The present disclosure provides an automatic separation apparatus for four fractions of heavy oil and a separation method thereof, wherein the apparatus includes a solvent reservoir tank (1), a separation unit for four fractions of heavy oil (100) and a receiving apparatus (9). The separation unit for four fractions of heavy oil (100) includes: a filter disc (4) having one end in communication with the solvent reservoir tank (1), and the other end in communication with an inlet of a pre-column flow path switching valve (5); a chromatographic column (6) having an inlet in communication with an outlet of the pre-column flow path switching valve (5), and an outlet in communication with an inlet of a post-column flow path switching valve (8). The receiving apparatus is in communication with an outlet of the post-column flow path switching valve (8).

Proposed is a pretreatment desulfurization system including a desulfurization agent storage tank for storing a liquid-phase pretreatment desulfurization agent and a metering pump for supplying the liquid-phase pretreatment desulfurization agent from the desulfurization agent storage tank to a fuel supply line through which marine fuel oil is supplied to a marine engine in a predetermined ratio. Since a fluid mixture composed of the marine fuel oil and the pretreatment desulfurization agent is supplied to the marine engine, sulfur oxides are adsorbed and removed during combustion of the fluid mixture.

A mobile gas processing plant includes an inlet and an outlet, first and second Joule-Thompson (JT) valve units, an inlet scrubber, a dehydration unit including a contact tower, inlet and outlet filter separators, a vertical separator, and a dual pass line heater including first and second heating coils. The mobile gas processing plant is a mobile unit that is permanently mounted on at least one transport. The dehydration unit includes a contact tower that is permanently mounted on the at least one transport such that the contact tower is rotated up to be in an upright position relative to a base frame of the transport in an operational mode, and the contact tower is rotated down to be in a prostrated position relative to the base frame in a transportation mode. Each of the first and second JT valve units includes a first JT valve and a second JT valve. In the operational mode, and for each of the first and second JT valve units, a hydrocarbon gas stream flows through one of the first and second JT valves operating as a primary valve, and does not flow through the other of the first and second JT valves operating as a backup valve.

A mobile gas processing plant includes an inlet and an outlet, first and second Joule-Thompson (JT) valve units, an inlet scrubber, a dehydration unit including a contact tower, inlet and outlet filter separators, a vertical separator, and a dual pass line heater including first and second heating coils. The mobile gas processing plant is a mobile unit that is permanently mounted on at least one transport. The dehydration unit includes a contact tower that is permanently mounted on the at least one transport such that the contact tower is rotated up to be in an upright position relative to a base frame of the transport in an operational mode, and the contact tower is rotated down to be in a prostrated position relative to the base frame in a transportation mode. Each of the first and second JT valve units includes a first JT valve and a second JT valve. In the operational mode, and for each of the first and second JT valve units, a hydrocarbon gas stream flows through one of the first and second JT valves operating as a primary valve, and does not flow through the other of the first and second JT valves operating as a backup valve.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of this gas processing system.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

Proposed is a pretreatment desulfurization method for marine fuel oil. The method includes a step of preparing a pretreatment desulfurization agent including (a) at least one oxide selected from the group consisting of SiO2, Al2O3, Fe2O3, TiO2, MgO, MnO, CaO, Na2O, K2O, and P2O3, (b) at least one metal selected from the group consisting of Li, Cr, Co, Ni, Cu, Zn, Ga, Sr, Cd, and Pb, and (c) at least one liquid composition selected from the group consisting of sodium tetraborate (Na2B4O7.10H2O), sodium hydroxide (NaOH), sodium silicate (Na2SiO3). and hydrogen peroxide (H2O2). The method also includes a step of feeding the pretreatment desulfurization agent to a fuel supply line through which marine fuel oil is supplied to a marine engine at a certain ratio so that a fluid mixture containing the marine fuel oil and the pretreatment desulfurization agent is supplied to the marine engine, thereby adsorbing and removing sulfur oxides during combustion of the fluid mixture.

A method for the desulfurization and separation of a catalytic cracking light product includes the steps of: 1) contacting a catalytic cracking light product with a desulfurization adsorbent in an adsorption desulfurization reaction unit in the presence of hydrogen for desulfurization, and optionally, carrying out gas-liquid separation on the resulting desulfurization product, to obtain a desulfurized rich gas and a desulfurized crude gasoline, wherein the catalytic cracking light product is an overhead oil-gas fraction from a catalytic cracking fractionator, or a rich gas and a crude gasoline from a catalytic cracking fractionator; and 2) separately sending the desulfurized rich gas and the desulfurized crude gasoline obtained in the step 1) to a catalytic cracking absorption stabilization system for separation, to obtain a desulfurized dry gas, a desulfurized liquefied gas and a desulfurized stabilized gasoline.

The invention includes a gas processing system for transforming a hydrocarbon-containing inflow gas into outflow gas products, where the system includes a gas delivery subsystem, a plasma reaction chamber, and a microwave subsystem, with the gas delivery subsystem in fluid communication with the plasma reaction chamber, so that the gas delivery subsystem directs the hydrocarbon-containing inflow gas into the plasma reaction chamber, and the microwave subsystem directs microwave energy into the plasma reaction chamber to energize the hydrocarbon-containing inflow gas, thereby forming a plasma in the plasma reaction chamber, which plasma effects the transformation of a hydrocarbon in the hydrocarbon-containing inflow gas into the outflow gas products, which comprise acetylene and hydrogen. The invention also includes methods for the use of the gas processing system.