Provided is an excellent phthalocyanine crystal having high sensitivity and little fluctuation in sensitivity for a humidity change in a use environment and applicable to the martial for solar battery, electronic paper, electrophotographic photoreceptor, etc. Namely, phthalocyanine crystal obtained by bringing a phthalocyanine crystal precursor into contact with an aromatic aldehyde compound to convert the crystal form. Also, provided is an electrophotographic photoreceptor that not only exhibits high sensitivity but also has little fluctuation in sensitivity for a humidity change in a use environment. Further, provided is an electrophotographic photoreceptor cartridge and an image-forming device, both of which can produce a stable quality images for a humidity change in a use environment by using the electrophotographic photoreceptor.

An electrophotographic photosensitive member includes a support and a photosensitive layer in this order. The photosensitive layer contains a chlorogallium phthalocyanine crystal obtained by mixing a hydroxygallium phthalocyanine crystal and an aqueous hydrochloric acid solution.

The electrophotographic photosensitive member has: a cylindrical support; a charge generating layer formed on the cylindrical support; and a charge transport layer formed on the charge generating layer, the charge generating layer contains a hydroxygallium phthalocyanine crystal having a particular CuKα characteristic X-ray diffraction peak, a titanyl phthalocyanine crystal having a particular CuKα characteristic X-ray diffraction peak or a chlorogallium phthalocyanine crystal having a particular spectral absorption spectrum as a charge generating material, and in the charge generating layer, with respect to the film thickness of the charge generating layer, when a region from the central position of an image forming area to the end position of the image forming area is divided in the axial direction of the cylindrical support into five equal regions and the average film thickness of the charge generating layer in each region satisfies a specific condition.

There is provided a novel halogenated zinc phthalocyanine pigment for a color filter, which can form a green color filter having excellent contrast and high luminance. A halogenated zinc phthalocyanine pigment for a color filter shows, in a Raman spectrum, a peak intensity of 3.0% or more at 716±2.2 cm.sup.−1 when a peak intensity at 650±10 cm.sup.−1 is regarded as 100%.

The halogenated zinc phthalocyanine pigment is for use as a green pigment for color filters and capable of achieving high brightness. In the halogenated zinc phthalocyanine pigment, when a coating film containing 1.00 part by mass of the pigment, 0.95 parts by mass of a benzyl methacrylate-methacrylic acid copolymer, and 0.30 parts by mass of a dimethylaminoethyl methacrylate copolymer is heated at 230° C. for one hour to form an evaluation coating film having a thickness of 4 μm, an average scattering intensity at scattering angles 2θ in a range of 17° to 21° is determined from a two-dimensional scattering image obtained by GI-WAXS measurement of the evaluation coating film, and a normalized average scattering intensity is determined such that the average scattering intensity at an azimuth of 45° is 1, the normalized average scattering intensity at azimuths of 5° to 89° is 0.70 to 1.15.

A usual ink composition can be expected to improve ink viscosity to a certain degree, but when used for a glycol ether-based ink recently required, an increase in viscosity in preparing the ink cannot be suppressed. In addition, there is unknown a copper phthalocyanine pigment composition which can satisfy both such an improvement in ink viscosity and resolubility as printability which is important for the glycol ether-based ink. In this situation, a problem to be solved by the present invention is to provide a copper phthalocyanine pigment composition having low viscosity and excellent resolubility in a glycol ether-based ink. It was found that when a copper phthalocyanine pigment is combined with a specified copper phthalocyanine acid derivative, a pigment composition having significantly low viscosity when formed into a glycol ether-based ink, and good familiarity with the ink can be produced, leading to the achievement of the present invention.

It is an object of the present technology to overcome the disadvantages of conventional chlorination of a copper phthalocyanine which produces copper phthalocyanine, wherein the number of chlorines is less than than or equal to 4. The pigments described herein contain less chlorine than standard commercial grades of tetrachlorinated (or greater) copper phthalocyanine pigments while achieving similar color space, chromaticity, fastness properties, and color travel in automotive waterborne and solvent borne systems. The inventive pigments are more advantageous from a toxicity and environmental perspective, and allow the manufacturer to produce pigments in a safe and economical manner.

The electrophotographic photosensitive member has: a cylindrical support; a charge generating layer formed on the cylindrical support; and a charge transport layer formed on the charge generating layer, the charge generating layer contains a hydroxygallium phthalocyanine crystal having a particular CuK characteristic X-ray diffraction peak, a titanyl phthalocyanine crystal having a particular CuK characteristic X-ray diffraction peak or a chlorogallium phthalocyanine crystal having a particular spectral absorption spectrum as a charge generating material, and in the charge generating layer, with respect to the film thickness of the charge generating layer, when a region from the central position of an image forming area to the end position of the image forming area is divided in the axial direction of the cylindrical support into five equal regions and the average film thickness of the charge generating layer in each region satisfies a specific condition.

The present technology is directed to pigment compositions having a pure, or substantially pure, crystal form, containing less chlorine than standard tetrachlorinated copper phthalocyanine pigments, while giving similar color space, chromaticity, fastness properties, and color travel in automotive waterborne and solvent borne systems. These pigments are more advantageous from a toxicity and environmental perspective, and allow the manufacturer to produce pigments in a safe and economical manner.

It is an object of the present technology to overcome the disadvantages of conventional chlorination of a copper phthalocyanine which produces copper phthalocyanine, wherein the number of chlorines is less than than or equal to 4. The pigments described herein contain less chlorine than standard commercial grades of tetrachlorinated (or greater) copper phthalocyanine pigments while achieving similar color space, chromaticity, fastness properties, and color travel in automotive waterborne and solvent borne systems. The inventive pigments are more advantageous from a toxicity and environmental perspective, and allow the manufacturer to produce pigments in a safe and economical manner.