Patent classifications
C10L1/196
Polymers as additives for fuels
A method minimizes power loss in a direct injection diesel engine by adding a copolymer to a diesel fuel composition. The copolymer contains, in a copolymerized form, (A) maleic anhydride, (B) an α-olefin having from 12 to 30 carbon atoms, (C) optionally an additional aliphatic or cycloaliphatic olefin which has at least 4 carbon atoms and is different from monomer (B), and (D) optionally an additional copolymerizable monomer other than monomers (A), (B) and (C). Monomer (D) can be a vinyl ester, a vinyl ether, a (meth)acrylic ester of an alcohol having at least 5 carbon atoms, an allyl alcohol or an ester thereof, a N-vinyl compound, an ethylenically unsaturated aromatic, an α,β-ethylenically unsaturated nitrile, a (meth)acrylamide, or an allylamine. Anhydride functionalities present in the copolymer are partly reacted with at least one compound (E) comprising an alcohol group and/or an amino group, and the anhydride functionalities present are hydrolyzed.
COMPOSITIONS AND METHODS AND USES RELATING THERETO
A fuel composition comprising as an additive the reaction product of a polycarboxylic acid having no more than 5 carbon atoms per carboxylic acid group, or an anhydride thereof and an alcohol having at least 5 carbon atoms.
COMPOSITIONS AND METHODS AND USES RELATING THERETO
A fuel composition comprising as an additive the reaction product of a polycarboxylic acid having no more than 5 carbon atoms per carboxylic acid group, or an anhydride thereof and an alcohol having at least 5 carbon atoms.
PARAFFIN INHIBITOR/PPD PRODUCTS WITH VINYL ACETATE-ALKYL ACRYLATE/METHACRYLATE COPOLYMERS COMBINED WITH ETHYLENE-BASED COPOLYMERS
A stabilized paraffin inhibitor/pour point depressant (PI/PPD) product formulation is described which includes a copolymer having a monomer selected from the group consisting of alkyl acrylate polymers, alkyl methacrylate polymers, and combinations thereof, where the copolymer comprises vinyl acetate and the product includes an ethylene-based copolymer. The presence of the vinyl acetate stabilizes the product to prevent or inhibit the ethylene-based copolymer from separating out of the product. The product is useful to reduce paraffin deposition and/or improve flow characteristics of petroleum fluids, such as crude oil.
PARAFFIN INHIBITOR/PPD PRODUCTS WITH VINYL ACETATE-ALKYL ACRYLATE/METHACRYLATE COPOLYMERS COMBINED WITH ETHYLENE-BASED COPOLYMERS
A stabilized paraffin inhibitor/pour point depressant (PI/PPD) product formulation is described which includes a copolymer having a monomer selected from the group consisting of alkyl acrylate polymers, alkyl methacrylate polymers, and combinations thereof, where the copolymer comprises vinyl acetate and the product includes an ethylene-based copolymer. The presence of the vinyl acetate stabilizes the product to prevent or inhibit the ethylene-based copolymer from separating out of the product. The product is useful to reduce paraffin deposition and/or improve flow characteristics of petroleum fluids, such as crude oil.
WAX ANTI-SETTLING ADDITIVE COMPOSITION FOR USE IN DIESEL FUELS
A composition comprising at least one fuel that is a diesel fuel, a biodiesel fuel, or combinations thereof and less than 100 ppm, less than 50 ppm (or less than 25 ppm, less than 10 ppm, 1 to 7 ppm, or 5 to 7 ppm) of an alkylene-coupled C.sub.10 to C.sub.60 (or C.sub.10 to C.sub.40, C.sub.14 to C.sub.32 or C.sub.24 to C.sub.28) alkylphenol; 25 to 500 ppm (or 50 to 500 ppm, or 150 to 450 ppm or 250 to 450 ppm, or 250 to 400 ppm) of a terpolymer; and 5 to 90 ppm, (or 10 to 70 ppm, to 60 ppm, or 10 to 55 ppm) of hydrocarbyl-substituted amine detergent having at least one tertiary amino group.
Methods of reducing the cold filter plugging point (“CFPP”) of a fuel, said method comprising adding the following components: less than 100 ppm, less than 50 ppm (or less than 25 ppm; less than 10 ppm, 1 to 7 ppm, or 5 to 7 ppm) of an alkylene-coupled C.sub.10 to C.sub.60 (or C.sub.10 to C.sub.40, C.sub.14 to C.sub.32 or C.sub.24 to C.sub.28) alkylphenol; 25 to 500 ppm (or 50 to 500 ppm, or 150 to 450 ppm or 250 to 450 ppm, or 250 to 400 ppm) of a terpolymer; and 5 to 90 ppm, (or 10 to 70 ppm, to 60 ppm, or 10 to 55 ppm) of hydrocarbyl-substituted amine detergent having at least one tertiary amino group.
Uses of a fuel additive composition to reduce the cold filter plugging point (“CFPP”) of a fuel, wherein the fuel additive composition comprises: 0.2 to 3 wt % of an alkylene-coupled C.sub.10 to C.sub.60 (or C.sub.10 to C.sub.40, C.sub.14 to C.sub.32 or C.sub.24 to C.sub.28) alkylphenol; 10 to 50 wt % of a terpolymer; and 2 to 10 wt % of hydrocarbyl-substituted amine detergent having at least one tertiary amino group; and an optional solvent.
Polymer compositions and use thereof as pour Point depressants in Paraffin-containing hydrocarbon oils
The invention relates to polymer compositions with improved manageability, The invention also relates to a polymer composition obtainable by radical polymerisation of A) 95-40 wt. % of a monomer mixture comprising Ai) 65-98 wt. % of at least alkyl (meth)acrylate having a linear C.sub.16-C.sub.40 alkyl radical and Aii) 2-35 wt. % of at least one comonomer selected from (meth)acrylates and (meth)acrylamides, which supports an optionally substituted aromatic radical bonded via an alkylene, alkenylene, oxyalkylene or polyoxyalkylene group to the ester group of the (meth)acrylate or to the amide group of the (meth)acrylamide, in the presence of B) 5-60% by weight % of at least one ethylene copolymer. The invention further relates to a method for the preparation and use thereof as flow improvers for paraffin-containing hydrocarbon oils.
Polycarboxylic acid-based additives for fuels and lubricants
An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.
Dewaxed diesel fuel composition
Diesel fuel compositions are provided that have unexpectedly beneficial cold flow properties. Methods for forming such diesel fuel compositions are also provided. The improved cold flow properties are achieved in part based on dewaxing of a distillate fraction of the composition. The improved cold flow properties are achieved further in part based on inclusion of a cold flow additive and fatty acid alkyl ester in the composition, such as fatty acid methyl ester.
Dewaxed diesel fuel composition
Diesel fuel compositions are provided that have unexpectedly beneficial cold flow properties. Methods for forming such diesel fuel compositions are also provided. The improved cold flow properties are achieved in part based on dewaxing of a distillate fraction of the composition. The improved cold flow properties are achieved further in part based on inclusion of a cold flow additive and fatty acid alkyl ester in the composition, such as fatty acid methyl ester.