A surface functionalizing method for use in high-throughput in situ synthesis of nucleic acids by 3D inkjet printing. The method includes subjecting a surface of a substrate to hydroxyl enrichment treatment; adding hydrophobic molecules to the surface of the substrate, the hydrophobic molecules being not reactive with phosphoramidite monomers; spraying, by a multi-channel piezoelectric inkjet head assembly, an etching ink to a predetermined area on the surface of the substrate for micro-etching, the etching ink being prepared with a fluoride compound reactive with the hydrophobic molecules; and adding hydrophilic molecules to the surface of the substrate. By using the method, a functionalized surface with given areas being patterned can be formed on the surface of the substrate, and then a same multi-channel piezoelectric inkjet head assembly can be directly used for subsequent high-resolution printing of phosphoramidite monomers and synthesis of nucleic acids.

The invention relates to a method for producing particles of mineral material comprising grinding of at least one mineral material in the presence of water. The grinding according to the invention is carried out in the presence of at least one polymer obtained by a radical polymerization reaction of a partial sodium salt of itaconic acid and partial decarboxylation of the polymer obtained followed by partial or total neutralization of the decarboxylated polymer. The invention also relates to an aqueous composition comprising particles of ground mineral material and such a polymer, in particular a mass-loading composition for the production of paper or a paper-coating-colour composition.

A precipitated silica suitable for thermal insulation applications and a process for its manufacture.

Compositions comprising Group 13 element-based coupling agents and/or aluminum-based substrates and methods for making such compositions are provided. Compositions herein further comprise an inorganic substrate, a functionalized polymer, or a combination thereof. Such compositions may further comprise a secondary coupling agent having two or more functional groups. Compositions comprising a particulate inorganic substrate dispersed in a polymer form composite materials having improved mechanical properties. Compositions comprising a monolithic inorganic substrate having at least one surface bonded to a polymer layer form articles having improved surface properties.

A method for producing a silica composite particle including a silica particle and at least one compound in which an aluminum atom bonds to an organic group through oxygen. The method includes: (i) providing a silica particle dispersion liquid having a silica particle content of about 20 mass % or more; (ii) mixing and reacting a compound represented by formula (S1) and the silica particle dispersion liquid to obtain a slurry; (iii) providing the at least one compound; and (iv) then mixing and reacting the slurry with the at least one compound to form the silica composite particle.

To improve storage stability of a resin composition used for applications such as a semiconductor sealing material. The resin composition is a resin composition that includes (A) an epoxy resin, (B) a curing agent, and (C) a silica filler. The silica filler of component (C) is surface-treated with a basic substance having a conjugate acid dissociation constant (pKa) of 9.4 or more. The resin composition further includes (D) a silane coupling agent, or the silica filler of component (C) is further surface-treated with a silane coupling agent.

Provided herein are surface treated pigments and methods of making and using the surface treated pigments. The surface treated pigments can comprise a mineral pigment surface treated with a hydrophilic latex composition and a hydrophobic material, which produce a film on an outer surface of the pigment. The hydrophobic material can be selected from a silane, a siloxane, or a siloxane/silicone resin blend, wax, fatty acid, styrene-butadiene latex, or a mixture thereof. The hydrophilic latex composition can be selected from a straight (meth)acrylic latex emulsion, a styrene-(meth)acrylic latex emulsion, or a blend thereof. The surface treated pigment has a surface energy that is less than a surface energy of the mineral pigment alone, a water contact angle of at least 90° and a dodecane contact angle of less than 150°.

The present invention relates to a process for preparing oxide particles, in particular metal oxide particles, coated with silicon oxide by means of flame spray pyrolysis technology, to oxide particles, in particular metal oxide particles, coated with silicon oxide, and to a composition comprising said particles. The present invention also relates to specific oxide particles, in particular metal oxide particles, coated with silicon oxide derived from such a process, to the compositions comprising such particles and also to the uses thereof.

Provided is a powder material for a cosmetic that has excellent dispersibility in any of silicone oil agents, hydrocarbon oil agents, and ester oil agents, and does not affect the color appearance of a formulation. The powder material for a cosmetic contains a powder for a cosmetic surface-treated with an ester compound of a fatty acid having 8-20 carbon atoms and glycerol. The ester compound is at least one selected from the group consisting of diglyceryl tetraisostearate, diglyceryl triisostearate, glyceryl tri(caprylate/caprate), glyceryl dilaurate, glyceryl triisostearate, decaglyceryl monoisostearate, and decaglyceryl diisostearate.

A fire retardant material includes a deconstructed nanoporous material including a plurality of elements, and solids of a fire-retarding solution within the elements of the nanoporous material. A method of forming the fire retardant material includes combining a nanoporous material and a fire-retarding solution such that elements of the nanoporous material absorb the fire retarding solution, and evaporating liquid from the elements of the nanoporous material having the fire-retarding solution absorbed therein such that a concentrate or solids thereof remain within the elements of the nanoporous material.