A compound of the general formula (I): A.sub.3BF.sub.2M.sub.1−xT.sub.xO.sub.2−2xF.sub.4+2x doped with Mn(IV), in which A is selected from the group consisting of Li, Na, K, Rb, Cs, Cu, Ag, Tl, NH4, NR4 and mixtures of two or more thereof, where R is an alkyl or aryl group, B is selected from the group consisting of H and D and mixtures thereof, where D is Deuterium, M is selected from the group consisting of Cr, Mo, W, Te, Re and mixtures of two or more thereof, T is selected from the group consisting of Si, Ge, Sn, Ti, Pb, Ce, Zr, Hf and mixtures of two or more thereof, and 0≤x≤1.

Disclosed is a composite particle for use in a marking that is suitable for identification/authentication purposes. The particle comprises at least one superparamagnetic portion and at least one thermoluminescent portion coated with an thermoisolating portion. Optionally also a thermoconductive portion between the superparamagnetic and thermoluminscent portions.

A luminophore may have the general formula A.sub.2EZ.sub.zX.sub.x:RE,

where: A is selected from the group of the monovalent elements; E is selected from the group of the tetravalent, pentavalent, or hexavalent elements; Z is selected from the group of the divalent elements; X is selected from the group of the monovalent elements; RE is selected from activator elements; 2+e=2z+x, with the charge number e of the element E; and x+z=5 and z>0.

A process is also disclosed that is directed to producing the luminophore and a corresponding radiation-emitting component.

To provide an oxide fluorescent material that has a light emission peak wavelength in a wavelength range of from red light to near infrared light. The oxide fluorescent material has a composition encompassed in a compositional formula represented by the following formula (1):

(Li.sub.1-tM.sup.1.sub.t).sub.u(Ga.sub.1-vM.sup.2.sub.v).sub.5O.sub.w:Cr.sub.x,Ni.sub.y,M.sup.3.sub.z,  (1)

wherein in the formula (1), M.sup.1 represents at least one kind of an element selected from the group consisting of Na, K, Rb, and Cs; M.sup.2 represents at least one kind of an element selected from the group consisting of B, Al, Sc, In, and a rare earth element; M.sup.3 represents at least one kind of an element selected from the group consisting of Si, Ge, Sn, Ti, Zr, Hf, Bi, V, Nb, and Ta; and t, u, v, w, x, y, and z each satisfy 0≤t≤1.0, 0.7≤u≤1.6, 0≤v<1.0, 7.85≤w≤11.5, 0.05≤x≤1.2, 0≤y≤0.5, 0.25<x+y≤1.2, y<x, and 0≤z≤0.5.

A light emitting device includes a light source that emits a primary light having a light energy density exceeding 0.5W/mm.sup.2, and a first phosphor that absorbs the primary light to convert the primary light into a first wavelength-converted light having a wavelength longer than that of the primary light. The first phosphor includes a compound serving as a host, the compound being a simple oxide including one kind of metal element or a composite oxide including a plurality of different kinds of the simple oxide as an end member. When an energy conversion value at a peak wavelength of the primary light is E1 electron volts and an energy conversion value at a fluorescence peak wavelength of the first wavelength-converted light is E2 electron volts, a bandgap energy of a crystal of the simple oxide is larger than a sum of the E1 electron volts and the E2 electron volts.

An oxide fluorescent material comprises: at least one first element M.sup.1 selected from Li, Na, K, Rb, and Cs; at least one second element M.sup.2 selected from Mg, Ca, Sr, Ba, and Zn; at least one third element M.sup.3 selected from B, Al, Ga, In, and rare earth elements; at least one fourth element M.sup.4 selected from Si, Ti, Ge, Zr, Sn, Hf, and Pb; O; and Cr, wherein when the molar ratio of the at least one fourth element M.sup.4 in 1 mol of the composition is 5, the molar ratio of the at least one first element M.sup.1 is 0.7 or more and 1.3 or less, the molar ratio of the at least one second element M.sup.2 is 1.5 or more and 2.5 or less, the molar ratio of the at least one third element M.sup.3 is 0.7 or more and 1.3 or less, the molar ratio of oxygen is 12.9 or more and 15.1 or less, and the molar ratio of Cr is more than 0 and 0.2 or less, and wherein the oxide fluorescent material has a light emission peak wavelength in a range of 700 nm or more and 1,050 nm or less in a light emission spectrum of the oxide fluorescent material.

Disclosed is a composite particle for use in a marking that is suitable for identification/authentication purposes. The particle comprises at least one superparamagnetic portion and at least one thermoluminescent portion and optionally also a thermoconductive portion between the superparamagnetic and thermoluminscent portions.

The present invention discloses a red light and near-infrared light-emitting material and a light-emitting device. The red light and near-infrared light-emitting material contains a compound represented by a molecular formula, xA.sub.2O.sub.3.Math.yIn.sub.2O.sub.3.Math.bR.sub.2O.sub.3, wherein the element A is Sc and/or Ga; the element R is one or two of Cr, Yb, Nd or Er and necessarily includes Cr; and 0.001≤x≤1, 0.001≤y≤1, 0.001≤b≤0.2, and 0.001≤b/(x+y)≤0.2. The light-emitting material can be excited by a technically mature blue light source to emit light with a high-intensity wide-spectrum or multiple spectra. Compared with existing materials, the light-emitting material has higher luminescent intensity. The light-emitting device uses an LED chip to combine an infrared light-emitting material and a visible light light-emitting material. In this way, the same LED chip can emit near-infrared light and visible light at the same time, which greatly simplifies the packaging process and reduces the packaging cost.

The present invention discloses a red light and near-infrared light-emitting material and a light-emitting device. The red light and near-infrared light-emitting material contains a compound represented by a molecular formula, xA.sub.2O.sub.3.yIn.sub.2O.sub.3.bR.sub.2O.sub.3, wherein the element A is Sc and/or Ga; the element R is one or two of Cr, Yb, Nd or Er and necessarily includes Cr; and 0.001≤x≤1, 0.001≤y≤1, 0.001≤b≤0.2, and 0.001≤b/(x+y)≤0.2. The light-emitting material can be excited by a technically mature blue light source to emit light with a high-intensity wide-spectrum or multiple spectra. Compared with existing materials, the light-emitting material has higher luminescent intensity. The light-emitting device uses an LED chip to combine an infrared light-emitting material and a visible light light-emitting material. In this way, the same LED chip can emit near-infrared light and visible light at the same time, which greatly simplifies the packaging process and reduces the packaging cost.

The purpose of the present invention is to increase the amount of near-infrared light emitted by a phosphor excited by near-ultraviolet light to blue light. The present invention relates to a phosphor containing gallium oxide Ga.sub.2O.sub.3 as the base composition, one or two elements selected from Cr and Fe as the light-emitting center, and aluminum fluoride AlF.sub.3 as the flux.