A process for operating a reforming system by operating a reforming section containing a plurality of reactors, wherein each of the plurality of reactors containing a reforming catalyst capable of catalyzing the conversion of at least a portion of the hydrocarbons in a treated hydrocarbon stream into a reactor effluent comprising aromatic hydrocarbons, and operating a sulfur guard bed (SGB) to remove sulfur and sulfur-containing hydrocarbons from a hydrocarbon feed to provide the treated hydrocarbon stream, where the SGB contains at least a layer of a SGB catalyst comprising the same catalyst as the reforming catalyst, and where each reactor of the plurality of reactors within the reforming section may be operated at a higher operating temperature than an operating temperature of the SGB. A system for carrying out the process is also provided.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

A system for producing a hydrocarbon by high-temperature Fischer-Tropsch synthesis is described. The system includes a Fischer-Tropsch synthesis unit, a reaction water separation unit, and a catalyst reduction unit. The catalyst reduction unit uses a gas containing the tail gas of the synthesis unit as a reducing gas and a small amount of synthesis gas for adjusting the hydrogen to carbon ratio, to react with the Fischer-Tropsch synthesis catalyst. After the reduction reaction, the reacted gas is cooled to room temperature, and enters a gas-liquid separator to obtain a gas phase and a liquid phase. The gas phase flows to a cryogenic separation unit to recover gaseous hydrocarbons. The liquid phase is separated into reaction water and Fischer-Tropsch oil products. The reduced catalyst is sent to the Fischer-Tropsch synthesis unit.

A method for processing a hydrocarbon feed to produce olefins may comprise introducing the hydrocarbon feed to a first fluid catalytic cracking system, which may cause at least a portion of the hydrocarbon feed to undergo catalytic cracking and produce a spent first cracking catalyst and a first cracked effluent comprising one or more olefins. The method may further comprise passing the first cracked effluent to a separation system downstream of the first fluid catalytic cracking system, which may separate the first cracked effluent to produce at least a naphtha effluent comprising one or more olefins. Additionally, the method may comprise passing the naphtha effluent to a second fluid catalytic cracking system downstream of the separation system, which may cause at least a portion of the naphtha effluent to undergo catalytic cracking and produce a spent cracking catalyst mixture and a second cracked effluent comprising one or more olefins.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

A process is provided for the catalytic cracking of a glyceride oil feedstock with a catalyst composition containing a deactivated phosphorus-containing ZSM-5 light olefins selective additive.

According to one or more embodiments, petrochemical products may be formed from a hydrocarbon material by a method that includes separating crude oil into at least two or more fractions in an atmospheric distillation column, hydrotreating the atmospheric residue to form a hydrotreated atmospheric residue, combining steam with the hydrotreated atmospheric residue, and cracking at least a portion of the hydrotreated atmospheric residue in the presence of a first catalyst to produce a cracking reaction product.

A system of reforming reactors comprises a plurality of reactors coupled by flow lines, a feed header coupled to the plurality of reactors by a plurality of feed lines, an effluent header coupled to the plurality of reactors by a plurality of effluent lines, and a plurality of valves disposed in the flow lines, the feed lines, and the effluent lines. Each reactor comprises a reforming catalyst, and the plurality of valves is configured to dynamically connect the plurality of reactors to create a first serial flow path and reconnect the plurality of reactors to create a second serial flow path through the plurality of reactors. A first reactor of the plurality of reactors is adjacent to a second reactor of the plurality of reactors in the first serial flow path, and the first reactor is not adjacent to the second reactor in the second serial flow path.

The present invention refers to an integrated operation method of conventional and residue FCC units that applies a model developed for predicting the catalytic performance of residue FCC units with any content and quality of flushing for the correct prediction and optimization of process simulators for residue FCC units and refining production planning models. The application can be for individual studies in process simulators or in digital twins to mitigate the unreliability in the prediction of the original simulator for studies with wide alteration in the content and quality of the flushing. The other application consists of modifying the refining production planning models based on the simulation result obtained in the modified process simulators to predict the performance of the waste units operating for any variation in the content and quality of the flushing catalyst used. The refining production planning model allows: 1. Indicative of potential profitability gain; 2. Optimum replacement of virgin and flushing catalysts in the conventional and residue FCC units; 3. Better distribution of the flushing content and flushing quality for FCC consumer units of the flushing system; 4. Quantifies the marginal value of flushing generated in the FCCs units that produce flushing; 5. Defines the best virgin catalyst budget and predicts the logistical costs of transporting flushing between the FCC units producing flushing and consuming flushing, considering all viable routes.

A method and a system for treatment of a spent chloroaluminate ionic liquid catalyst and an alkaline wastewater, where the method includes: 1) mixing the catalyst with a concentrated brine for hydrolysis reaction until residual activity of the catalyst is completely eliminated, to obtain an acidic hydrolysate and an acid-soluble oil; 2) mixing the acidic hydrolysate with an alkaline solution containing the alkaline wastewater for neutralization reaction until this reaction system becomes weak alkaline, to obtain a neutralization solution; 3) fully mixing the neutralization solution with a flocculant, carrying out sedimentation and separation, collecting the concentrated brine at an upper layer for reuse in the hydrolysis reaction, and collecting concentrated flocs at a lower layer; 4) dehydrating the concentrated flocs to obtain concentrated brine for reuse into the hydrolysis reaction, and collecting a wet solid slag; and 5) drying the wet solid slag to obtain a dry solid slag.