The invention relates to aqueous composition comprising water-soluble glycerin-based polyalkylene glycols as synthetic base oils as well as the use of the composition and the glycerin-based polyalkylene glycols as or in metalworking fluids, wherein the glycerin was consecutively alkoxylated in the following order: first with propylene oxide, followed by ethylene oxide and finally with propylene oxide.

The invention relates to aqueous composition comprising water-soluble glycerin-based polyalkylene glycols as synthetic base oils as well as the use of the composition and the glycerin-based polyalkylene glycols as or in metalworking fluids, wherein the glycerin was consecutively alkoxylated in the following order: first with propylene oxide, followed by ethylene oxide and finally with propylene oxide.

This invention relates to a functional fluid, comprising (A) from 70 to 90, preferably 75-87 wt.-% of alkoxy glycol according to formula (I) CH.sub.3—O—(CH.sub.2—CH.sub.2—O).sub.n—H wherein n is a number from 2 to 5, with the proviso that in at least 30 wt.-% of all compounds according to formula (I) n is 3, and that 15 to 65 wt.-% of all compounds according to formula (I) have n=4 or 5, and (B) less than 1.0 wt.-% of alkoxy glycol according to formula (II) R.sub.1—O—(CH.sub.2—CH.sub.2—O).sub.m—H wherein R.sub.1 is a C.sub.2 to C.sub.8 alkyl residue, m is a number from 2 to 6, (C) from 8 to 25, preferably 12-23 wt.-% of at least one compound according to formula (III) H—O—(CH.sub.2—CH.sub.2—O).sub.k—H wherein k is a number of 2 or higher, with the proviso that in at least 80 wt.-% of all compounds according to formula (III) k is 2 or 3, (D) at least one additive, selected from the group consisting of corrosion inhibitors, alkalinity agents, aging protection agents, defoamers and lubricants, the lubricants being selected from the group consisting of propylene oxide containing alkylene oxide polymers that are optionally substituted with a C.sub.1 to C.sub.4 alkyl group, triglycerides, castor oil, ricinoleic acid, and ethoxylates of castor oil or ricinoleic acid, and mixtures thereof, the fluid comprising at most 3 wt.-% of an ester between boric acid and a glycol or alkylpolyglycol compound.

This invention relates to a functional fluid, comprising (A) from 70 to 90, preferably 75-87 wt.-% of alkoxy glycol according to formula (I) CH.sub.3—O—(CH.sub.2—CH.sub.2—O).sub.n—H wherein n is a number from 2 to 5, with the proviso that in at least 30 wt.-% of all compounds according to formula (I) n is 3, and that 15 to 65 wt.-% of all compounds according to formula (I) have n=4 or 5, and (B) less than 1.0 wt.-% of alkoxy glycol according to formula (II) R.sub.1—O—(CH.sub.2—CH.sub.2—O).sub.m—H wherein R.sub.1 is a C.sub.2 to C.sub.8 alkyl residue, m is a number from 2 to 6, (C) from 8 to 25, preferably 12-23 wt.-% of at least one compound according to formula (III) H—O—(CH.sub.2—CH.sub.2—O).sub.k—H wherein k is a number of 2 or higher, with the proviso that in at least 80 wt.-% of all compounds according to formula (III) k is 2 or 3, (D) at least one additive, selected from the group consisting of corrosion inhibitors, alkalinity agents, aging protection agents, defoamers and lubricants, the lubricants being selected from the group consisting of propylene oxide containing alkylene oxide polymers that are optionally substituted with a C.sub.1 to C.sub.4 alkyl group, triglycerides, castor oil, ricinoleic acid, and ethoxylates of castor oil or ricinoleic acid, and mixtures thereof, the fluid comprising at most 3 wt.-% of an ester between boric acid and a glycol or alkylpolyglycol compound.

A refrigerator oil composition with a base oil (A), and a first phosphorus compound (B). The first phosphorus compound (B) is a first phosphite ester (B1) represented by formula (1) and a second phosphite ester (B2) represented by formula (2):

(R.sup.11—O—).sub.n—PO—R.sup.12).sub.3-n   (1)

##STR00001##

A method of producing a refrigerator oil composition by mixing a base oil (A) with a first phosphorus compound (B). A refrigerator mixture composition includes the refrigerator oil composition and a refrigerant.

A refrigerator oil composition with a base oil (A), and a first phosphorus compound (B). The first phosphorus compound (B) is a first phosphite ester (B1) represented by formula (1) and a second phosphite ester (B2) represented by formula (2):

(R.sup.11—O—).sub.n—PO—R.sup.12).sub.3-n   (1)

##STR00001##

A method of producing a refrigerator oil composition by mixing a base oil (A) with a first phosphorus compound (B). A refrigerator mixture composition includes the refrigerator oil composition and a refrigerant.

The invention relates to a lubricating oil composition and a refrigerant composition containing a polyalkylene glycol having a terpenoid end group, such as a farnesol end group.

The invention relates to a lubricating oil composition and a refrigerant composition containing a polyalkylene glycol having a terpenoid end group, such as a farnesol end group.

The present invention relates to new ether carboxylic acids as high temperature stable rheology modifier, viscosifier, lubricant or emulsifier additives in oilfield and industrial applications. In particular, the invention relates to an ether carboxylic acid or a derivative thereof obtainable by reacting a branched polyol alkoxylate with a halogen carboxylic acid or a halogen carboxylic acid derivative. Further aspects of the invention relate to a lubricant composition comprising an ether carboxylic acid of the invention and the use of said ether carboxylic acid.

The lubricating oil composition for a refrigerator according to the present invention is a lubricating oil composition for a refrigerator containing a base oil containing a low-viscosity base oil component having added thereto a polyoxyalkylene glycol compound having a kinetic viscosity at 100° C. that is higher than the low-viscosity base oil component, and the base oil has a kinetic viscosity at 100° C. of 2.4 to 25 mm.sup.2/s and a ratio (Mw/Mn) of a weight average molecular weight (Mw) and a number average molecular weight (Mn) of 1.3 to 13.