Patent classifications
C09D125/06
Optical film and image display device including same
The present invention relates to an optical film exhibiting excellent optical properties such as low gloss value and reflectance, and an appropriate level of haze properties, and to an image display device including the same. The optical film comprises: a light-transmitting substrate film; an antiglare layer including a binder containing a (meth)acrylate-based crosslinked polymer, and organic fine particles of a micron (μm) scale dispersed on the binder and inorganic fine particles of a nanometer (nm) scale dispersed on the binder; and a low refractive index layer which is formed on the antiglare layer and includes a binder resin containing a (co)polymer of a photopolymerizable compound, and hollow silica particles dispersed in the binder resin, wherein the organic and inorganic fine particles exhibit a predetermined particle size distribution, refractive index difference, and content range.
Optical film comprising a stretched resin film and a liquid crystal layer including a polyfunctional compound having two or more polymerizable groups in one molecule, circularly polarizing plate, and image display apparatus
Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.
Optical film comprising a stretched resin film and a liquid crystal layer including a polyfunctional compound having two or more polymerizable groups in one molecule, circularly polarizing plate, and image display apparatus
Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.
Method and composition for selectively modifying base material surface
A composition for use in selective modification of a base material surface includes a polymer having, at an end of a main chain or a side chain thereof, a group including a first functional group capable of forming a bond with a metal, and a solvent.
Method and composition for selectively modifying base material surface
A composition for use in selective modification of a base material surface includes a polymer having, at an end of a main chain or a side chain thereof, a group including a first functional group capable of forming a bond with a metal, and a solvent.
COMBINATION OF CROSSLINKERS TO IMPROVE COATING PROPERTIES
Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from -25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.
COMBINATION OF CROSSLINKERS TO IMPROVE COATING PROPERTIES
Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from -25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.
COMBINATION OF CROSSLINKERS TO IMPROVE COATING PROPERTIES
Multiphase polymers comprising crosslinking monomers and polyfunctional amine are disclosed. The multiphase polymer comprises a first phase polymer having a Tg from 60° C. to 240° C., a second phase polymer having a Tg from 40° C. to 240° C., and a soft phase polymer having a Tg from -25° C. to 30° C. The crosslinking monomers include a triacrylate such as trimethylol propane triacrylate, an unsaturated alkoxysilane, and an unsaturated keto monomer reactive with the polyfunctional amine. In contrast to conventional knowledge, incorporation of trimethylolpropane triacrylate reduces the minimum film forming temperature of multiphase polymers. This unusual reduction in MFFT helps to reduce the VOC requirement to form a good film at low VOC. The other crosslinking monomers including unsaturated alkoxy silane and unsaturated keto monomer which react with the polyfunctional amine improve print resistance, block resistance and lower the tackiness of paint films. The multiphase polymer is particularly suitable for use in deep base paints.
OPTICAL FILM, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY APPARATUS
Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.
OPTICAL FILM, CIRCULARLY POLARIZING PLATE, AND IMAGE DISPLAY APPARATUS
Provided are an optical film, a circularly polarizing plate, and an image display apparatus in each of which the occurrence of cracks is suppressed in the obtained film in a case of being punched. The optical film includes a stretched resin film and a liquid crystal layer formed by fixing a liquid crystal compound twist-aligned along a helical axis extending along a direction in thickness, in which a δa value calculated using a three-dimensional solubility parameter of a resin in the stretched resin film is 8.0 MPa.sup.1/2 or less, the liquid crystal layer contains a cured substance of a polyfunctional compound having two or more polymerizable groups in one molecule, and an absolute value of a difference between the δa value calculated using the three-dimensional solubility parameter of the polyfunctional compound and the δa value calculated using the three-dimensional solubility parameter of the resin is 4.0 MPa.sup.1/2 or less.