The present disclosure provides methods and systems for composite-to-metal hybrid bonded structures compromising the laser surface treatment on titanium alloys to promote adhesive bond performance. For example, a computer may be programmed to set a laser path corresponding to a predetermined geometric pattern. A laser may be coupled to the computer and apply a pulsed laser beam to a contact surface of the titanium alloy along the predefined geometric pattern. The laser may generate an open pore oxide layer on the contact surface of the substrate with a thickness of 100 and 500 nm. The open pore oxide layer may have a topography corresponding to the predefined geometric pattern. The topography may contain high degree of open pore structure and promote adhesive bond performance. Adhesive, primer or composite resin matrix may fully infiltrate into the open pore structures. Adhesive and composite laminate may co-cure to form composite-to-titanium hybrid bonded structures.

A method for surface preparation of composite substrates prior to adhesive bonding. A curable surface treatment layer is applied onto a curable, resin-based composite substrate, followed by co-curing. After co-curing, the composite substrate is fully cured but the surface treatment layer remains partially cured. The surface treatment layer may be a resin film or a removal peel ply composed of resin-impregnated fabric. After surface preparation, the composite substrate is provided with a chemically-active, bondable surface that can be adhesively bonded to another composite substrate to form a covalently-bonded structure.

A method for surface preparation of composite substrates prior to adhesive bonding. A curable surface treatment layer is applied onto a curable, resin-based composite substrate, followed by co-curing. After co-curing, the composite substrate is fully cured but the surface treatment layer remains partially cured. The surface treatment layer may be a resin film or a removal peel ply composed of resin-impregnated fabric. After surface preparation, the composite substrate is provided with a chemically-active, bondable surface that can be adhesively bonded to another composite substrate to form a covalently-bonded structure.

A manufacturing method of an adhesive layer includes: providing a preliminary adhesive layer, attaching a mask to a first area portion of the preliminary adhesive layer, and thereby, provide a second area portion of the preliminary adhesive layer that is adjacent to the first area portion and to which the mask is not attached, to provide an adhesive layer that exhibits good folding reliability. In addition, a display device may exhibit good folding reliability characteristics by including the adhesive layer from which an adhesion force of a folding area is reduced between a supporting member and a display panel of the display device.

The invention relates a process for the preparation of a bonded structure (4) comprising at least a first plastic part (1) having a first bonding surface (1a), said process comprising the step of a) treating at least part of a first bonding surface of said first plastic part with a flame of a propane-comprising gas, said propane-comprising gas being propane or a mixture comprising at least 50 wt. % of propane based on the weight of the propane-comprising gas with one or more gases selected from the group consisting of methane, ethane, butane, pentane, and hexane, wherein, during treatment with a flame of the propane-comprising gas, a flame is produced by burning a mixture of air and the propane-comprising gas, wherein the gas-to-air ratio is chosen such that the propane gas to oxygen volume ratio is equal to or less than 1:5.01, for example less than 1:5.00 and preferably at least 3.50 to obtain a first plastic part having a flame-treated first bonding surface.

Where printing plate is to be secured to a plate cylinder by means of double-sided adhesive tape, the surface of the printing plate to be secured to the plate cylinder is, prior to bonding, partially pre-treated by means of a low-temperature plasma pencil after cleaning with isopropanol.

Where printing plate is to be secured to a plate cylinder by means of double-sided adhesive tape, the surface of the printing plate to be secured to the plate cylinder is, prior to bonding, partially pre-treated by means of a low-temperature plasma pencil after cleaning with isopropanol.

The present disclosure provides methods for forming sol-gels, sol-gel films and substrates, such as vehicle components, having a sol-gel film disposed thereon. At least one method of forming a sol-gel includes mixing a metal alkoxide, an acid stabilizer, and an organic solvent to form a first mixture having about 10 wt % or less water content based on the total weight of the first mixture. The method includes mixing an organosilane with the first mixture to form a second mixture having about 10 wt % or less water content based on the total weight of the second mixture.

The present disclosure provides methods for forming sol-gels, sol-gel films and substrates, such as vehicle components, having a sol-gel film disposed thereon. At least one method of forming a sol-gel includes mixing a metal alkoxide, an acid stabilizer, and an organic solvent to form a first mixture having about 10 wt % or less water content based on the total weight of the first mixture. The method includes mixing an organosilane with the first mixture to form a second mixture having about 10 wt % or less water content based on the total weight of the second mixture.

Provided is an aqueous composition comprising dispersed particles that comprise a polyurethane, wherein said polyurethane is a reaction product of a group of reactants (GR1), wherein GR1 comprises one or more aromatic polyisocyanates and, a polyol component, wherein said polyol component comprises (a) 50% to 99% by weight, based on the weight of said polyol component, one or more polyester polyols, (b) 0.1% to 10% by weight, based on the weight of said polyol component, one or more diols having a hydrophilic side chain, and (c) 0.9% to 40% by weight, based on the weight of said polyol component, one or more polyols different from (a) and (b). Also provided is a method of bonding a metal foil to a polymer film using such an aqueous composition.