The use of a heat-transfer composition including at least one refrigerant chosen from halogenated hydrocarbons, perhalogenated hydrocarbons, fluorinated ketones, fluorinated ethers and also combinations thereof, and at least one dielectric fluid, for cooling a battery of an item of equipment, such as an electric or hybrid vehicle, the heat-transfer composition having a volume resistivity of greater than or equal to 106 Ω.Math.cm at 25° C.

The present application relates to compositions comprising difluoromethane (R-32), 1,1,1,2-tetrafluoroethane (R-134a), and trifluoroiodomethane (CF3I), that are useful in refrigeration, air conditioning, or heat pump systems. Methods of replacing a refrigerant selected from R-410A, R-22, and R-134a in refrigeration, air conditioning, or heat pump systems are also provided.

A heat exchange unit is provided with which, even if a flammable refrigerant is used, the likelihood of the refrigerant reaching an electric component unit is reduced. An outdoor unit (20) constitutes a portion of an air-conditioning apparatus (1), and is connected to an indoor unit (30) via a liquid-side refrigerant connection pipe (6) and a gas-side refrigerant connection pipe (5). The outdoor unit (20) includes an outdoor housing (50), an outdoor heat exchanger (23) disposed inside the outdoor housing (50) and in which a refrigerant flows, a liquid-side shutoff valve (29) connected to the liquid-side refrigerant connection pipe (6), a gas-side shutoff valve (28) connected to the gas-side refrigerant connection pipe (5), and an outdoor electric component unit (8) disposed inside the outdoor housing (50). The refrigerant is a flammable refrigerant containing at least 1,2-difluoroethylene. When the outdoor unit (20) is in its installed state, the lower end of the outdoor electric component unit (8) is positioned above the liquid-side shutoff valve (29) and the gas-side shutoff valve (28).

To provide a working medium for heat cycle which has less influence over the ozone layer, which has less influence over global warming and which provides a heat cycle system excellent in the cycle performance (the efficiency and the capacity), and a heat cycle system excellent in the cycle performance (the efficiency and the capacity). A working medium for heat cycle comprising 1,2-difluoroethylene is employed for a heat cycle system (such as a Rankine cycle system, a heat pump cycle system, a refrigerating cycle system 10 or a heat transport system).

The present invention provides a composition, such as a refrigerant composition comprising 1, 1-difluoroethene (vinylidene fluoride, R-1132a); trifluoromethane (R-23); and one or more compound selected from hexafluoroethane (R-116), ethane (R-170) and carbon dioxide (R-744, CO.sub.2).

The present disclosure relates to compositions comprising Z-1,1,1,4,4,4-hexafluoro-2-butene and additional compounds that may be useful as refrigerants, heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or vapor form.

The present disclosure relates to compositions comprising E-1,1,1,4,4,4-hexafluoro-2-butene and additional compounds that may be useful as refrigerants, heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, power cycle working fluids, extinguishing agents, and fire suppression agents in liquid or vapor form, and in methods for detecting leaks.

The invention relates a method for preparing a composition with low corrosive effect and low freezing point, by mixing an ammonium cation source with a carboxyl anion source in an appropriate molar or weight ratio, either without a medium or by using an appropriate medium for obtaining liquid or water-soluble organic ammonium carboxylate of formula (1):

[NR.sup.1R.sup.2R.sup.3R.sup.4].sup.+.sub.n [R.sup.5(COO).sub.n].sup.−n,   (1),

in which R.sup.1, R.sup.2, and R.sup.3 are selected from the group comprising hydrogen, substituted and unsubstituted alkyls containing 1-6 carbon atoms, R.sup.4 is a substituted or unsubstituted alkyl containing 1-6 carbon atoms, R.sup.5 is hydrogen, a substituted or unsubstituted hydrocarbon containing 1-6 carbon atoms and n is an integral 1-6 and thereafter adding possible solvent and at the same time keeping alkali or alkali-earth metal content of the composition in a range of 0.001-30 wt-%, preferably in a range of 0.001-30 wt-% and most preferably in a range of 0.001-1.0 wt-% and halide content in a range of 0.001-1 wt-% most preferably in a range of 0.001-0.1 wt-%.

The invention relates a method for preparing a composition with low corrosive effect and low freezing point, by mixing an ammonium cation source with a carboxyl anion source in an appropriate molar or weight ratio, either without a medium or by using an appropriate medium for obtaining liquid or water-soluble organic ammonium carboxylate of formula (1):

[NR.sup.1R.sup.2R.sup.3R.sup.4].sup.+.sub.n [R.sup.5(COO).sub.n].sup.−n,   (1),

in which R.sup.1, R.sup.2, and R.sup.3 are selected from the group comprising hydrogen, substituted and unsubstituted alkyls containing 1-6 carbon atoms, R.sup.4 is a substituted or unsubstituted alkyl containing 1-6 carbon atoms, R.sup.5 is hydrogen, a substituted or unsubstituted hydrocarbon containing 1-6 carbon atoms and n is an integral 1-6 and thereafter adding possible solvent and at the same time keeping alkali or alkali-earth metal content of the composition in a range of 0.001-30 wt-%, preferably in a range of 0.001-30 wt-% and most preferably in a range of 0.001-1.0 wt-% and halide content in a range of 0.001-1 wt-% most preferably in a range of 0.001-0.1 wt-%.

A process is disclosed for making CF.sub.3CF═CHF. The process involves reacting CF.sub.3CClFCCl.sub.2F with H.sub.2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF.sub.3CF═CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H.sub.2 to CF.sub.3CClFCCl.sub.2F fed to the reaction zone is between about 1:1 and about 5:1. Also disclosed are azeotropic compositions of CF.sub.3CClFCCl.sub.2F and HF and azeotropic composition of CF.sub.3CHFCH.sub.2F and HF.