Disclosed is a method for precipitating a polymer by adding a precipitation agent into a first suspension to form a second suspension; wherein the first suspension comprises a polymer and an aqueous solvent; and wherein the polymer comprises a copolymer comprising a structural unit derived from an acid group-containing monomer and a structural unit derived from a hydrophobic group-containing monomer. The method for precipitation of a polymer disclosed herein is developed to initiate the bond disruption and/or breakage between the polymer and the aqueous solvent within the second suspension. This is accompanied with the structural transformation of the polymer driven by the intermolecular and intramolecular interactions of the polymer chains which brings about the precipitation of the polymer. The method circumvents both complex separation process and contamination of the polymer, enables excellent materials recovery and allows the precipitation of the polymer to be achieved within a short time frame. An application of the method for precipitating a polymeric binder in a battery electrode is disclosed herein.

An undercoat agent including a block copolymer having a plurality of blocks bonded formed on a substrate. The undercoat agent contains a resin component that includes a structural unit having an aromatic ring and a structural unit having no aromatic ring, and the resin component includes a group which can interact with the substrate and does not include a 3 to 7-membered, ether-containing cyclic group; and a method of forming a pattern of a layer containing a block copolymer. The method includes applying an undercoat agent to a substrate to form a layer containing the undercoat agent; forming a layer containing a block copolymer having multiple blocks bonded on a surface of the layer containing the undercoat agent, followed by a phase separation of the layer containing the block copolymer; and selectively removing a phase containing at least one block of multiple blocks constituting the block copolymer.

An undercoat agent including a block copolymer having a plurality of blocks bonded formed on a substrate. The undercoat agent contains a resin component that includes a structural unit having an aromatic ring and a structural unit having no aromatic ring, and the resin component includes a group which can interact with the substrate and does not include a 3 to 7-membered, ether-containing cyclic group; and a method of forming a pattern of a layer containing a block copolymer. The method includes applying an undercoat agent to a substrate to form a layer containing the undercoat agent; forming a layer containing a block copolymer having multiple blocks bonded on a surface of the layer containing the undercoat agent, followed by a phase separation of the layer containing the block copolymer; and selectively removing a phase containing at least one block of multiple blocks constituting the block copolymer.

An aqueous ink for ink jet including a resin particle. The resin particle has a first layer and a second layer in this order from the inside toward the outside of the resin particle. The first layer is formed of a first resin in which the proportion of a unit derived from a cycloaliphatic-group-containing ethylenically unsaturated monomer is 10% by mass or less. The tetrahydrofuran-insoluble fraction of the second layer is 15% by mass or more. The second layer is formed of a second resin having the unit derived from the cycloaliphatic-group-containing ethylenically unsaturated monomer and a unit derived from an ionic-group-containing ethylenically unsaturated monomer. The proportion of the unit derived from the ionic-group-containing ethylenically unsaturated monomer in the second resin is 3% by mass or more to 70% by mass or less.

The present invention provides a curable composition having an excellent permeability to a porous substrate and a sufficient strength for use as a coating film, and also having a suitable curing time (set time), accordingly the curable composition having a pot life from the application until the completion of the permeation to pore portions. Particularly, the present invention also provides a favorable coating agent for surface reinforcement coating of a porous substrate. These objects can be achieved by using a curable composition containing the following (A) and (B): (A) a cyanoacrylate compound; and (B) a hydrofluoroether having such a structure that the number of carbon atoms substituted only with fluorine in the molecule is 1 or more to 6 or less, and the number of carbon atoms in the molecule is less than 7.

The present invention provides a curable composition having an excellent permeability to a porous substrate and a sufficient strength for use as a coating film, and also having a suitable curing time (set time), accordingly the curable composition having a pot life from the application until the completion of the permeation to pore portions. Particularly, the present invention also provides a favorable coating agent for surface reinforcement coating of a porous substrate. These objects can be achieved by using a curable composition containing the following (A) and (B): (A) a cyanoacrylate compound; and (B) a hydrofluoroether having such a structure that the number of carbon atoms substituted only with fluorine in the molecule is 1 or more to 6 or less, and the number of carbon atoms in the molecule is less than 7.

An object has a superhydrophic, self-cleaning, and icephobic coating includes a substrate and a layer disposed on the substrate, the layer resulting from coating with a formulation having an effective amount of microstructuring microparticles, liquid silane having one or more groups configured to graft to a microstructuring microparticle and at least another group that results in hydrophobicity. The microstructuring microparticles are dispersed in the liquid silane. Another effective amount of synthetic adhesive, selected from thermosetting adhesives, moisture curing adhesives or polymers that form a strong interaction with a surface, is in solution with a solvent. Upon curing, the layer has a contact angle greater than 90° and a sliding angle of less than 10° and, less than 5% of an area of the layer is removed in a Tape test.

An object has a superhydrophic, self-cleaning, and icephobic coating includes a substrate and a layer disposed on the substrate, the layer resulting from coating with a formulation having an effective amount of microstructuring microparticles, liquid silane having one or more groups configured to graft to a microstructuring microparticle and at least another group that results in hydrophobicity. The microstructuring microparticles are dispersed in the liquid silane. Another effective amount of synthetic adhesive, selected from thermosetting adhesives, moisture curing adhesives or polymers that form a strong interaction with a surface, is in solution with a solvent. Upon curing, the layer has a contact angle greater than 90° and a sliding angle of less than 10° and, less than 5% of an area of the layer is removed in a Tape test.

Provided is a method for recycling a battery electrode by immersing the electrode into a delamination solution and subsequently precipitating a polymeric binder with the addition of a precipitation agent; wherein the electrode comprises a current collector and an electrode layer material coated on one side or both sides of the current collector; wherein the electrode layer material comprises a polymeric binder; and wherein the polymeric binder comprises a copolymer comprising a structural unit derived from an acid group-containing monomer and a structural unit derived from a hydrogen bond-forming group-containing monomer (ii). The method disclosed herein circumvents complex separation process, corrosion of current collector and contamination of polymeric binder, enables excellent materials recovery and allows the recycling of battery electrode to be achieved in a highly efficient manner.

An object has a superhydrophic, self-cleaning, and icephobic coating includes a substrate and a layer disposed on the substrate, the layer resulting from coating with a formulation having an effective amount of microstructuring microparticles, liquid silane having one or more groups configured to graft to a microstructuring microparticle and at least another group that results in hydrophobicity. The microstructuring microparticles are dispersed in the liquid silane. Another effective amount of synthetic adhesive, selected from thermosetting adhesives, moisture curing adhesives or polymers that form a strong interaction with a surface, is in solution with a solvent. Upon curing, the layer has a contact angle greater than 90 and a sliding angle of less than 10 and, less than 5% of an area of the layer is removed in a Tape test.