A method using silicon dioxide improves the cathodic anticorrosion effect of ground coats, preferably of a zinc primer, based on epoxy-functional polymers and at least one metal particle.

A self-stratifying anticorrosive coating is described herein, including a zinc-rich epoxy, a curing agent chosen from the group consisting of amines, thiols, phenols, and carboxylic anhydrides, a binding agent chosen from the group consisting of aminoalkyl dialkoxysilane, dimethoxysilane, and aminoalkyl trialkoxysilane, a graphitic material, a solvent, a water scavenger, and a moisture-cured siloxane.

A process for preparing an anticorrosive coating includes providing a substrate, providing a sacrificial metal particle, chemically binding a graphitic material to a first molecule comprising a first group, a first spacer, and a second group, chemically binding said graphitic material to a second molecule comprising a third group, a second spacer, and a fourth group, wherein said third group is a different group from said first group, binding said sacrificial metal particle to either said first or said third group, binding either said first or said third group with said substrate, wherein said group bound to said substrate is different from said group bound to said sacrificial metal particle, chemically binding said second group and said fourth group to said graphitic material, growing thermoset resin side chains on said graphitic material, and growing siloxane side chains on said graphitic material.

The present invention relates to platelet-shaped zinc-magnesium pigments, wherein the platelet-shaped zinc-magnesium pigments comprise the 40.8 to 67.8 mol % of zinc, 32.2 to 59.2 mol % of magnesium and 0 to 7 mol % of Mn, Li, Be, Y, Sn, Al, Ti, Fe, Cu and mixtures thereof, based in each case on the total molar amount of the elements Zn, Mg, Mn, Be, Y, Li, Sn, Al, Ti, Fe and Cu, where the molar percentages add up to 100 mol %, and the median thickness h.sub.50 of the pigments is less than 1 μm. The invention further relates to the use and production of these pigments.

One or more techniques are disclosed for a method for functionalized a graphitic material comprising the steps of: 1) providing a graphitic material; 2) providing a first molecule comprising a first group, a spacer, and a second group; 3) providing a second molecule comprising a third group, a spacer, and a fourth group, wherein the third group is a different group from the first group; and 4) bonding the first molecule and the second molecule to the graphitic material. Also disclosed is a tunable material composition comprising the functionalized carbon nanotubes or functionalized graphene prepared by the methods described herein.

A laminate includes a layer containing a polyaniline-based polymer and a phenoxy-based resin, and a layer containing zinc and/or a zinc alloy, a laminate includes, in sequence, a layer containing a polyaniline-based polymer and a phenoxy-based resin, a layer containing zinc and/or a zinc alloy, and an aluminum or aluminum alloy layer. A rust prevention method includes forming a layer containing a polyaniline-based polymer and a phenoxy-based resin on a layer containing zinc and/or a zinc alloy or on a layer containing zinc and/or a zinc alloy disposed on an aluminum or aluminum alloy layer. The laminates and the rust prevention method are for reducing the formation of rust on the layer containing zinc and/or the zinc alloy or the aluminum or aluminum alloy layer for a long period of time.

A graphene anti-corrosion coating is described that comprises an epoxy resin and graphene subjected to surface modification, where the addition amount of the graphene is 0.01-0.2 wt % of the total mass of coating solid. By performing surface treatment on the graphene, the dispersity of the graphene in the coating is improved, and the compactness of the coating is enhanced.

A high temperature substrate coating to mitigate liquid metal embrittlement (LME) cracking in automobile vehicles includes a substrate. A coating is disposed on the substrate, the coating being one of a zinc-based material and an aluminum-based material, with the coating having a melting point of at least 500° C.

A process includes combining a copolymer and mono- or di-valent metal ions to form a mixture, wherein the copolymer has from about 70 to about 98 wt % of an alpha-olefin moiety and about 2 to about 30 wt % of a (meth)acrylate moiety; reactively extruding the mixture to form a neutralized copolymer having a melt flow index of from about 5 to about 1500 g/10 min, wherein about 2 to about 50 wt % of the (meth)acrylate moiety is neutralized to form a mono- or di-valent metal salt present in an amount of from about 0.2 to about 20% based on the total (meth)acrylic acid content of the copolymer; and grinding the neutralized copolymer to form the powder having a Dv50 particle size of from about 10 to about 600 μm as determined using ASTM D5861, wherein the process is free of utilizing a liquid and/or a slurry.

A layered tetravalent metal phosphate composition (e.g., a layered zirconium phosphate composition) and a first corrosion inhibitor (e.g., cerium (III), a vanadate, a molybdate, a tungstate, a manganous, a manganate, a permanganate, an aluminate, a phosphonate, a thiazole, a triazole, and/or an imidazole) is dispersed in an aqueous solution and stirred to form a first solution. A precipitate of the first solution is collected and washed to form a first corrosion inhibiting material (CIM), which includes the first corrosion inhibitor intercalated in the layered tetravalent metal phosphate composition. The first CIM is added to a first sol-gel composition to form a first CIM-containing sol-gel composition. The first CIM-containing sol-gel composition is applied on a substrate to form a CIM-containing sol-gel layer, cured by UV radiation, and thermally cured to form a corrosion-resistant coating. One or more additional sol-gel composition may be applied on the substrate.