The present disclosure provides fuel additives including Mannich-based quaternary ammonium salt additives, fuel compositions including such additives, and Methods of improving performance of fuel injector using such additives.

The present disclosure provides fuel additives including Mannich-based quaternary ammonium salt additives, fuel compositions including such additives, and Mehtods of improving performance of fuel injector using such additives.

An olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, or a nitrogen compound quaternized with epoxide in the presence of an olefin-carboxylic acid copolymer, containing at least one free carboxylic acid side group, can be used as a fuel additive or lubricant additive. Processes can be used for preparing additives of this kind and fuels and lubricants additized therewith, such as a detergent additive. These additives, fuels, and lubricants can be used for reduction or prevention of deposits in injection systems of direct injection diesel engines, especially in common rail injection systems; for reduction of fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems; and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems. The additives can also be used for gasoline fuels, especially for operation of DISI engines.

A process of making a fuel product from a non-combustible high protein organic material such as a biological by-product or waste material. The moisture content of the high protein organic material is mechanically reduced and dried to reduce the moisture content to less than ten percent (10%). The high protein organic material is pulverized to a particle size of less than about 2 mm. The high protein organic waste material is fed into a combustion chamber and separated during combustion such as by spraying high protein organic waste material within the combustion chamber. Temperature and combustion reactions within the combustion chamber are controlled by controlling the moisture in the combustion atmosphere and energy injections at or downstream of the combustion chamber. The concentration of protein thermal decomposition by-products, temperature, and residence time and/or additions of energy plasma within the combustion chamber environment are controlled to degrade hazardous polyfluoro compounds.

The use as a valve deposit controlling additive in a fuel composition for a direct injection spark-ignition internal combustion engine of a combination of: a) at least one hydrocarbyl-substituted aromatic compound; and b) at least one polyalkylene amine.

The use of tetrahydrobenzoxazines I ##STR00001##
where R.sup.1 is a hydrocarbyl radical and R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each independently hydrogen atoms, hydroxyl groups or hydrocarbyl radicals, and where R.sup.2 to R.sup.5 may also form a second and a third tetrahydrooxazine ring, with the proviso that at least one of the substituents has from 4 to 3000 carbon atoms and the remaining substituents, when they are hydrocarbyl radicals, each have from 1 to 20 carbon atoms, as stabilizers for stabilizing inanimate organic material, especially turbine fuels, against the action of light, oxygen and heat.

The present technology is related to imide containing quaternary ammonium salts having a hydrocarbyl substituent of number average molecular weight less 300, and additive packages having such quaternary ammonium salts and improved stability.

New, highly effective substantially pure Mannich detergents for use in hydrocarbon fuels reduce engine deposits in spark and compression ignition internal combustion engines. The Mannich condensation reaction products are obtainable by reacting: (i) a polyamine having primary amino groups, (ii) a hydrocarbyl-substituted hydroxyaromatic compound, and (iii) an aldehyde, wherein the reaction is conducted at in a molar ratio of (i):(ii):(iii) of approximately 1:2:3. The Mannich detergent compounds may be dispersed in a liquid carrier to provide a fuel additive concentrate for hydrocarbon engine fuels which effectively control engine deposit formation in intake valves, port fuel injectors and combustion chambers.

The use as a sludge controlling additive in a fuel composition for a spark-ignition internal combustion engine or a compression-ignition gasoline internal combustion engine of a combination of: a. a hydrocarbyl-substituted aromatic compound; and b. a polyalkylene amine. The fuel composition may also be used for maintaining oil pathways and/or lubrication in an engine.

The use as a particulate emissions and/or a complex poly-aromatic nuclei (CPAN) controlling additive in a fuel composition for a direct-injection spark-ignition internal combustion engine or a compression-ignition gasoline internal combustion engine of a combination of: a. a hydrocarbyl-substituted aromatic compound; and b. a polyalkylene amine.