The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying the feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent at a plurality of different operating temperatures based on the ash softening temperature of the feedstock and finally recovering the synthesis gas. The apparatus is configured to perform the process and comprises a plurality of nozzles arranged at an acute angle relative to a horizontal plane of the gasifier.

A fly ash recycling gasification furnace includes a fly ash burner, an ash remover, a fly ash storage tank, a variable pressure lock hopper, a fly ash blending system, an exhaust filter, and a backflushing nitrogen buffer tank. The fly ash burner is located on an inner wall of a hearth of the gasification furnace. The ash remover has an inlet connected to an outlet of a waste boiler of the gasification furnace. The fly ash storage tank is connected to a pressurized nitrogen inlet pipe, and a bottom outlet of the ash remover. The variable pressure lock hopper is connected to the fly ash storage tank. The fly ash blending system is connected to the variable pressure lock hopper and the fly ash burner. The exhaust filter is connected to the storage tank, the lock hopper and the blending system. The buffer tank is connected to the exhaust filter.

The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying the feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent at a plurality of different operating temperatures based on the ash softening temperature of the feedstock and finally recovering the synthesis gas. The apparatus is configured to perform the process and comprises a plurality of nozzles arranged at an acute angle relative to a horizontal plane of the gasifier.

A pulverized coal gasification furnace with multi-level feeding of high speed circulating gasification agent which includes a pulverized coal gasification furnace and a gasification method. The present invention solves the existing problems in short life of burner, uneven slag deposition on the surface of the gasification device which causes burning and corrosion, and uneven temperature distribution along the height direction. The steps are: 1. setting parameters for the gasification chamber; 2. feeding pulverized coal; 3. burning pulverized coal to form molten slag; 4. gasification process of molten slag inside the gasification furnace; 5. removing slag. In the present invention, the furnace body is divided into different levels for the gasification agent, the internal temperature of the furnace along the height direction is evenly distributed, and the furnace is applicable to the coal types which has severe change in ash viscosity in response to temperature changes.

A process for producing black powder oxygen carriers for use in a chemical looping combustion unit includes the steps of: (a) removing and collecting the black powder waste material that was formed in a gas pipeline; (b) pre-treating the collected black powder to adjust its spherical shape to avoid attrition and fines production; and (c) activating the black powder to increase its reactivity rate and produce the black powder oxygen carrier that is suitable for use in the chemical looping combustion process as an oxygen carrier.

An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

The present invention provides a process and apparatus for converting feedstock comprising biomass and/or carbon-containing solid waste material to synthesis gas. The process comprises supplying the feedstock to a gasifier comprising a fluidized bed zone and a post-gasification zone and contacting the feedstock with a gasification agent at a plurality of different operating temperatures based on the ash softening temperature of the feedstock and finally recovering the synthesis gas. The apparatus is configured to perform the process and comprises a plurality of nozzles arranged at an acute angle relative to a horizontal plane of the gasifier.

A fly ash recycling gasification furnace includes a fly ash burner, an ash remover, a fly ash storage tank, a variable pressure lock hopper, a fly ash blending system, an exhaust filter, and a backflushing nitrogen buffer tank. The fly ash burner is located on an inner wall of a hearth of the gasification furnace. The ash remover has an inlet connected to an outlet of a waste boiler of the gasification furnace. The fly ash storage tank is connected to a pressurized nitrogen inlet pipe, and a bottom outlet of the ash remover. The variable pressure lock hopper is connected to the fly ash storage tank. The fly ash blending system is connected to the variable pressure lock hopper and the fly ash burner. The exhaust filter is connected to the storage tank, the lock hopper and the blending system. The buffer tank is connected to the exhaust filter.

An integrated refinery process for the disposal of metal-containing spent coked catalyst from hydrotreating and/or hydrocracking unit operations includes introducing the spent coked catalyst into a membrane wall gasification reactor in the form of flowable particles along with predetermined amounts of oxygen and steam based upon an analysis of the hydrocarbon content of the coke, and optionally, a liquid hydrocarbon; gasifying the feed to produce synthesis gas and a slag material; recovering and subjecting the slag material to further processes in preparation for a leaching step to solubilize and form one or more active phase metal compounds that are recovered from the leaching solution, either separately by sequential processing, or together. The recovered active metal compounds can be used, e.g., in preparing fresh catalyst for use in the refinery's hydroprocessing units.

The present disclosure provides an internally self-circulating fluidized bed gasifier and an air distributor therein for generating a stepped constrained wind. The air distributor includes a gas-material mixture through hole and a plurality of vent holes. Each of the vent holes is designed to have a winding path. Due to the winding paths of the vent holes and an arrangement of converging outlets of the vent holes to the gas-material mixture through hole, which is in communication with a furnace chamber, the present disclosure enables a gas entering the furnace chamber to form a stepped constrained wind and effectively prevents solid-phase materials in the furnace chamber from leaking into a gas mixture chamber. The internally self-circulating fluidized bed gasifier can achieve self-circulation combustion gasification for multiple times and a well-controlled gasification temperature, resulting in a high coal gasification efficiency without an ash leakage.