The invention relates to a surfactant comprising a grafted rosin ester which is a rosin ester grafted with a capped polyalkylene glycol, wherein the capped polyalkylene glycol is a polyalkylene glycol capped by an alkyl ether and an aqueous dispersion consisting of an aqueous phase and resin particles dispersed in the aqueous phase, wherein the dispersion comprises the surfactant according to the invention.

The invention relates to a surfactant comprising a grafted rosin ester which is a rosin ester grafted with a capped polyalkylene glycol, wherein the capped polyalkylene glycol is a polyalkylene glycol capped by an alkyl ether and an aqueous dispersion consisting of an aqueous phase and resin particles dispersed in the aqueous phase, wherein the dispersion comprises the surfactant according to the invention.

The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters which derived from rosin and or hydrogenated rosin reacted with an epihalohydrin. The above glycidyl esters compositions can be used for example, as monomer in binder compositions for paints or adhesives, as reactive diluent or as acid scavenger. This invention is also about the uses of rosin and or hydrogenated rosin glycidyl ester in combinations with polyester polyols, or acrylic polyols, or polyether polyols.

The invention relates to compositions of α,α-branched alkane carboxylic acids glycidyl esters which derived from rosin and or hydrogenated rosin reacted with an epihalohydrin. The above glycidyl esters compositions can be used for example, as monomer in binder compositions for paints or adhesives, as reactive diluent or as acid scavenger. This invention is also about the uses of rosin and or hydrogenated rosin glycidyl ester in combinations with polyester polyols, or acrylic polyols, or polyether polyols.

Disclosed are compositions comprising dimeric decarboxylated rosins (DDCRs), methods for making them, and applications thereof. DDCR of purity from 50-100 wt. % is obtained by decarboxylating a dimeric rosin acid or by dimerizing a decarboxylated rosin, in the presence of a catalyst, followed by one or more purification steps separation on differences in boiling point. The isolated DDCR fractions display unexpectedly high T.sub.g/M.sub.n ratios, softening points and viscosities, and low polydispersities. The DDCR product comprises 50 to 100 wt. % of polycyclic hydrocarbon compounds having one or more aliphatic, unsaturated or aromatic groups, and 34-80 carbon atoms, with a molecular weight M.sub.n of 250-900 Da, and an oxygen to carbon ratio of <5%. The DDCR product has at least 50%, and up to 100% as dimeric species, with the remainder being trimeric and larger polymeric species.

A process for a continuous condensation reaction with feedstocks derived from bio-renewable resources, e.g., pine chemical derived feedstock, is disclosed. The process employs at least a multi-stage mixing reactor, selected from any of a multi-stage continuous stirred tank reactor (CSTR), a multi-stage horizontal continuous stirred tank reactor (HCSTR), or a continuous oscillating baffle reactor (COBR). The multi-stage mixing reactors are provided with a plurality of baffles for creating a mixing in a number of stages or cells created by the baffles, allowing the condensation reaction to proceed at a production rate at least twice that of a batch process with reactors of equivalent volume. The feedstocks derived from bio-renewable resources is selected from gum rosin, wood rosin, tall oil rosin and mixtures thereof; and polymeric fatty acids derived from bio-renewable resources such as tall oil.

A process for a continuous condensation reaction with feedstocks derived from bio-renewable resources, e.g., pine chemical derived feedstock, is disclosed. The process employs at least a multi-stage mixing reactor, selected from any of a multi-stage continuous stirred tank reactor (CSTR), a multi-stage horizontal continuous stirred tank reactor (HCSTR), or a continuous oscillating baffle reactor (COBR). The multi-stage mixing reactors are provided with a plurality of baffles for creating a mixing in a number of stages or cells created by the baffles, allowing the condensation reaction to proceed at a production rate at least twice that of a batch process with reactors of equivalent volume. The feedstocks derived from bio-renewable resources is selected from gum rosin, wood rosin, tall oil rosin and mixtures thereof; and polymeric fatty acids derived from bio-renewable resources such as tall oil.

Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.

Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.

The instant invention relates to a method for purifying a rosin-containing material from sulfur compounds. In particular the method comprises a) contacting a rosin-containing material comprising rosin and sulfur compounds with an oxidizing agent at a temperature from 0 to 60° C. for 10 minutes to 3 hours, to oxidize at least part of the sulfur compounds; and b) separating the rosin from the oxidized sulfur compounds; to obtain a purified rosin-containing material. The invention also relates to the purified rosin-containing materials, the preparation of products derived therefrom and the use of the purified rosin-containing materials and derived products.