An apparatus and methods for using coatings for metal applications are disclosed. According to one embodiment, an article comprises a cured polymeric film having a first reaction product of a cationic photoinitiator and a compound suitable for cationic polymerization. The article has a second reaction product of a free-radical photoinitiator and a compound suitable for free-radical polymerization; The article has a metal substrate, wherein the cured polymeric film coats the metal substrate.

An apparatus and methods for using coatings for metal applications are disclosed. According to one embodiment, an article comprises a cured polymeric film having a first reaction product of a cationic photoinitiator and a compound suitable for cationic polymerization. The article has a second reaction product of a free-radical photoinitiator and a compound suitable for free-radical polymerization; The article has a metal substrate, wherein the cured polymeric film coats the metal substrate.

An apparatus and methods for using coatings for metal applications are disclosed. According to one embodiment, an article comprises a cured polymeric film having a first reaction product of a cationic photoinitiator and a compound suitable for cationic polymerization. The article has a second reaction product of a free-radical photoinitiator and a compound suitable for free-radical polymerization; The article has a metal substrate, wherein the cured polymeric film coats the metal substrate.

The present invention provides an aqueous polymer dispersion comprising at least one polymer having a carboxyl group and optionally an additional functional group selected from hydroxy, isocyanate, fluoro, phosphate, hydrazide, acetoacetate group and combination thereof, in which the polymer has a glass transition temperature of larger than −40° C. and less than 35° C., and the aqueous polymer dispersion has a solid content of larger than 50% by weight.

The present invention provides an aqueous polymer dispersion comprising at least one polymer having a carboxyl group and optionally an additional functional group selected from hydroxy, isocyanate, fluoro, phosphate, hydrazide, acetoacetate group and combination thereof, in which the polymer has a glass transition temperature of larger than −40° C. and less than 35° C., and the aqueous polymer dispersion has a solid content of larger than 50% by weight.

A copolymer is formed by reacting (A) aromatic monomer, an oligomer thereof, or a polymer thereof, with (B) aliphatic monomer, an oligomer thereof, or a polymer thereof. The aromatic monomer has a chemical structure of

##STR00001##

in which each of R.sup.1 is independently H or CH.sub.3, and n=1-4. R.sup.2 is a single bond, —O—,

##STR00002##

Each of R.sup.3 is independently

##STR00003##

An apparatus and methods for using coatings for metal applications are disclosed. According to one embodiment, an article comprises a cured polymeric film having a first reaction product of a cationic photoinitiator and a compound suitable for cationic polymerization. The article has a second reaction product of a free-radical photoinitiator and a compound suitable for free-radical polymerization; The article has a metal substrate, wherein the cured polymeric film coats the metal substrate.

An apparatus and methods for using coatings for metal applications are disclosed. According to one embodiment, an article comprises a cured polymeric film having a first reaction product of a cationic photoinitiator and a compound suitable for cationic polymerization. The article has a second reaction product of a free-radical photoinitiator and a compound suitable for free-radical polymerization; The article has a metal substrate, wherein the cured polymeric film coats the metal substrate.

A method of making a porous structure is described herein. The method includes combining a hard material comprising a carbonaceous material, an inorganic material, or a combination thereof, with a polymer blend to provide a mixture; and heating the mixture to a temperature effective to template the hard material, degrade the polymer blend and provide the porous structure comprising the hard material. Porous structures having a a solid continuous phase and a gaseous dispersed phase are also provided.

A method of making a porous structure is described herein. The method includes combining a hard material comprising a carbonaceous material, an inorganic material, or a combination thereof, with a polymer blend to provide a mixture; and heating the mixture to a temperature effective to template the hard material, degrade the polymer blend and provide the porous structure comprising the hard material. Porous structures having a a solid continuous phase and a gaseous dispersed phase are also provided.