C10J3/20

Phosphorus coal gasification reaction device for combined production of yellow phosphorus and syngas
20230002693 · 2023-01-05 ·

Disclosed is a phosphorus coal gasification reaction device for combined production of yellow phosphorus and syngas, including a stock bin, a mineral aggregate lock hopper, a phosphorous coal gasification reactor, a slag quench chamber and a slag lock hopper. In the phosphorous coal gasification reactor, a drying zone, a dry distillation zone, a combustion zone, a phosphate rock reduction zone, and a slag bath zone are formed from top to bottom. A gas product outlet communicating with the phosphorous coal gasification reactor is installed at a top of the phosphorous coal gasification reactor, two to eight fuel burners are symmetrically arranged on the combustion zone, and an auxiliary burner communicating with the slag bath zone is arranged at the bottom of the slag bath zone. The reactor device can improve the production capacity of the yellow phosphorus, and reduce the emission of CO.sub.2.

Gasification reactor adaptable for feedstock with wide particle size distribution

The disclosure belongs to the technical field of solid fuel utilization and discloses a gasification reactor adaptable for feedstock with wide particle size distribution, including a reactor body. The reactor body is composed of a first reaction chamber, a second reaction chamber, and a third reaction chamber, which are connected with each other. The side wall of the first reaction chamber is provided with a first vent for introducing a gasification agent to fluidize the fine feedstock particles in the first reaction chamber and the gasification reaction occurs. The bottom of the second reaction chamber is provided with a second vent for introducing an oxidant to react with the coarse feedstock particles in the second reaction chamber. The bottom of the third reaction chamber is provided with a third vent for introducing a gasification agent to fluidize and gasify the incompletely reacted particles in the third reaction chamber.

Gasification reactor adaptable for feedstock with wide particle size distribution

The disclosure belongs to the technical field of solid fuel utilization and discloses a gasification reactor adaptable for feedstock with wide particle size distribution, including a reactor body. The reactor body is composed of a first reaction chamber, a second reaction chamber, and a third reaction chamber, which are connected with each other. The side wall of the first reaction chamber is provided with a first vent for introducing a gasification agent to fluidize the fine feedstock particles in the first reaction chamber and the gasification reaction occurs. The bottom of the second reaction chamber is provided with a second vent for introducing an oxidant to react with the coarse feedstock particles in the second reaction chamber. The bottom of the third reaction chamber is provided with a third vent for introducing a gasification agent to fluidize and gasify the incompletely reacted particles in the third reaction chamber.

METHOD OF ELIMINATION OF POLY- AND PERFLUOROALKYL SUBSTANCES (PFAS) IN A WASTEWATER BIOSOLIDS GASIFICATION PROCESS USING A THERMAL OXIDIZER AND HYDRATED LIME INJECTION

An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

METHOD OF ELIMINATION OF POLY- AND PERFLUOROALKYL SUBSTANCES (PFAS) IN A WASTEWATER BIOSOLIDS GASIFICATION PROCESS USING A THERMAL OXIDIZER AND HYDRATED LIME INJECTION

An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

Advanced thermal chemical conversion process of municipal solid waste
11584893 · 2023-02-21 · ·

A method of processing MSW, either sorted or unsorted, which can be carried out through the use of canisters to hold the waste feedstock, and autoclaves specially designed to process the waste at suitable temperature and pressure combinations is disclosed. The final solid product is a mixture of carbon ash and non-combustible materials, such as, metals, drywall, etc., and syngas that has an enhanced BTU value, typically between about 300 to 700 BTU/ft.sup.3. The remainder solid material generally amounts to approximately 5% of the original MSW volume. This material can then be sorted for metals with the balance being sent to a landfill or other recycling processes depending on its composition.

GASIFICATION REACTOR ADAPTABLE FOR FEEDSTOCK WITH WIDE PARTICLE SIZE DISTRIBUTION

The disclosure belongs to the technical field of solid fuel utilization and discloses a gasification reactor adaptable for feedstock with wide particle size distribution, including a reactor body. The reactor body is composed of a first reaction chamber, a second reaction chamber, and a third reaction chamber, which are connected with each other. The side wall of the first reaction chamber is provided with a first vent for introducing a gasification agent to fluidize the fine feedstock particles in the first reaction chamber and the gasification reaction occurs. The bottom of the second reaction chamber is provided with a second vent for introducing an oxidant to react with the coarse feedstock particles in the second reaction chamber. The bottom of the third reaction chamber is provided with a third vent for introducing a gasification agent to fluidize and gasify the incompletely reacted particles in the third reaction chamber.

GASIFICATION REACTOR ADAPTABLE FOR FEEDSTOCK WITH WIDE PARTICLE SIZE DISTRIBUTION

The disclosure belongs to the technical field of solid fuel utilization and discloses a gasification reactor adaptable for feedstock with wide particle size distribution, including a reactor body. The reactor body is composed of a first reaction chamber, a second reaction chamber, and a third reaction chamber, which are connected with each other. The side wall of the first reaction chamber is provided with a first vent for introducing a gasification agent to fluidize the fine feedstock particles in the first reaction chamber and the gasification reaction occurs. The bottom of the second reaction chamber is provided with a second vent for introducing an oxidant to react with the coarse feedstock particles in the second reaction chamber. The bottom of the third reaction chamber is provided with a third vent for introducing a gasification agent to fluidize and gasify the incompletely reacted particles in the third reaction chamber.

Apparatus and method for generating electricity and producing carbon and heat via biomass fixed bed gasification
11485919 · 2022-11-01 ·

A method and apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, said method and apparatus utilising medium calorific value combustible gas to satisfy high-temperature high-pressure boiler heat requirements, and increasing overall electricity generation efficiency. The method and apparatus have low nitrogen oxides amounts, satisfy environmental protection requirements, and do not require denitrification treatment. The method comprises the following steps: feeding a biomass raw material into a gasification apparatus to prepare a medium calorific value biomass combustible gas, and performing gasification on the biomass raw material at 700-850° C. under the effect of an air/water vapour pre-mixed gasification agent to produce a combustible gas, the calorific value of the combustible gas being 1600-1800 kcal, the temperature being 200-300° C.; directly feeding the combustible gas into an environmentally friendly combustion chamber for combustion, and then into a high-temperature high-pressure boiler, the gas combusting within the high-temperature high-pressure boiler to produce high-temperature high-pressure steam, which drives a steam turbine to generate electricity; utilising steam waste heat discharged by the steam turbine; using boiler tail gas to heat air by means of an air preheater, the hot air being respectively fed into the combustion chamber and the gasification apparatus by means of an air blower, and utilising the waste heat.

Apparatus and method for generating electricity and producing carbon and heat via biomass fixed bed gasification
11485919 · 2022-11-01 ·

A method and apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, said method and apparatus utilising medium calorific value combustible gas to satisfy high-temperature high-pressure boiler heat requirements, and increasing overall electricity generation efficiency. The method and apparatus have low nitrogen oxides amounts, satisfy environmental protection requirements, and do not require denitrification treatment. The method comprises the following steps: feeding a biomass raw material into a gasification apparatus to prepare a medium calorific value biomass combustible gas, and performing gasification on the biomass raw material at 700-850° C. under the effect of an air/water vapour pre-mixed gasification agent to produce a combustible gas, the calorific value of the combustible gas being 1600-1800 kcal, the temperature being 200-300° C.; directly feeding the combustible gas into an environmentally friendly combustion chamber for combustion, and then into a high-temperature high-pressure boiler, the gas combusting within the high-temperature high-pressure boiler to produce high-temperature high-pressure steam, which drives a steam turbine to generate electricity; utilising steam waste heat discharged by the steam turbine; using boiler tail gas to heat air by means of an air preheater, the hot air being respectively fed into the combustion chamber and the gasification apparatus by means of an air blower, and utilising the waste heat.