A present invention related to a method for manufacturing a dot bonding shoe insole using an adhesive resin containing hydrophobic nano-silica, including: melting adhesive resin made of any one selected from thermoplastic polyurethane (TPU) or ethylene vinyl acetate (EVA) containing hydrophobic nano-silica in the range of 0.2 to 5 phr and applying to the surface of the transfer roller in which the intaglio dot pattern is formed in a mesh shape in the shape of the shoe insole;

removing the adhesive resin applied other area than the intaglio dot pattern of the surface of the transfer roller;
transferring the adhesive resin applied to the intaglio dot pattern of the surface of the transfer roller to either one of the foam or the fabric;
bonding the foam and the fabric by compressing; and
cutting a shoe insole shape in a package in which the foam and the fabric are bonded.

Aspects of the present disclosure provide for composite structures including a bonding layer that adheres a substrate (e.g., including a polymeric composition such as rubber) to a material (e.g., including a polymer such as polyurethane). The adhesion of the substrate to the material through the bonding layer can include chemical bonds such as, but not limited to, siloxane linkages, silanol linkages, silyl linkages, or any combination thereof in the bonding layer.

Aspects of the present disclosure provide for composite structures including a bonding layer that adheres a substrate (e.g., including a polymeric composition such as rubber) to a material (e.g., including a polymer such as polyurethane). The adhesion of the substrate to the material through the bonding layer can include chemical bonds such as, but not limited to, siloxane linkages, silanol linkages, silyl linkages, or any combination thereof in the bonding layer.

A method of manufacturing at least a part of a footwear in an automatic manufacturing line includes providing a footwear part in the form of a leather base layer, providing a footwear part in the form of a leather attachment layer, automatically stacking the leather base layer and the leather attachment layer against each other with an intermediate application of adhesive between them, automatically activating the adhesive, automatically forcing the leather base layer and the leather attachment layer against each other under a pressure with the adhesive between them, curing the adhesive and thereby bonding the leather base layer and the leather attachment layer to each other thereby providing at least a part of a footwear upper.

Two part sole structures are provided having a first foam component containing a polyolefin resin with a polyurethane resin component adhered to a surface of the first foam component. For example, in some aspects, a sole structure or a portion thereof is provided having a first sole component containing a foam composition and a second sole component adhered to a surface of the first sole component, where the second sole component includes a polyurethane resin. The second sole component is in some aspects printed or extruded onto the surface of the foam. In particular, midsoles including the foams and having an outsole component on the ground facing portion are provided for use in an article of footwear. Methods of making the sole structures are provided, as well as methods of making an article of footwear including one of the sole structures.

A method of manufacturing a footwear includes the steps of providing a leather base layer and providing a leather attachment layer. The leather base layer and the leather attachment layer are fixed against each other with an intermediate application of adhesive between them. The applied adhesive is activated. The leather base layer and the leather attachment layer are forced against each other under a pressure with the adhesive between them. The adhesive is cured and thereby the leather base layer and the leather attachment layer are bonded to each other. The bonded leather base layer and the leather attachment layer are integrated as part of the footwear.

Curable compositions include a urethane (meth)acrylate oligomer having a number—average molecular weight of at least 6000 g/mol; at least one mono(meth)acrylate monomer; a multifunctional crosslinking monomer chosen from acrylate monomers, methacrylate monomers, or combinations thereof; and an ethylene-vinyl acetate grafted terpolymer. The mono(meth)acrylate monomers may include a first mono(meth)acrylate with Tg between 50° C. and 175° C. and a second mono(meth)acrylate with Tg between −50° C. and 30° C. The curable compositions may be applied onto a surface of a substrate then cured to form a low-tack adhesive layer on the surface. The curable compositions may be cured by exposure to visible radiation, UV radiation, LED radiation, laser radiation, electron-beam radiation, peroxide, accelerator, or heat. Methods for bonding substrates include contacting a second substrate to a tow-tack adhesive layer on a first substrate, then heating the low-tack adhesive layer to bond the substrates and form a laminate.

Curable compositions include a urethane (meth)acrylate oligomer having a number—average molecular weight of at least 6000 g/mol; at least one mono(meth)acrylate monomer; a multifunctional crosslinking monomer chosen from acrylate monomers, methacrylate monomers, or combinations thereof; and an ethylene-vinyl acetate grafted terpolymer. The mono(meth)acrylate monomers may include a first mono(meth)acrylate with Tg between 50° C. and 175° C. and a second mono(meth)acrylate with Tg between −50° C. and 30° C. The curable compositions may be applied onto a surface of a substrate then cured to form a low-tack adhesive layer on the surface. The curable compositions may be cured by exposure to visible radiation, UV radiation, LED radiation, laser radiation, electron-beam radiation, peroxide, accelerator, or heat. Methods for bonding substrates include contacting a second substrate to a tow-tack adhesive layer on a first substrate, then heating the low-tack adhesive layer to bond the substrates and form a laminate.

Two part sole structures are provided having a first foam component containing a polyolefin resin with a polyurethane resin component adhered to a surface of the first foam component. For example, in some aspects, a sole structure or a portion thereof is provided having a first sole component containing a foam composition and a second sole component adhered to a surface of the first sole component, where the second sole component includes a polyurethane resin. The second sole component is in some aspects printed or extruded onto the surface of the foam. In particular, midsoles including the foams and having an outsole component on the ground facing portion are provided for use in an article of footwear. Methods of making the sole structures are provided, as well as methods of making an article of footwear including one of the sole structures.

An uncured or partially cured foxing tape (10) comprises: a two-layer structure of a base foxing tape (11) and an uncrosslinked or partially crosslinked adhesive (12), wherein the base foxing tape (11) comprises an uncured or partially cured rubber, wherein the base foxing tape (11) has a first side and a second side opposite the first side, wherein the uncrosslinked or partially crosslinked adhesive (12) is in contact with the uncured or partially cured rubber on the second side of the base foxing tape (11), wherein the uncrosslinked or partially crosslinked adhesive (12) comprises: an uncured or partially cured rubber; a tackifying resin; and a filler.