butyronitrile rubber powder-based PVC thermoplastic elastomer. By using the wasted NBR powder as a main material, which turns waste into treasure and has low cost, and the butyronitrile rubber powder-based PVC thermoplastic elastomer has excellent comprehensive performance.
Heat-resistant chlorine-containing crosslinked resin formed body and its production method, silane masterbatch and masterbatch mixture, and heat-resistant product
A method of producing a heat-resistant chlorine-containing crosslinked resin formed body, formed from: Step (a) of melt-mixing, to a base resin containing a chlorinated polyethylene and a polyvinyl chloride and a plasticizer, an organic peroxide, an inorganic filler, and a silane coupling agent, at a specific ratio, at a temperature equal to or higher than a decomposition temperature of the organic peroxide; Step (b) of mixing a silane masterbatch obtained in Step (a) and a silanol condensation catalyst; and Step (c) of crosslinking by bringing a formed body obtained by Step (b) into contact with water; wherein, in Step (a), from 5 to 55 mass % of the plasticizer is contained in 100 mass % of the base resin to be used in the reaction with the silane coupling agent; the formed body produced therefrom; a silane masterbatch and a mixture thereof; and a heat resistant product.
Heat-resistant chlorine-containing crosslinked resin formed body and its production method, silane masterbatch and masterbatch mixture, and heat-resistant product
A method of producing a heat-resistant chlorine-containing crosslinked resin formed body, formed from: Step (a) of melt-mixing, to a base resin containing a chlorinated polyethylene and a polyvinyl chloride and a plasticizer, an organic peroxide, an inorganic filler, and a silane coupling agent, at a specific ratio, at a temperature equal to or higher than a decomposition temperature of the organic peroxide; Step (b) of mixing a silane masterbatch obtained in Step (a) and a silanol condensation catalyst; and Step (c) of crosslinking by bringing a formed body obtained by Step (b) into contact with water; wherein, in Step (a), from 5 to 55 mass % of the plasticizer is contained in 100 mass % of the base resin to be used in the reaction with the silane coupling agent; the formed body produced therefrom; a silane masterbatch and a mixture thereof; and a heat resistant product.
CO-EXTRUSION SPC FOAM FLOORING AND MANUFACTURING METHOD THEREOF
A foam flooring includes a stone-plastic base material structure, which sequentially comprises, from top to bottom, a first stable layer, a foaming layer and a second stable layer. The first stable layer and the second stable layer are both sheets with a PVC resin and filler powder as main components, with 25-40 parts by mass of the PVC resin and 55-75 parts by mass of the filler powder; and the density of the SPC foam flooring is 1.4-1.6 g/cm3. The foaming layer is arranged between the two stable layers, such that the overall density of the flooring is significantly reduced and reaches 1.4-1.6 g/m3; since the foaming layer is arranged inside, the surface strength of the overall flooring is not influenced.