C09B67/0027

Method for producing quinacridone solid solution pigment, pigment dispersion, and inkjet ink

There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters. Specifically, a method for producing a quinacridone solid solution pigment, the method including a crude quinacridone solid solution production step of subjecting a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution containing a solid solution of an unsubstituted quinacridone and a 2,9-dialkylquinacridone, the solid solution containing water, a drying step of drying the water-containing crude quinacridone solid solution to reduce the water content to less than 1% and obtain a powdery, crude quinacridone solid solution, and a pigmentation step of heating the powdery, crude quinacridone solid solution in a liquid medium that cannot dissolve the crude quinacridone solid solution.

Method for producing quinacridone solid solution pigment, pigment dispersion, and inkjet ink

There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters. Specifically, a method for producing a quinacridone solid solution pigment, the method including a crude quinacridone solid solution production step of subjecting a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution containing a solid solution of an unsubstituted quinacridone and a 2,9-dialkylquinacridone, the solid solution containing water, a drying step of drying the water-containing crude quinacridone solid solution to reduce the water content to less than 1% and obtain a powdery, crude quinacridone solid solution, and a pigmentation step of heating the powdery, crude quinacridone solid solution in a liquid medium that cannot dissolve the crude quinacridone solid solution.

METHOD FOR PRODUCING QUINACRIDONE SOLID SOLUTION PIGMENT, PIGMENT DISPERSION, AND INKJET INK

There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters. Specifically, a method for producing a quinacridone solid solution pigment, the method including a crude quinacridone solid solution production step of subjecting a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution containing a solid solution of an unsubstituted quinacridone and a 2,9-dialkylquinacridone, the solid solution containing water, a drying step of drying the water-containing crude quinacridone solid solution to reduce the water content to less than 1% and obtain a powdery, crude quinacridone solid solution, and a pigmentation step of heating the powdery, crude quinacridone solid solution in a liquid medium that cannot dissolve the crude quinacridone solid solution.

SOLID SOLUTION OF QUINACRIDONE AND INK COMPOSITION CONTAINING SAME

An object to be achieved by the present, invention is to provide a quinacridone pigment having hue that is yellowish and clear and having excellent storage stability, wherein the quinacridone pigment can be advantageously used in an ink-jet ink and the like. Provided is a quinacridone solid solution pigment comprising at least C. I. Pigment Violet 19 and C. I. Pigment Red 122, wherein the ratio of a diffraction peak intensity at a diffraction angle 2 of 14.80.2 to a diffraction peak intensity at a diffraction angle 2 of 11.90.2 is 1.20 or less, as measured by X-ray diffractometry with respect to the quinacridone solid solution pigment.

METHOD FOR PRODUCING QUINACRIDONE SOLID-SOLUTION PIGMENT, PIGMENT DISPERSION, AND INK-JET INK
20200407563 · 2020-12-31 ·

The present invention relates to a technique for providing a quinacridone solid solution pigment, by which a quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue, and suitably, that has a controlled particle diameter and has the above-described, desired hue can be obtained. The present invention provides a method for producing a quinacridone solid solution pigment, wherein a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid are subjected to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution such that water is contained in a solid solution having a mass ratio of unsubstituted quinacridone to a 2,9-dialkylquinacridone of 85:15 to 60:40; the water-containing crude quinacridone solid solution obtained above is dried in a drying step, thereby obtaining a powdery, crude quinacridone solid solution having a water content of less than 1%; and the powdery, crude quinacridone solid solution is heated in a liquid medium that does not dissolve the crude quinacridone solid solution in a pigmentation step, and the present invention also provides a pigment dispersion liquid and an inkjet ink each containing the obtained quinacridone solid solution pigment.

METHOD FOR PRODUCING QUINACRIDONE SOLID SOLUTION PIGMENT, PIGMENT DISPERSION, AND INKJET INK

There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters. Specifically, a method for producing a quinacridone solid solution pigment, the method including a crude quinacridone solid solution production step of subjecting a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid to a co-cyclization reaction in polyphosphoric acid, thereby obtaining a water-containing crude quinacridone solid solution containing a solid solution of an unsubstituted quinacridone and a 2,9-dialkylquinacridone, the solid solution containing water, a drying step of drying the water-containing crude quinacridone solid solution to reduce the water content to less than 1% and obtain a powdery, crude quinacridone solid solution, and a pigmentation step of heating the powdery, crude quinacridone solid solution in a liquid medium that cannot dissolve the crude quinacridone solid solution.

Method for producing quinacridone solid-solution pigment, pigment dispersion, and ink-jet ink

A quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue and has a controlled particle diameter, and a method for producing the quinacridone solid solution pigment. In the method, a water-containing crude quinacridone solid solution is produced by a co-cyclization reaction of a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid in polyphosphoric acid, then the resulting water-containing crude quinacridone solid solution having a mass ratio of unsubstituted quinacridone to a 2,9-dialkylquinacridone of 85:15 to 60:40 is dried, thereby obtaining a powdery, crude quinacridone solid solution having a water content of less than 1%. Then, the resulting powdery, crude quinacridone solid solution is heated in a liquid medium that does not dissolve the crude quinacridone solid solution. Also, a pigment dispersion liquid and an inkjet ink each containing the obtained quinacridone solid solution pigment are provided.