A label having a silicone-free (water-based) release coating and compatible adhesive patch is provided. The label includes a thermally coated substrate having a silicone-free substrate overlaid thereon of a first surface. A second surface includes a microsphere adhesive layer.

A biodegradable cellulose fiber-based substrate, at least one side of which is coated with a release coating including: a) at least one water-soluble polymer (WSP) containing hydroxyl groups, and b) at least one lactone substituted with at least one linear or branched and/or cyclic C.sub.8-C.sub.30 hydrocarbon chain which may contain heteroatoms. The biodegradable substrate is certified biodegradable in accordance with EN 13432. A method of production thereof is also disclosed.

A label having a silicone-free (water-based) release coating and compatible adhesive patch is provided. The label includes a thermally coated substrate having a silicone-free substrate overlaid thereon of a first surface. A second surface includes a microsphere adhesive layer.

An adhesive label with a water-based release coating and methods for applying the water-based release coating to the adhesive label are provided. The water-based release coating is a non-silicon based formulation having a fluorochemical. The water-based release coating can be applied in a single-pass process or a double-pass process when manufacturing the adhesive label.

A biodegradable cellulose fiber-based substrate, at least one side of which is coated with a release coating including: a) at least one water-soluble polymer (WSP) containing hydroxyl groups, and b) at least one lactone substituted with at least one linear or branched and/or cyclic C.sub.8-C.sub.30 hydrocarbon chain which may contain heteroatoms. The biodegradable substrate is certified biodegradable in accordance with EN 13432. A method of production thereof is also disclosed.

A label having a silicone-free (water-based) release coating and compatible adhesive patch is provided. The label includes a thermally coated substrate having a silicone-free substrate overlaid thereon of a first surface. A second surface includes a microsphere adhesive layer.

A label having a silicone-free (water-based) release coating and compatible adhesive patch is provided. The label includes a thermally coated substrate having a silicone-free substrate overlaid thereon of a first surface. A second surface includes a microsphere adhesive layer.

An adhesive label with a water-based release coating and methods for applying the water-based release coating to the adhesive label are provided. The water-based release coating is a non-silicon based formulation having a fluorochemical. The water-based release coating can be applied in a single-pass process or a double-pass process when manufacturing the adhesive label.

An adhesive label with a water-based release coating and methods for applying the water-based release coating to the adhesive label are provided. The water-based release coating is a non-silicon based formulation having a fluorochemical. The water-based release coating can be applied in a single-pass process or a double-pass process when manufacturing the adhesive label.

A recyclable web of media for batch printing labels includes a recyclable label media which includes a substrate to accept printing on a first side of the substrate. An adhesive or pattern of adhesive is deposited on a second surface of the substrate opposite the first side of the substrate. A recyclable backing structure includes a print label backer material. A recyclable release layer coats one surface of the print label backer material. The recyclable backing structure is non-permanently and removably affixed to a surface of the adhesive or pattern of adhesive.