A reactor configuration is proposed for selectively converting gaseous, liquid or solid fuels to a syngas specification which is flexible in terms of H.sub.2/CO ratio. This reactor and system configuration can be used with a specific oxygen carrier to hydro-carbon fuel molar ratio, a specific range of operating temperatures and pressures, and a co-current downward moving bed system. The concept of a CO.sub.2 stream injected in-conjunction with the specified operating parameters for a moving bed reducer is claimed, wherein the injection location in the reactor system is flexible for both steam and CO.sub.2 such that, carbon efficiency of the system is maximized.

An optimized gasification/vitrification processing system having a gasification unit which converts organic materials to a hydrogen rich gas and ash in communication with a joule heated vitrification unit which converts the ash formed in the gasification unit into glass, and a plasma which converts elemental carbon and products of incomplete combustion formed in the gasification unit into a hydrogen rich gas.

Novel redox based systems for fuel and chemical production with in-situ CO.sub.2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydrogenation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO.sub.2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

A system for removing impurities from post-combustion gas includes an oxidizer and a reducer operatively connected to the oxidizer, the reducer configured to receive the post-combustion gas. The system further includes a CLOU material capable of selective circulation between the oxidizer and reducer. The CLOU material further oxidizes impurities present in the post-combustion gas to reduce or remove the same.

A chemical looping reactor is provided. The reactor comprises a first reduction reactor, a second reduction reactor and a shared oxidation reactor. The shared oxidation reactor is set between the first and second reduction reactors. Therein, the present invention applies interconnected fluidized beds in chemical looping combustion. Single redox is processed with oxygen carrier (oxide of metal like nickel or copper). The first and second reduction reactors individually handle their own reactions and reactants. Thus, in a chemical looping reactor, two different source materials can be handled at the same time. The oxygen carrier can be cycled separately as well for fully releasing oxygen contained within. High-purity carbon dioxide is further obtained. The application can be extended to hydrogen generation. Hence, the present invention simplifies the reaction mechanism, enhances the yield, improves the operation efficiency and reduces the cost.

Apparatus operable using concentrated solar radiation, the apparatus comprising a body having a cavity adapted to receive concentrated solar radiation, a heat energy absorber associated with the cavity to receive heat from concentrated solar radiation within the cavity, a chamber containing a body of matter, the chamber being in heat exchange relation with the heat energy absorber to receive heat therefrom for heating the body of matter, and an inlet means for introducing fluid into the chamber for contacting the contained body of matter. Also, a reactor system for contacting a reactant liquid with two gaseous reactants, the reactor system comprising two reactors interconnected for circulation of a reactant liquid therebetween, whereby the circulating reactant liquid is enabled to react with a gaseous reactant introduced into one reactor and to also react with a gaseous reactant introduced into the other reactor.

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.

Novel redox based systems for fuel and chemical production with in-situ CO.sub.2 capture are provided. A redox system using one or more chemical intermediates is utilized in conjunction with liquid fuel generation via indirect Fischer-Tropsch synthesis, direct hydrogenation, or pyrolysis. The redox system is used to generate a hydrogen rich stream and/or CO.sub.2 and/or heat for liquid fuel and chemical production. A portion of the byproduct fuels and/or steam from liquid fuel and chemical synthesis is used as part of the feedstock for the redox system.

A reactor configuration is proposed for selectively converting gaseous, liquid or solid fuels to a syngas specification which is flexible in terms of H.sub.2/CO ratio. This reactor and system configuration can be used with a specific oxygen carrier to hydro-carbon fuel molar ratio, a specific range of operating temperatures and pressures, and a co-current downward moving bed system. The concept of a CO.sub.2 stream injected in-conjunction with the specified operating parameters for a moving bed reducer is claimed, wherein the injection location in the reactor system is flexible for both steam and CO.sub.2 such that, carbon efficiency of the system is maximized.

This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO.sub.2 and the selective reaction with organic compounds.